公开(公告)号：US4847185A

公开(公告)日：1989-07-11

申请号：US213416

申请日：1988-06-30

申请人： William J. Begley ,  Michael J. Carmody ,  John M. Buchanan

发明人： William J. Begley ,  Michael J. Carmody ,  John M. Buchanan

IPC分类号： C07D255/04 ,  C07D257/04 ,  C07D401/12 ,  C07D403/06 ,  C07D403/12 ,  G03C7/305

CPC分类号： C07D257/04 ,  C07D255/04 ,  C07D401/12 ,  C07D403/06 ,  C07D403/12 ,  G03C7/30576 ,  Y10S430/156 ,  Y10S430/158

摘要： Photographic compounds capable of releasing a photographically useful group (PUG) by means of an intramolecular nucleophilic displacement provide increased image acutance when a coupling-off group in the coupling position of the compound is a group of the formula: ##STR1## wherein PUG is a photographically useful group; Q is N or C--R where R is hydrogen or a substituent that does not adversely affect imaging; and Z represents atoms completing a non-aromatic, heterocyclic ring. The photographic compounds are useful in photographic materials and processes.

公开(公告)号：US4414308A

公开(公告)日：1983-11-08

申请号：US358685

申请日：1982-03-16

申请人： Fumio Hamada

发明人： Fumio Hamada

IPC分类号： G03C7/30 ,  G03C7/305 ,  G03C1/40

CPC分类号： G03C7/3003 ,  G03C7/30576 ,  G03C2007/3034 ,  G03C2200/35 ,  G03C7/30541 ,  Y10S430/158

摘要： In a silver halide color photographic photosensitive material, having a red, a green and a blue light-sensitive emulsion layer on a support, each emulsion containing a nondiffusible image forming coupler, improvement is attained by providing a layer structure in which at least one of the red, the green and the blue light-sensitive emulsion layer is separated into a high sensitivity silver halide emulsion layer and a low sensitivity silver halide emulsion layer, both layers having photosensitive regions in substantially the same spectral region, by an intermediate layer and incorporating at least one kind of DIR compounds represented by formula (I) defined in the specification in at least one layer of the high sensitivity silver halide emulsion layer, the low sensitivity silver halide emulsion and the intermediate layer.

摘要翻译： 在一种卤化银彩色照相感光材料中，在支持体上具有红色，绿色和蓝色感光乳剂层，每种乳液含有不扩散图像形成成色剂，通过提供一种层结构来实现改进，其中至少一种 将红色，绿色和蓝色感光乳剂层分离成高灵敏度卤化银乳剂层和低灵敏度卤化银乳剂层，两层具有基本相同的光谱区域中的感光区域，通过中间层并结合 至少一种在本说明书中限定的至少一种高灵敏度卤化银乳剂层，低灵敏度卤化银乳剂和中间层中的式（I）表示的DIR化合物。

公开(公告)号：US20040086811A1

公开(公告)日：2004-05-06

申请号：US10689356

申请日：2003-10-21

申请人： FUJI PHOTO FILM CO., LTD.

发明人： Fumitaka Ueda ,  Koji Takaku ,  Ryoji Nishimura ,  Keisuke Matsumoto ,  Yoshio Ishii

IPC分类号： G03C001/08 ,  G03C007/26 ,  G03C007/32

CPC分类号： G03C7/30576 ,  G03C7/3022 ,  G03C7/3029 ,  G03C2001/0055 ,  G03C2001/0056 ,  G03C2007/3034 ,  G03C2200/03

摘要： A silver halide color photosensitive material has, on a support, a unit blue-sensitive silver halide emulsion layer, a unit green-sensitive silver halide emulsion layer and a unit red-sensitive silver halide emulsion layer, each comprising two or more light-sensitive layers having the same color sensitivity but differing in speed to each other. The silver halide color photosensitive material contains at least one compound represented by the following general formula (I) or general formula (II); and at least one of the light-sensitive layers contains silver halide grains in which tabular grains each having an aspect ratio of 5.0 or more account for 60% or more of the total projected area of the silver halide grains. 1 The respective definitions of the substituents are described in the specification.

摘要翻译： 卤化银色感光材料在载体上具有单位感蓝卤化银乳剂层，单位感绿卤化银乳剂层和单位红敏卤化银乳剂层，每层包含两个或更多个光敏感 具有相同颜色灵敏度但彼此不同速度的层。 卤化银色感光材料含有至少一种由以下通式（I）或通式（II）表示的化合物： 并且感光层中的至少一个含有卤化银颗粒，其中各自具有5.0以上的纵横比的片状颗粒占卤化银颗粒的总投影面积的60％以上。 取代基的各自定义在说明书中描述。

公开(公告)号：US06413708B1

公开(公告)日：2002-07-02

申请号：US09710341

申请日：2000-11-09

申请人： Wojciech K. Slusarek ,  Xiqiang Yang ,  David H. Levy

发明人： Wojciech K. Slusarek ,  Xiqiang Yang ,  David H. Levy

IPC分类号： G03C142

CPC分类号： G03C7/30576 ,  G03C7/305 ,  G03C7/30511

摘要： This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.

摘要翻译： 本发明涉及一种成像元件，其包括具有结构I的化合物的成像层：在上述结构I中，取代基如本申请中所定义。 这些化合物具有良好的反应性，并且可以通过用于阻挡照相用的化合物如显影剂，直到在预选条件下热活化。 根据本发明的化合物在彩色光热敏成像元件中特别有用。

公开(公告)号：US5985531A

公开(公告)日：1999-11-16

申请号：US887931

申请日：1997-07-03

申请人： Takeshi Nakamine ,  Hajime Nakagawa ,  Osamu Uchida ,  Hideaki Sato ,  Toshio Kawagishi

发明人： Takeshi Nakamine ,  Hajime Nakagawa ,  Osamu Uchida ,  Hideaki Sato ,  Toshio Kawagishi

IPC分类号： G03C7/00 ,  G03C7/305

CPC分类号： G03C7/30576 ,  G03C7/30552 ,  Y10S430/158

摘要： A silver halide color photographic light-sensitive material containing a compound represented by formula (I) belowformula (I)A--O--C(.dbd.O)--N(X.sub.1)--C(X.sub.2)(X.sub.3)--DIwherein A represents a coupler residue, X.sub.1 represents a heterocyclic group or a --C(X.sub.4)(X.sub.5)--Y group, Y represents an --SO.sub.2 R.sup.1, --SO.sub.2 NR.sup.1 R.sup.2, --CONR.sup.1 R.sup.2, --CO.sub.2 Z, --CN, --CF.sub.3, --CCl.sub.3, or --NO.sub.2 group, each of R.sup.1 and R.sup.2 independently represents a hydrogen atom or a substituted or nonsubstituted alkyl, cycloalkyl, alkenyl, aryl, or heterocyclic group, Z represents a hydrogen atom or a substituted or nonsubstituted cycloalkyl, alkenyl, aryl, or heterocyclic group, each of X.sub.2, X.sub.3, X.sub.4, and X.sub.5 represents a hydrogen atom or a substituent group, and DI represents a development inhibitor residue which is bonded by a hetero atom and released to form mercaptoazole.

摘要翻译： 含有由式（I）表示的化合物（I）表示的化合物的卤化银彩色照相感光材料AOC（= O）-N（X1）-C（X2）（X3）-DI其中A表示成色剂残基X1 表示杂环基或-C（X 4）（X 5）-Y基，Y表示-SO 2 R 1，-SO 2 NR 1 R 2，-CONR 1 R 2，-CO 2 Z，-CN，-CF 3，-CCl 3或-NO 2基， R 2独立地表示氢原子或取代或未取代的烷基，环烷基，烯基，芳基或杂环基，Z表示氢原子或取代或未取代的环烷基，烯基，芳基或杂环基，X， X4和X5表示氢原子或取代基，DI表示通过杂原子键合并释放形成巯基唑的显影抑制剂残基。

公开(公告)号：US5837438A

公开(公告)日：1998-11-17

申请号：US35878

申请日：1993-03-23

申请人： Atsuhiro Ohkawa ,  Keiji Mihayashi

发明人： Atsuhiro Ohkawa ,  Keiji Mihayashi

IPC分类号： C07D403/12 ,  G03C7/305 ,  G03C7/32

CPC分类号： C07D403/12 ,  G03C7/30576 ,  G03C7/30541 ,  Y10S430/158

摘要： A compound represented by the following general formula (I) is added to at least one layer of a silver halide photographic photosensitive material, thereby improving sharpness and graininess or decreasing a variation in photographic performance during storage after photography and before development: ##STR1## where A represents a coupler moiety, each of R.sup.1 and R.sup.2 independently represents a hydrogen atom or a substituent, each of R.sup.3 and R.sup.4 independently represents a hydrogen atom or an alkyl group, INH represents a group having a development inhibiting function, and R.sup.5 represents a nonsubstituted phenyl group, a nonsubstituted primary alkyl group, or a primary alkyl group substituted with a group other than an aryl group, at least one of R.sup.1 to R.sup.4 being a substituent other than a hydrogen atom, and an --OC(.dbd.O)-- group combining with one of two nitrogen atoms forming a pyrazole ring.

摘要翻译： 将由以下通式（I）表示的化合物加入到至少一层卤化银照相感光材料中，从而在摄影和显影前储存期间提高清晰度和颗粒度或降低摄影性能的变化： 式（I）其中A表示成色剂部分，R 1和R 2各自独立地表示氢原子或取代基，R 3和R 4各自独立地表示氢原子或烷基，INH表示具有显影抑制功能的基团， R 5表示非取代的苯基，未取代的伯烷基或被除芳基以外的基团取代的伯烷基，R 1〜R 4为除氢原子以外的取代基中的至少一个，-OC（ = O） - 与形成吡唑环的两个氮原子中的一个结合。

公开(公告)号：US5686234A

公开(公告)日：1997-11-11

申请号：US590661

申请日：1996-01-24

申请人： William James Begley ,  Teh Hsuan Chen ,  Donald Singleton, Jr. ,  Frank Dino Coms

发明人： William James Begley ,  Teh Hsuan Chen ,  Donald Singleton, Jr. ,  Frank Dino Coms

IPC分类号： C07D403/12 ,  G03C7/305 ,  G03C7/40

CPC分类号： C07D403/12 ,  G03C7/30576 ,  G03C2200/33 ,  Y10S430/156 ,  Y10S430/157 ,  Y10S430/158 ,  Y10S430/159 ,  Y10S430/16

摘要： A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formula COUP--T.sup.1 --T.sup.2 --(T.sup.3).sub.b --PUG wherein COUP is a coupler moiety having a coupling site to which T.sup.1 is attached; T.sup.1 is a timing or linking group which releases from COUP during processing and which functions by electron transfer down a conjugated or unconjugated chain, or by nucleophilic displacement reaction, to release T.sup.2, T.sup.2 being an indazole timing or linking group which, after release from T.sup.1, functions by electron transfer down a conjugated chain to release T.sup.3 or PUG, and which is represented by the formula: ##STR1## wherein ** denotes the point of attachment to T.sup.1 and *** denotes the point of attachment to T.sup.3 or PUG; R.sup.1 and R.sup.2 are independently selected from hydrogen, or an aliphatic, carbocyclic, or heterocyclic group, or may be bonded together to form a 5, 6, or 7 membered ring; V is independently selected from the group consisting of an alkyl, carbocyclic, heterocyclic, halo, carbamoyl, sulfamoyl, carbonamido, sulfonamido, keto, sulfo, nitro, hydroxyl, carboxyl, amino, alkoxy, alkoxycarbonyl, aryloxy, or arylthio group; q is 0, 1, 2, 3 or 4; T.sup.3 is a timing or linking group attached to T.sup.2 which is released therefrom after T.sup.2 releases from T.sup.1, and which functions by electron transfer down a conjugated or unconjugated chain, or by nucleophilic displacement reaction, to release PUG; b is 0 or 1; and PUG is a photographically useful group.

摘要翻译： 一种照相元件，包括一个载体，其上至少有一个卤化银乳剂层，该层含有由COUP-T1-T2-（T3）代表的COUP-T1-T2-（T3）b-PUG的照相成色剂，其中COUP是具有偶合位点的成色剂部分， T1连接; T1是在加工期间从COUP释放的定时或连接基团，并且通过电子转移通过共轭或非共轭链或通过亲核取代反应进行功能释放T2，T2是吲唑定时或连接基团，其在从T1释放后 通过电子转移共轭链释放T3或PUG起作用，其由下式表示：其中**表示与T1的连接点，***表示与T3或PUG的连接点; R 1和R 2独立地选自氢或脂族，碳环或杂环基，或可以键合在一起形成5,6或7元环; 卤素，氨基甲酰基，氨基磺酰基，碳酰氨基，亚磺酰氨基，酮基，磺基，硝基，羟基，羧基，氨基，烷氧基，烷氧基羰基，芳氧基或芳硫基。 q是0，1，2，3或4; T3是连接T2的定时或连接基团，其在T2从T2释放后从其释放，并且通过电子转移通过共轭或非共轭链或通过亲核置换反应起作用以释放PUG; b为0或1; PUG是一个摄影有用的小组。

公开(公告)号：US5631125A

公开(公告)日：1997-05-20

申请号：US609964

申请日：1996-02-29

申请人： Jean-Marie Dewanckele ,  Johan Loccufier ,  Pierre De Clercq ,  Dirk Van Haver ,  Noel Hosten

发明人： Jean-Marie Dewanckele ,  Johan Loccufier ,  Pierre De Clercq ,  Dirk Van Haver ,  Noel Hosten

IPC分类号： G03C7/00 ,  C07D285/12 ,  C07D285/125 ,  C07D417/12 ,  G03C1/06 ,  G03C1/43 ,  G03C7/305 ,  G03C1/34 ,  G03C1/42

CPC分类号： C07D285/125 ,  C07D417/12 ,  G03C1/061 ,  G03C7/30576 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/16

摘要： A photographic element is disclosed containing a compound capable of releasing image-wise a photographic useful group (PUG) based on a mechanism involving radical formation under development conditions and splitting of a homolytically labile bond. In a preferred embodiment the compound capable of releasing the PUG is a hydrazine derivative or a 1-aryl-3-pyrazolidinone derivative.

摘要翻译： 公开了一种照相材料，其含有能够基于在显影条件下自由基形成的机理和均质不稳定键的分裂的能够以图像方式照相的有用基团（PUG）的化合物的化合物。 在优选的实施方案中，能够释放PUG的化合物是肼衍生物或1-芳基-3-吡唑烷酮衍生物。

公开(公告)号：US5447819A

公开(公告)日：1995-09-05

申请号：US250416

申请日：1994-05-27

申请人： Jared B. Mooberry ,  James J. Seifert ,  David Hoke ,  Zheng Z. Wu ,  David T. Southby ,  Frank D. Coms

发明人： Jared B. Mooberry ,  James J. Seifert ,  David Hoke ,  Zheng Z. Wu ,  David T. Southby ,  Frank D. Coms

IPC分类号： G03C7/00 ,  G03C7/30 ,  G03C7/305 ,  G03C7/36 ,  G03C7/333

CPC分类号： G03C7/30576 ,  G03C7/30547 ,  Y10S430/156

摘要： The invention provides a photographic element comprising a support bearing a photographic silver halide emulsion layer having associated therewith a high dye-yield coupler having the formula:COUP--(T).sub.m --L--DYEwhere COUP is the parent group of the coupler capable of reacting at the coupling position with oxidized color developer to form a first dye, T is one or more timing groups with m=1 or 2, L is a linking group selected from the group consisting of --OC(O)--, --OC(S)--, --SC(O)--, --SC(S)--, or --OC(.dbd.N SO.sub.2 R)--, where R is substituted or unsubstituted alkyl or aryl, and DYE is a second dye or precursor thereof, wherein there is present at least one T group that contains a substituent having the formula:--(LINK).sub.p --A--B--(C--D).sub.nwherein:LINK is an alkylene group capable of linking the above group to the group T, where p=0 or 1;A is a member selected from the group consisting of --NHCO--, --N(R')C(O)N(R--)--, --CONH--, --NR'SO.sub.2 --, --SO.sub.2 NR'--, and --OPO.sub.2 --, where R' is hydrogen or substituted or unsubstituted alkyl;B is a substituted or unsubstituted aromatic carbocyclic or heterocyclic group;C is a solubilizing group selected from --NHSO.sub.2 -- and --SO.sub.2 NH--;D is a substituted or unsubstituted alkyl, aryl, or heterocyclic ring; andn is from 1 to 3.The invention also provides a photographic coupler, a photographic silver halide emulsion, and a process for forming an image in a photographic element in accordance with the invention.

摘要翻译： 本发明提供了一种照相元件，其包括带有照相卤化银乳剂层的载体，其具有下式的高染料收率成色剂：COUP-（T）mL-DYE，其中COUP是能够在 与氧化的显色剂的偶联位置形成第一染料，T是m = 1或2的一个或多个时基，L是选自-OC（O） - ， - OC（S） - ， - SC（O） - ， - SC（S） - 或-OC（= N SO 2 R） - ，其中R是取代或未取代的烷基或芳基，DYE是第二种染料或其前体， 含有具有下式的取代基的至少一个T基团： - （LINK）pAB-（CD）n其中：LINK是能够将上述基团连接到基团T的亚烷基，其中p = 0或1; A是选自-NHCO-，-N（R'）C（O）N（R） - ， - CONH - ， - NR'SO 2 - ， - SO 2 NR' - 和-OPO 2 - 其中R'是氢或取代或未取代的烷基; B是取代或未取代的芳族碳环或杂环基; C是选自-NHSO 2 - 和-SO 2 NH-的增溶基团; D是取代或未取代的烷基，芳基或杂环; 并且n为1至3.本发明还提供照相成色剂，照相卤化银乳剂，以及根据本发明在照相元件中形成图像的方法。

公开(公告)号：US5360709A

公开(公告)日：1994-11-01

申请号：US37680

申请日：1993-03-25

申请人： Atsuhiro Ohkawa ,  Masuji Motoki ,  Keiji Mihayashi

发明人： Atsuhiro Ohkawa ,  Masuji Motoki ,  Keiji Mihayashi

IPC分类号： G03C7/305 ,  G03C7/32

CPC分类号： G03C7/30529 ,  G03C7/30541 ,  G03C7/30576 ,  Y10S430/158

摘要： A silver halide color photographic material comprising on a support at least a silver halide emulsion layer, comprising a compound represented by general formula (I):A--(L).sub.r --INH--(CH.sub.2).sub.n --Q(I)wherein A represents a coupler residue excepting 1H-pyrazolo[1,5-b]-1,2,4-triazole and 1H-pyrazolo[5,1-c]-1,2,4-triazole; L represents a timing group or a group which reduces an oxidation product of a developing agent; r represents an integer of 2 to 4; n represents an integer of 0 to 3; Q represents a group having a molecular weight of 80 to 250; and INH represents a development inhibitor residue bonded to A--(L).sub.r via hetero atoms and selected from a group ##STR1## wherein * represents the position at which the group is connected to L and ** represents the position at which the group is connected to --(CH.sub.2).sub.n --Q.

摘要翻译： 一种卤化银彩色照相材料，在载体上至少含有卤化银乳剂层，其包含通式（I）表示的化合物：A-（L）r-INH-（CH 2）n Q（I）其中A表示成色剂 除1H-吡唑并[1,5-b] -1,2,4-三唑和1H-吡唑并[5,1-c] -1,2,4-三唑以外的残基; L表示降低显影剂的氧化产物的定时基团或基团; r表示2〜4的整数， n表示0〜3的整数， Q表示分子量为80〜250的基团; 并且INH表示通过杂原子键合到A-（L）r的显影抑制剂残基并且选自组IMA（INH-1）（INH-2）其中*表示 组连接到L，**表示组连接到 - （CH2）nQ的位置。