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公开(公告)号：US4533707A
公开(公告)日：1985-08-06
申请号：US621462
申请日：1984-06-18
Applicant: Ian D. McKenzie
Inventor： Ian D. McKenzie
CPC classification number: C08F10/00 , Y10S526/904 , Y10S526/906
Abstract: A supported transition metal composition is obtained by suspending a support material in an inert liquid medium, spraying the suspension, collecting a solid material and contacting the sprayed solid with a transition metal compound. The support material may be a metal halide such as magnesium chloride or an inorganic oxide such as silica or alumina. In addition to being contacted with the transition metal compound, the support material may be contacted either before or after the spraying step with other reagents such as organo metallic compounds, halogen compounds, or Lewis Base compounds. The product obtained after contacting with the transition metal compound may be used as a component of a polymerization catalyst system to polymerize an unsaturated monomer such as ethylene or propylene.
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42.发明授权Catalyst prepared from organomagnesium compound, carbon dioxide, reducing aluminum source, transition metal compound and zinc compound 失效催化剂由有机镁化合物，二氧化碳，还原铝源，过渡金属化合物和锌化合物制备
公开(公告)号：US4529715A
公开(公告)日：1985-07-16
申请号：US542854
申请日：1983-10-17
Applicant: Ricardo Fuentes, Jr. , Calvin P. Esneault
Inventor： Ricardo Fuentes, Jr. , Calvin P. Esneault
CPC classification number: C08F10/00
Abstract: A catalyst for polymerizing olefins is the product resulting from a mixture of (A) an organomagnesium material, (B) essentially anhydrous carbon dioxide, (C) a reducing halide source and (D) the reaction product or complex resulting from admixing a transition metal compound and an organozinc compound.
Abstract translation: 用于聚合烯烃的催化剂是由（A）有机镁材料，（B）基本上无水的二氧化碳，（C）还原卤化物源和（D）由（A）混合过渡金属 化合物和有机锌化合物。
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43.发明授权Method of preparing a supported Ziegler-catalyst for the polymerization of alpha-olefins 失效制备用于α-烯烃聚合的负载齐格勒催化剂的方法
公开(公告)号：US4506027A
公开(公告)日：1985-03-19
申请号：US550422
申请日：1983-11-10
Applicant: Renzo Invernizzi , Ferdinando Ligorati
Inventor： Renzo Invernizzi , Ferdinando Ligorati
CPC classification number: C08F10/00 , Y10S526/904
Abstract: Method of preparing a supported Ziegler-catalyst active in the polymerization of alpha-olefins to polymers particularly suited to working by blow-moulding, by reacting:(A) an organometallic compound of aluminium, and(B) the product of the reaction of titanium and vanadium halides with a solid support obtained by the spray drying of magnesium chloride in a mixed solution of ethanol and methanol, the support containing both ethanolic and methanolic alcoholic hydroxyl groups.
Abstract translation: 通过使（A）铝的有机金属化合物和（B）钛的反应产物反应，制备在α-烯烃聚合中活性的负载的齐格勒 - 催化剂的方法，特别适用于通过吹塑加工 和通过在乙醇和甲醇的混合溶液中喷雾干燥氯化镁获得的固体支持物的钒卤化物，该载体含有乙醇和甲醇的醇羟基。
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公开(公告)号：US4497906A
公开(公告)日：1985-02-05
申请号：US465674
申请日：1983-02-10
Applicant: Katsumi Hanji , Kiyoshi Kawai
Inventor： Katsumi Hanji , Kiyoshi Kawai
CPC classification number: C08F10/00
Abstract: A solid catalyst component for olefin polymerization comprising a hydrocarbon-insoluble product (III) obtained by reacting(A) a silicon compound selected from the group consisting of(1) halogen-containing silicon compounds,(2) silicon compounds having a monomeric unit ##STR1## (wherein R.sup.1 and R.sup.2 may be the same or different, R.sup.1 represents an alkyl, aryl, cycloalkyl, alkoxy, or aryloxy group, or a hydrogen atom, and R.sup.2 represents an alkyl, aryl, or cycloalkyl group or a hydrogen or halogen atom) and a polymerization degree of 2 to 10,000,(3) silanols of the general formula R.sub.l.sup.3 Si(OH).sub.4-l (wherein R.sup.3 represents an alkyl, aryl, or cycloalkyl group or a hydrogen atom, and l is 1, 2 or 3) or condensation products thereof,(4) silicon compounds represented by the general formula R.sub.m.sup.4 Si(OR.sup.5).sub.4-m (wherein R.sup.4 represents n alkyl, aryl, cycloalkyl, or alkenyl group or a hydrogen atom, R.sup.5 represents an alkyl or aryl group or a fatty acid moiety, and m is 1, 2 or 3), and(5) silicon compounds or polymers thereof represented by the general formula [SiO.sub.a (OR.sup.6).sub.b ].sub.n (wherein R.sup.6 represents an alkyl, cycloalkyl, aralkyl or aryl group or a fatty acid moiety, and a and b are each a number defined by the formula 0.ltoreq.a.ltoreq.1 or 2.ltoreq.b.ltoreq.4, and n is an integer of from 1 to 10,000), with(B) a compound of a transition metal of Groups IVa, Va and VIa of the periodic table to form a reaction mixture (I), further reacting the reaction mixture (I) with(C) an organomagnesium compound selected from organomagnesium compounds or hydrocarbon-soluble complexes thereof with an organometallic compound capable of solubilizing said organomagnesium compounds, to produce an intermediate product (II) and contacting the intermediate product (II) with(D) an organoaluminum halide represented by the general formula R.sub.0.sup.7 AlX.sub.3-c (wherein R.sup.7 represents an organic group having 1 to 20 carbon atoms, X represents a halogen, and c is a number defined by the formula 0
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公开(公告)号：US4483939A
公开(公告)日：1984-11-20
申请号：US406449
申请日：1982-08-09
Applicant: Kazuo Baba , Kizuku Wakatsuki , Toshimi Sato , Tadashi Hikasa
Inventor： Kazuo Baba , Kizuku Wakatsuki , Toshimi Sato , Tadashi Hikasa
CPC classification number: C08F10/00
Abstract: A process for producing a polyolefin, which comprises polymerizing an olefin in the presence of a catalyst system comprising:(a) a solid catalyst component obtained by supporting a titanium compound and/or a vanadium compound on a solid product derived from the reaction of a phenol, an aromatic carboxylate ester, and a solid reaction product of an organomagnesium compound and an aryloxyaluminum compound represented by the general formula Al(OR.sup.1).sub.3, wherein R.sup.1 represents an aryl group having 6 to 20 carbon atoms; and(b) an organoaluminum compound.
Abstract translation: 一种制备聚烯烃的方法，其包括在催化剂体系存在下使烯烃聚合，所述催化剂体系包括：（a）通过将钛化合物和/或钒化合物负载在由 苯酚，芳族羧酸酯，以及由通式Al（OR 1）3表示的有机镁化合物和芳氧基铝化合物的固体反应产物，其中R1表示碳原子数为6〜20的芳基。 和（b）有机铝化合物。
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Patent Agency Ranking
公开(公告)号：US4468477A
公开(公告)日：1984-08-28
申请号：US164930
申请日：1980-07-01
Applicant: Anthony D. Caunt , Paul D. Gavens , John McMeeking
Inventor： Anthony D. Caunt , Paul D. Gavens , John McMeeking
CPC classification number: C08F10/00
Abstract: A catalyst component is a transition metal composition which is obtained by reacting together an inert particulate material, an organic magnesium compound, a halogen-containing compound such as carbon tetrachloride or silicon tetrachloride and a specified transition metal compound. The catalyst component obtained can be used, together with an organic metal compound, to give an olefin polymerization catalyst. The catalyst can be used to effect the polymerization of olefin monomers, for example, the copolymerization of ethylene with an alpha-olefin monomer such as butene-1 in a fluidized bed reactor.
Abstract translation: 催化剂组分是通过将惰性颗粒材料，有机镁化合物，含卤素化合物如四氯化碳或四氯化硅与特定的过渡金属化合物反应而获得的过渡金属组合物。 获得的催化剂组分可与有机金属化合物一起使用以产生烯烃聚合催化剂。 催化剂可用于实现烯烃单体的聚合，例如在流化床反应器中乙烯与α-烯烃单体如丁烯-1的共聚。
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公开(公告)号：US4444968A
公开(公告)日：1984-04-24
申请号：US424803
申请日：1982-09-27
Applicant: Max P. McDaniel , Marvin M. Johnson
Inventor： Max P. McDaniel , Marvin M. Johnson
CPC classification number: C08F10/00
Abstract: In accordance with one embodiment of this invention, a zerovalent chromium compound is introduced onto an activated phosphate-containing support and utilized in conjunction with an organometal cocatalyst, such as a trialkylborane. In accordance with another embodiment of this invention, a phosphate-containing xerogel is formed by removing water from an aluminum phosphate-containing hydrogen by means of azeotropic distillation or washing with a volatile, water miscible organic compound, activated and thereafter zerovalent chromium is incorporated therewith. In other embodiments of this invention, a phosphate-containing support is formed by forming aluminum phosphate from an aluminum alkoxide or from a melt, or by phosphating silica or alumina, or by forming an aluminum phosphate/silica combination. A support thus formed is activated and a zerovalent chromium compound added. The resulting catalysts are capable of giving high melt index, broad molecular weight distribution polymer, which polymer also exhibits other deviations from typical olefin polymers including lower flexural modulus. The catalyst is ideally suited for forming olefin polymers such as ethylene and ethylene copolymers in a slurry system.
Abstract translation: 根据本发明的一个实施方案，将零价铬化合物引入到活化的含磷酸盐载体上并与有机金属助催化剂如三烷基硼烷结合使用。 根据本发明的另一个实施方案，通过共沸蒸馏或用挥发性水混溶性有机化合物洗涤来从含磷酸氢盐的氢中除去水而形成含磷酸的干凝胶，然后活化其中的零价铬 。 在本发明的其他实施方案中，通过由烷氧基铝或熔体形成磷酸铝，或通过磷酸二氧化硅或氧化铝，或通过形成磷酸铝/二氧化硅组合形成含磷酸盐的载体。 如此形成的载体被活化并加入零价铬化合物。 所得到的催化剂能够提供高熔体指数，宽分子量分布的聚合物，该聚合物还表现出与典型烯烃聚合物的其它偏差，包括较低的弯曲模量。 该催化剂理想地适用于在淤浆体系中形成烯烃聚合物如乙烯和乙烯共聚物。
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公开(公告)号：US4440869A
公开(公告)日：1984-04-03
申请号：US429632
申请日：1982-09-30
Applicant: Mark L. Shannon , Mark P. Mack
Inventor： Mark L. Shannon , Mark P. Mack
CPC classification number: C08F10/00
Abstract: High activity catalysts for the polymerization of ethylene and other .alpha.-olefins are made by contacting a soluble magnesium compound of the general formula Mg(OSiR.sub.3).sub.2, wherein each R is, independently, alkyl, alkoxy or aryl, with a titanium tetralkoxide (titanate) in a saturated aliphatic hydrocarbon solution, followed by chlorination and precipitation by a suitable chlorinating agent. These catalysts show high activity for the polymerization of ethylene under slurry polymerization conditions.
Abstract translation: 通过使通式Mg（OSiR 3）2的可溶性镁化合物，其中每个R独立地是烷基，烷氧基或芳基与四氢化钛（钛酸盐）接触来制备用于乙烯和其它α-烯烃聚合的高活性催化剂 ）饱和脂肪族烃溶液中，然后通过合适的氯化剂进行氯化和沉淀。 这些催化剂在淤浆聚合条件下对乙烯的聚合显示出高活性。
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公开(公告)号：US4433121A
公开(公告)日：1984-02-21
申请号：US395472
申请日：1982-07-06
Applicant: Yasunori Kabu , Masayoshi Yasunaka , Yoshinori Morita , Masanori Motowoka
Inventor： Yasunori Kabu , Masayoshi Yasunaka , Yoshinori Morita , Masanori Motowoka
CPC classification number: C08F10/00 , C08F10/02 , C08F210/16
Abstract: In a process for polymerizing a monomer capable of being formed, upon polymerization, into a solution having an upper cloud point of the corresponding polymer in a reaction medium being liquid under the reaction conditions, the polymerization being carried out under such conditions that the resulting polymer dissolves in the reaction medium; the improvement wherein(i) the polymerization is carried out in a polymerization zone at a temperature above the upper cloud point of said polymer solution and under conditions which enable the polymer solution to be separated into two phases,(ii) the polymerization is carried out under stirring conditions which maintain the two phases under said phase-separating conditions in a dispersed and mixed state, and(iii) the resulting polymer solution is sent to a separating zone located independently of said polymerization zone, thereby separating it into two phases in the separating zone at a temperature above the upper cloud point, and thereafter, the polymer-rich liquid phase as a lower layer is recovered while the polymer-lean liquid phase as an upper layer is recycled to the polymerization zone.
Abstract translation: 在能够形成的单体聚合的过程中，在反应介质中在反应介质中具有相应聚合物的上部浊点为液体的溶液中，在这样的条件下进行聚合，所得聚合物 溶解在反应介质中; 其改进在于（i）聚合反应在聚合反应区中在高于所述聚合物溶液的上部浊点的温度下进行，并且使聚合物溶液能够分离成两相，（ii）进行聚合 在分散和混合状态下在所述相分离条件下保持两相的搅拌条件下，和（iii）将得到的聚合物溶液送至与所述聚合区无关的分离区，从而将其分离成两相 在高于上部浊点的温度下分离区，然后回收富含聚合物的液相作为下层，而作为上层的贫聚合物液相再循环至聚合区。
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50.发明授权Olefin polymerization with phosphated silica-chromium catalyst with boron-containing cocatalyst 失效烯烃聚合与磷化二氧化硅 - 铬催化剂与含硼助催化剂
公开(公告)号：US4398004A
公开(公告)日：1983-08-09
申请号：US424793
申请日：1982-09-27
Applicant: Max P. McDaniel , Marvin M. Johnson
Inventor： Max P. McDaniel , Marvin M. Johnson
CPC classification number: C08F10/00
Abstract: A catalyst system suitable for olefin polymerization comprising a catalyst component made up of chromium on a phosphated silica-containing base and a boron-containing cocatalyst. The resulting catalyst is particularly sensitive to the effects of hydrogen as a molecular weight control agent, thus allowing the production of polymers of having a melt flow varying over a wide spectrum utilizing the same catalyst.
Abstract translation: 一种适用于烯烃聚合的催化剂体系，包括由磷化二氧化硅基底上的铬构成的催化剂组分和含硼助催化剂。 所得到的催化剂对氢作为分子量控制剂的作用特别敏感，从而允许使用相同的催化剂制备在宽谱上具有变化的熔体流动的聚合物。
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