摘要:
An enclosed non-aqueous secondary cell is herein disclosed, in which a group of electrodes comprising positive and negative electrodes allowing absorption and release of a light metal and separators are accommodated in a closed-end cell-armoring can together with a non-aqueous electrolyte and an opening of the armoring can is closed by an insulating gasket positioned around the inner periphery of the opening of the can and a closing lid fitted in and supported by the gasket and simultaneously serving as a positive or negative terminal, wherein the closing lid comprises an explosion-proof valve capable of deforming towards the direction opposite to the group of electrodes in response to an increase in the internal pressure of the cell, a terminal cap provided with vent holes and arranged at the side of the explosion-proof valve opposed to the group of electrodes and a non-reverse type switch which is positioned between the explosion-proof valve and the terminal cap and serves to shut-off the electrical connection between the terminal cap and the positive or negative electrode when the temperature of the cell is raised or the pressure in the cell is increased. The foregoing cell construction permits shutting off of the electrical connections within the cell when the temperature and/or internal pressure thereof increase.
摘要:
A silver halide color photographic material enables rapid processing, provides a high quality image and has excellent light fastness under extensive conditions, even under high humidity comprises a support, provided thereon at least three silver halide emulsion layers each containing at least one different coupler for forming a different dye by a coupling reaction with the oxidation product of an aromatic primary amine developing agent and each having a different light sensitivity, and at least one anti-color mixing layer provided between each of the emulsion layers and comprising a light-insensitive layer, wherein at least one of the above silver halide emulsion layers contains silver halide grains having a silver chloride content of 90 mole % or more and a magenta coupler represented by the following formula (I) and at least two of the anti-color mixing layers contain at least one anti-color mixing agent having a molecular weight of 350 or more and at least one high boiling organic solvent having the dielectric constant of 5.0 or more: ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituent; Z.sub.a, Z.sub.b, and Z.sub.c each represent methine, substituted methine, .dbd.N--, or --NH--; Y represents a hydrogen atom or a group capable of splitting off upon a coupling reaction with the oxidation product of a developing agent; provided that a dimer or polymer may be formed via R.sub., Y or Z.sub.a, Z.sub.b or Z.sub.c each of which is a substituted methine.
摘要:
Disclosed is a silver halide color photographic material comprising a support having thereon at least one layer containing one or more cyan couplers of formula (I): ##STR1## wherein R.sub.11 represents a branched or cyclic alkyl group, a branched or cyclic alkoxy group, a substituted aryl group, or a substituted aryloxy group; R.sub.21 represents a substituent which may optionally be substituted. R.sub.12 represents an aliphatic group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an alkylamino group, an anilino group, a heterocyclic-oxy group, or a heterocyclic-amino group; R.sub.22 and R.sub.32 each represents a substituent; r.sub.2 represents an integer of from 0 to 4; provided that when r.sub.2 is a plural number, the plurality of R.sub.32 groups may be the same or different; R.sub.13, R.sub.23 and R.sub.33 each represent a hydrogen atom or a substituent; provided that the total of Taft's substituent constant .sigma.* values of R.sub.13, R.sub.23 and R.sub.33 is 1.5 or more; R.sub.43 represents a substituent. In formulae (I), (II) and (III), X.sub.1, X.sub.2 and X.sub.3 each represents a hydrogen atom, or a group which is capable of splitting off from the formula by a coupling reaction with an oxidation product of an aromatic primary amine color developing agent; and the group of R.sub.11, R.sub.21 or X.sub.1, the group of R.sub.12, R.sub.22, R.sub.32 or X.sub.2, or the group of R.sub.13, R.sub.23, R.sub.33, R.sub.43 or X.sub.3 may be a divalent group to form a dimer or a higher polymer or to bond to a polymer chain to form a homopolymer or a copolymer. The material forms a color image with good color hue and color fastness. It is hardly fogged, and the dyes formed from the couplers hardly associate with each other in the material.
摘要翻译:公开了一种卤化银彩色照相材料,其包括其上具有至少一层含有一种或多种式(I)的青色成色剂的载体的载体:其中R 11表示(ⅰ) 支链或环状烷基,支链或环状烷氧基,取代芳基或取代芳氧基; R 21表示可任选被取代的取代基。 R 12表示脂肪族基,芳基,杂环基,烷氧基,芳氧基,烷基氨基,苯胺基,杂环氧基或杂环氨基。 R 22和R 32各自表示取代基; r2表示0〜4的整数, 条件是当r2是多个数时,多个R32基团可以相同或不同; R 13,R 23和R 33各自表示氢原子或取代基; 条件是R13,R23和R33的塔夫脱取代基常数σ*值为1.5以上; R43表示取代基。 在式(I),(II)和(III)中,X 1,X 2和X 3各自表示氢原子,或者可以通过与芳族伯胺的氧化产物的偶联反应从式分解的基团 彩色显影剂; 并且R 11,R 21或X 1,R 12,R 22,R 32或X X,或R 13,R 23,R 33,R 43或X 3的基团可以是二价基团以形成二聚体或更高级的聚合物或键合 到聚合物链以形成均聚物或共聚物。 该材料形成具有良好色调和色牢度的彩色图像。 它几乎不起雾,并且由成色剂形成的染料在材料中几乎不相互关联。
摘要:
A method of flexible photovoltaic device manufacture in which an inorganic separation layer and inorganic first protective film layer are formed on a supporting substrate. On the inorganic first protective film, a first electrode, an amorphous silicon photovoltaic layer, a second electrode, and a second protective film are formed in that order. Then the supporting substrate and the inorganic separation layer are separated. The inorganic separation layer is a material that bonds weakly with both the supporting substrate and the inorganic first protective film.
摘要:
Disclosed is a silver halide color photographic material comprising a silver halide emulsion layer on a support, wherein said layer contains a dispersion of fine oleophilic grains, which grains contain at least one nondiffusible oil-soluble cyan coupler capable of forming a substantially nondiffusible dye by coupling with the oxidation product of an aromatic primary amine developing agent and at least one coupler solvent which is immiscible with water and has no aromatic group in the molecule and which has a melting point of 100.degree. C. or lower and has a boiling point or decomposition point of 140.degree. C. or higher. As the characteristic feature of the invention, the dispersion of said fine oleophilic grains is formed by emulsifying and dispersing a mixture solution comprising at least one of the coupler, at least one of the coupler solvent and at least one water-insoluble and organic solvent-soluble homopolymer or copolymer. By the combination of the coupler, coupler solvent and polymer, the light fastness and dark fastness of the photographic material is improved. In particular, the stability of the coating composition is improved, and the color balance of the color image formed may be maintained well after being stored even under high temperature and high moisture conditions.
摘要:
A silver halide color photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, at least one layer thereof containing a yellow coupler represented by formula (I), a sparingly water-soluble epoxy compound represented by formula (II) and a water-insoluble but organic solvent-soluble homopolymer or copolymer: ##STR1## wherein R.sub.11 represents an N-arylcarbamoyl group; and Z.sub.11 represents a group capable of being released by a reaction with the oxidation product of an aromatic primary amine color developing agent; and ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents hydrogen, an aliphatic group, an aromatic group, an aliphatic oxycarbonyl group, an aromatic oxycarbonyl group or a carbamoyl group; provided that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents a group other than hydrogen; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 contain a total of 8 to 60 carbon atoms; and R.sub.1 and R.sub.2, or R.sub.1 and R.sub.3 may be linked to form a 5-membered to 7-membered ring. Because of the combination of the particular yellow coupler, epoxy resin and polymer, the storage stability of the yellow image formed in the material is excellent.
摘要:
A color photograph comprising a support having provided thereon at least one photographic layer, wherein said at least one photographic layer contains a storage stability improving compound which forms a chemically inert and substantially colorless compound by combining chemically with the oxidation product of an aromatic amine color developing agent remaining in said color photograph after color development processing.
摘要:
A pyrazoloazoleazomethine dye represented by formula (I) ##STR1## wherein, R.sub.1 represents a substituent having a Hammett's substituent constant value of at least 0.6; Za, Zb, and Zc each represents .dbd.CH--, ##STR2## (wherein R.sub.2 represents a hydrogen atom or a substituent), or .dbd.N--; when Zc=Zb is a carbon-carbon double bond, it may form a part of an aromatic ring; R.sub.3, R.sub.4, and R.sub.5 each represents a hydrogen atom or a substituent; and n represents 1 or 2; said dye may form a dimer or higher polymer by combining with each other or to a polymer through a divalent or higher valent group at R.sub.1, Za, Zb, or Zc.
摘要:
A silver halide color photosensitive material is disclosed, characterized in that a lipophilic fine grain dispersed in at least one hydrophilic colloidal layer formed on a support contains at least one compound of formula (I) and at least one compound of formula (II):R.sub.1 --SO.sub.2.M.sub.1 (I)R.sub.2 --SO.sub.3.M.sub.2 (II)wherein each of R.sub.1 and R.sub.2 represents an aliphatic group having 8 or more carbon atoms, an aromatic group having 8 or more carbon atoms or a heterocyclic group having 8 or more carbon atoms; each of M.sub.1 and M.sub.2 represents a hydrogen atom or an inorganic or organic salt-forming atom or atomic group; also M.sub.1 represents a protective group to be hydrolyzed with alkali; and sodium dodecylbenzenesulfonate is excluded from the compounds of formula (II). The combined use of the compounds of formulae (I) and (II) can effectively control the formation of stains on the processed white ground after the lapse of time without substantially lowering the maximum color density.