Non-aqueous secondary cell
    51.
    发明授权
    Non-aqueous secondary cell 失效
    无水二次电池

    公开(公告)号:US5567539A

    公开(公告)日:1996-10-22

    申请号:US445416

    申请日:1995-05-19

    摘要: An enclosed non-aqueous secondary cell is herein disclosed, in which a group of electrodes comprising positive and negative electrodes allowing absorption and release of a light metal and separators are accommodated in a closed-end cell-armoring can together with a non-aqueous electrolyte and an opening of the armoring can is closed by an insulating gasket positioned around the inner periphery of the opening of the can and a closing lid fitted in and supported by the gasket and simultaneously serving as a positive or negative terminal, wherein the closing lid comprises an explosion-proof valve capable of deforming towards the direction opposite to the group of electrodes in response to an increase in the internal pressure of the cell, a terminal cap provided with vent holes and arranged at the side of the explosion-proof valve opposed to the group of electrodes and a non-reverse type switch which is positioned between the explosion-proof valve and the terminal cap and serves to shut-off the electrical connection between the terminal cap and the positive or negative electrode when the temperature of the cell is raised or the pressure in the cell is increased. The foregoing cell construction permits shutting off of the electrical connections within the cell when the temperature and/or internal pressure thereof increase.

    摘要翻译: 本文公开了一种封闭的非水性二次电池,其中包括允许轻金属和隔板的吸收和释放的正极和负极的电极组与非水电解质一起容纳在封闭端的电池铠装罐中 并且铠装罐的开口由位于罐的开口的内周周围的绝缘垫圈和由垫圈装配并支撑并同时用作正或负端子的封闭盖封闭,其中闭合盖包括 能够响应于电池的内部压力的增加而朝向与电极组相反的方向变形的防爆阀,设置有通气孔的端子盖,并且布置在与防爆阀相对的一侧 该组电极和非反向型开关,其位于防爆阀和端子帽之间,用于关闭 f当电池的温度升高或电池中的压力增加时,端子帽和正极或负极之间的电连接。 当其温度和/或内部压力增加时,上述电池结构允许关闭电池内的电连接。

    Silver halide color photographic material
    53.
    发明授权
    Silver halide color photographic material 失效
    卤化银彩色照相材料

    公开(公告)号:US5356763A

    公开(公告)日:1994-10-18

    申请号:US24437

    申请日:1993-03-01

    CPC分类号: G03C7/3003

    摘要: A silver halide color photographic material enables rapid processing, provides a high quality image and has excellent light fastness under extensive conditions, even under high humidity comprises a support, provided thereon at least three silver halide emulsion layers each containing at least one different coupler for forming a different dye by a coupling reaction with the oxidation product of an aromatic primary amine developing agent and each having a different light sensitivity, and at least one anti-color mixing layer provided between each of the emulsion layers and comprising a light-insensitive layer, wherein at least one of the above silver halide emulsion layers contains silver halide grains having a silver chloride content of 90 mole % or more and a magenta coupler represented by the following formula (I) and at least two of the anti-color mixing layers contain at least one anti-color mixing agent having a molecular weight of 350 or more and at least one high boiling organic solvent having the dielectric constant of 5.0 or more: ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituent; Z.sub.a, Z.sub.b, and Z.sub.c each represent methine, substituted methine, .dbd.N--, or --NH--; Y represents a hydrogen atom or a group capable of splitting off upon a coupling reaction with the oxidation product of a developing agent; provided that a dimer or polymer may be formed via R.sub., Y or Z.sub.a, Z.sub.b or Z.sub.c each of which is a substituted methine.

    摘要翻译: 卤化银彩色照相材料能够快速加工,提供高质量的图像并且在广泛的条件下具有优异的耐光性,即使在高湿度下也包含一个载体,其上设置有至少三个卤化银乳剂层,每个卤化银乳剂层含有至少一个不同的成色剂 通过与芳族伯胺显影剂的氧化产物的偶联反应并且各自具有不同的光敏感性的不同的染料,以及设置在每个乳剂层之间并包含不透光层的至少一个防混色层, 其中上述卤化银乳剂层中的至少一种含有氯化银含量为90摩尔%以上的卤化银颗粒和由下式(I)表示的品红色偶联剂,并且至少两种防混色层含有 至少一种分子量为350以上的至少一种抗混色剂和至少一种高沸点有机物 介电常数为5.0以上的醇类:其中R1表示氢原子或取代基;(I) Za,Zb和Zc各自表示次甲基,取代的次甲基,= N-或-NH-; Y表示氢原子或与显影剂的氧化产物偶联反应时可分解的基团; 条件是可以经由R,Y或Za,Zb或Zc形成二聚体或聚合物,其各自为取代的次甲基。

    Silver halide color photographic material
    54.
    发明授权
    Silver halide color photographic material 失效
    卤化银彩色照相材料

    公开(公告)号:US5348847A

    公开(公告)日:1994-09-20

    申请号:US982445

    申请日:1992-11-27

    IPC分类号: C07D487/04 C09B55/00 G03C7/38

    摘要: Disclosed is a silver halide color photographic material comprising a support having thereon at least one layer containing one or more cyan couplers of formula (I): ##STR1## wherein R.sub.11 represents a branched or cyclic alkyl group, a branched or cyclic alkoxy group, a substituted aryl group, or a substituted aryloxy group; R.sub.21 represents a substituent which may optionally be substituted. R.sub.12 represents an aliphatic group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an alkylamino group, an anilino group, a heterocyclic-oxy group, or a heterocyclic-amino group; R.sub.22 and R.sub.32 each represents a substituent; r.sub.2 represents an integer of from 0 to 4; provided that when r.sub.2 is a plural number, the plurality of R.sub.32 groups may be the same or different; R.sub.13, R.sub.23 and R.sub.33 each represent a hydrogen atom or a substituent; provided that the total of Taft's substituent constant .sigma.* values of R.sub.13, R.sub.23 and R.sub.33 is 1.5 or more; R.sub.43 represents a substituent. In formulae (I), (II) and (III), X.sub.1, X.sub.2 and X.sub.3 each represents a hydrogen atom, or a group which is capable of splitting off from the formula by a coupling reaction with an oxidation product of an aromatic primary amine color developing agent; and the group of R.sub.11, R.sub.21 or X.sub.1, the group of R.sub.12, R.sub.22, R.sub.32 or X.sub.2, or the group of R.sub.13, R.sub.23, R.sub.33, R.sub.43 or X.sub.3 may be a divalent group to form a dimer or a higher polymer or to bond to a polymer chain to form a homopolymer or a copolymer. The material forms a color image with good color hue and color fastness. It is hardly fogged, and the dyes formed from the couplers hardly associate with each other in the material.

    摘要翻译: 公开了一种卤化银彩色照相材料,其包括其上具有至少一层含有一种或多种式(I)的青色成色剂的载体的载体:其中R 11表示(ⅰ) 支链或环状烷基,支链或环状烷氧基,取代芳基或取代芳氧基; R 21表示可任选被取代的取代基。 R 12表示脂肪族基,芳基,杂环基,烷氧基,芳氧基,烷基氨基,苯胺基,杂环氧基或杂环氨基。 R 22和R 32各自表示取代基; r2表示0〜4的整数, 条件是当r2是多个数时,多个R32基团可以相同或不同; R 13,R 23和R 33各自表示氢原子或取代基; 条件是R13,R23和R33的塔夫脱取代基常数σ*值为1.5以上; R43表示取代基。 在式(I),(II)和(III)中,X 1,X 2和X 3各自表示氢原子,或者可以通过与芳族伯胺的氧化产物的偶联反应从式分解的基团 彩色显影剂; 并且R 11,R 21或X 1,R 12,R 22,R 32或X X,或R 13,R 23,R 33,R 43或X 3的基团可以是二价基团以形成二聚体或更高级的聚合物或键合 到聚合物链以形成均聚物或共聚物。 该材料形成具有良好色调和色牢度的彩色图像。 它几乎不起雾,并且由成色剂形成的染料在材料中几乎不相互关联。

    Method of flexible photovoltaic device manufacture
    55.
    发明授权
    Method of flexible photovoltaic device manufacture 失效
    柔性光伏器件制造方法

    公开(公告)号:US5232860A

    公开(公告)日:1993-08-03

    申请号:US851785

    申请日:1992-03-16

    摘要: A method of flexible photovoltaic device manufacture in which an inorganic separation layer and inorganic first protective film layer are formed on a supporting substrate. On the inorganic first protective film, a first electrode, an amorphous silicon photovoltaic layer, a second electrode, and a second protective film are formed in that order. Then the supporting substrate and the inorganic separation layer are separated. The inorganic separation layer is a material that bonds weakly with both the supporting substrate and the inorganic first protective film.

    摘要翻译: 一种柔性光伏器件制造方法,其中在支撑衬底上形成无机分离层和无机第一保护膜层。 在无机第一保护膜上依次形成第一电极,非晶硅光电转换层,第二电极和第二保护膜。 然后分离支撑基板和无机分离层。 无机分离层是与支持基板和无机第一保护膜两者弱结合的材料。

    Silver halide color photographic materials
    56.
    发明授权
    Silver halide color photographic materials 失效
    卤化银彩色照相材料

    公开(公告)号:US5057408A

    公开(公告)日:1991-10-15

    申请号:US294701

    申请日:1989-01-09

    CPC分类号: G03C7/3882

    摘要: Disclosed is a silver halide color photographic material comprising a silver halide emulsion layer on a support, wherein said layer contains a dispersion of fine oleophilic grains, which grains contain at least one nondiffusible oil-soluble cyan coupler capable of forming a substantially nondiffusible dye by coupling with the oxidation product of an aromatic primary amine developing agent and at least one coupler solvent which is immiscible with water and has no aromatic group in the molecule and which has a melting point of 100.degree. C. or lower and has a boiling point or decomposition point of 140.degree. C. or higher. As the characteristic feature of the invention, the dispersion of said fine oleophilic grains is formed by emulsifying and dispersing a mixture solution comprising at least one of the coupler, at least one of the coupler solvent and at least one water-insoluble and organic solvent-soluble homopolymer or copolymer. By the combination of the coupler, coupler solvent and polymer, the light fastness and dark fastness of the photographic material is improved. In particular, the stability of the coating composition is improved, and the color balance of the color image formed may be maintained well after being stored even under high temperature and high moisture conditions.

    摘要翻译: 公开了一种卤化银彩色照相材料,其在载体上包含卤化银乳剂层,其中所述层含有亲油性细颗粒的分散体,该颗粒含有至少一种不可扩散的油溶性青色成色剂,能够通过偶联形成基本上不扩散的染料 与芳族伯胺显影剂的氧化产物和至少一种与水不混溶并且在分子中不具有芳族基团并且具有熔点为100℃或更低并且具有沸点或分解的成色剂溶剂 点在140℃以上。 作为本发明的特征,所述亲油亲油颗粒的分散体是通过乳化和分散包含至少一种成色剂,至少一种成色剂溶剂和至少一种水不溶性和有机溶剂 - 可溶性均聚物或共聚物。 通过耦合剂,成色剂溶剂和聚合物的组合,提高了照相材料的耐光牢度和牢度。 特别是改善了涂料组合物的稳定性,即使在高温高湿条件下储存后,也能够保持形成的彩色图像的色彩平衡。

    Silver halide color photographic material containing sparingly water
soluble epoxy compound and organic soluble polymer
    57.
    发明授权
    Silver halide color photographic material containing sparingly water soluble epoxy compound and organic soluble polymer 失效
    含有微溶水性环氧化合物和有机可溶性聚合物的卤化银彩色照相材料

    公开(公告)号:US5001045A

    公开(公告)日:1991-03-19

    申请号:US234872

    申请日:1988-08-22

    CPC分类号: G03C7/39268 G03C7/396

    摘要: A silver halide color photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, at least one layer thereof containing a yellow coupler represented by formula (I), a sparingly water-soluble epoxy compound represented by formula (II) and a water-insoluble but organic solvent-soluble homopolymer or copolymer: ##STR1## wherein R.sub.11 represents an N-arylcarbamoyl group; and Z.sub.11 represents a group capable of being released by a reaction with the oxidation product of an aromatic primary amine color developing agent; and ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents hydrogen, an aliphatic group, an aromatic group, an aliphatic oxycarbonyl group, an aromatic oxycarbonyl group or a carbamoyl group; provided that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents a group other than hydrogen; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 contain a total of 8 to 60 carbon atoms; and R.sub.1 and R.sub.2, or R.sub.1 and R.sub.3 may be linked to form a 5-membered to 7-membered ring. Because of the combination of the particular yellow coupler, epoxy resin and polymer, the storage stability of the yellow image formed in the material is excellent.

    Pyrazoloazoleazomethine dyes
    59.
    发明授权
    Pyrazoloazoleazomethine dyes 失效
    吡唑并唑吲嗪染料

    公开(公告)号:US4921968A

    公开(公告)日:1990-05-01

    申请号:US130489

    申请日:1987-12-09

    摘要: A pyrazoloazoleazomethine dye represented by formula (I) ##STR1## wherein, R.sub.1 represents a substituent having a Hammett's substituent constant value of at least 0.6; Za, Zb, and Zc each represents .dbd.CH--, ##STR2## (wherein R.sub.2 represents a hydrogen atom or a substituent), or .dbd.N--; when Zc=Zb is a carbon-carbon double bond, it may form a part of an aromatic ring; R.sub.3, R.sub.4, and R.sub.5 each represents a hydrogen atom or a substituent; and n represents 1 or 2; said dye may form a dimer or higher polymer by combining with each other or to a polymer through a divalent or higher valent group at R.sub.1, Za, Zb, or Zc.

    摘要翻译: 由式(I)表示的吡唑并唑甲酰胺染料其中,R1表示哈米特取代基常数值至少为0.6的取代基; Za,Zb和Zc各自表示= CH-,(其中R2表示氢原子或取代基)或= N-; 当Zc = Zb是碳 - 碳双键时,它可以形成芳环的一部分; R3,R4和R5各自表示氢原子或取代基; n表示1或2; 所述染料可以通过在R1,Za,Zb或Zc处通过二价或更高价基团彼此结合或与聚合物形成二聚体或更高级聚合物。

    Silver halide color photosensitive materials
    60.
    依法登记的发明
    Silver halide color photosensitive materials 失效
    卤化银色感光材料

    公开(公告)号:USH706H

    公开(公告)日:1989-11-07

    申请号:US237205

    申请日:1988-08-29

    CPC分类号: G03C7/39236

    摘要: A silver halide color photosensitive material is disclosed, characterized in that a lipophilic fine grain dispersed in at least one hydrophilic colloidal layer formed on a support contains at least one compound of formula (I) and at least one compound of formula (II):R.sub.1 --SO.sub.2.M.sub.1 (I)R.sub.2 --SO.sub.3.M.sub.2 (II)wherein each of R.sub.1 and R.sub.2 represents an aliphatic group having 8 or more carbon atoms, an aromatic group having 8 or more carbon atoms or a heterocyclic group having 8 or more carbon atoms; each of M.sub.1 and M.sub.2 represents a hydrogen atom or an inorganic or organic salt-forming atom or atomic group; also M.sub.1 represents a protective group to be hydrolyzed with alkali; and sodium dodecylbenzenesulfonate is excluded from the compounds of formula (II). The combined use of the compounds of formulae (I) and (II) can effectively control the formation of stains on the processed white ground after the lapse of time without substantially lowering the maximum color density.