公开(公告)号：US07011738B2

公开(公告)日：2006-03-14

申请号：US10332048

申请日：2001-06-25

申请人： Lars-Erik Bergman ,  Erik Zimmerman ,  Tomas Widenfalk ,  Bernd Busse

发明人： Lars-Erik Bergman ,  Erik Zimmerman ,  Tomas Widenfalk ,  Bernd Busse

IPC分类号： C25D5/48

CPC分类号： C25B11/04 ,  C23C18/42 ,  C25B11/00 ,  C25B11/0473

摘要： The present invention relates to a method for activation of a cathode comprising at least a cathode substrate wherein the cathode is cleaned by means of an acid, the cleaned cathode is coated with at least one electrocatalytic coating solution, drying the coated cathode until it is at least substantially dry, and thereafter contacting the cathode with a solvent redissolving precipitated electrocatalytic salts or acids formed on the cathode, originating from the electrocatalytic solution, to form dissolved electrocatalytic metal ions on the cathode surface, so that said electrocatalytic metal ions can precipitate as metals on the cathode. The invention also comprises a cathode obtainable by the method and the use of an activated cathode in an electrolytic cell for producing chlorine and alkali hydroxide.

公开(公告)号：US06811911B1

公开(公告)日：2004-11-02

申请号：US09622676

申请日：2000-10-18

申请人： Emanuel Peled ,  Tair Duvdevani ,  Avi Melman

发明人： Emanuel Peled ,  Tair Duvdevani ,  Avi Melman

IPC分类号： H01M810

CPC分类号： H01M4/0404 ,  C08J5/20 ,  C08J5/2218 ,  C25B9/10 ,  C25B11/04 ,  C25B11/0415 ,  C25B11/0452 ,  C25B13/04 ,  H01M2/164 ,  H01M4/04 ,  H01M4/0407 ,  H01M4/0409 ,  H01M4/0411 ,  H01M6/06 ,  H01M8/0289 ,  H01M8/1051 ,  H01M8/1081 ,  H01M12/06 ,  Y02P70/56

摘要： The present invention provides an ion conducting matrix comprising: (i) 5 to 60% by volume of an inorganic powder having a good aqueous electrolyte absorption capacity; (ii) 5 to 50% by volume of a polymeric binder that is chemically compatible with an aqueous electrolyte; and (iii) 10 to 90% by volume of an aqueous electrolyte, wherein the inorganic powder comprises essentially sub-micron particles. The present invention further provides a membrane being a film made of the matrix of the invention and a composite electrode comprising 10 to 70% by volume of the matrix of the invention.

摘要翻译： 本发明提供了一种离子传导性基体，其包括：（i）5〜60体积％的具有良好的水性电解质吸收能力的无机粉末; （ii）5至50体积％的与水性电解质化学相容的聚合物粘合剂; 和（iii）10至90体积％的水性电解质，其中所述无机粉末包含基本上亚微米的颗粒。 本发明还提供了由本发明的基质制成的膜和包含10至70体积％的本发明的基质的复合电极。

公开(公告)号：US06398938B2

公开(公告)日：2002-06-04

申请号：US09742537

申请日：2000-12-22

申请人： Claudia Merk ,  Günther Huber

发明人： Claudia Merk ,  Günther Huber

IPC分类号： C25B300

CPC分类号： C25B3/02 ,  C25B11/00 ,  C25B11/04

摘要： One embodiment of the present invention provides a process, which includes: electrochemically oxidizing at least one organic compound by bringing the organic compound into contact with an anode, wherein the anode includes: an electrically conductive support; and an electrically conductive, anodically polarized layer on the support; wherein the anodically polarized layer is formed in situ upon the support by precoating; and wherein the organic compound is not phosphonomethyliminodiacetic acid. Another embodiment of the present invention provides a product, produced by the above process.

摘要翻译： 本发明的一个实施方案提供了一种方法，其包括：通过使有机化合物与阳极接触来电化氧化至少一种有机化合物，其中所述阳极包括：导电载体; 并且在载体上具有导电的阳极极化层;其中所述阳极极化层通过预涂在所述载体上原位形成; 并且其中有机化合物不是膦酰甲基亚氨基二乙酸。 本发明的另一个实施方案提供了通过上述方法制备的产品。

公开(公告)号：US20010019020A1

公开(公告)日：2001-09-06

申请号：US09742537

申请日：2000-12-22

申请人： BASF AKTIENGESELLSCHAFT

发明人： Claudia Merk ,  Gunther Huber

IPC分类号： C25B003/00 ,  C25B003/02

CPC分类号： C25B3/02 ,  C25B11/00 ,  C25B11/04

摘要： One embodiment of the present invention provides a process, which includes: electrochemically oxidizing at least one organic compound by bringing the organic compound into contact with an anode, wherein the anode includes: an electrically conductive support; and an electrically conductive, anodically polarized layer on the support; wherein the anodically polarized layer is formed in situ upon the support by precoating; and wherein the organic compound is not phosphonomethyliminodiacetic acid. Another embodiment of the present invention provides a product, produced by the above process.

摘要翻译： 本发明的一个实施方案提供了一种方法，其包括：通过使有机化合物与阳极接触来电化氧化至少一种有机化合物，其中所述阳极包括：导电载体; 和在支撑体上的导电的阳极极化层; 其中所述阳极极化层通过预涂在所述载体上原位形成; 并且其中所述有机化合物不是膦酰基甲基亚氨基二乙酸。 本发明的另一个实施方案提供了通过上述方法制备的产品。

公开(公告)号：US5873988A

公开(公告)日：1999-02-23

申请号：US856237

申请日：1997-05-14

申请人： Dirk Schulze ,  Wolfgang Beyer

发明人： Dirk Schulze ,  Wolfgang Beyer

IPC分类号： C25B11/03 ,  C25B11/04 ,  C25B11/00

CPC分类号： C25B11/035 ,  C25B11/04

摘要： The invention relates to a multilayer electrode with a porous core structure produced by sintering and composed of an electrically conducting material for an electrolysis cell, especially with a solid electrolyte, in which the porous core structure contains at least two layers of spherical bodies made of metal packed densely together, said layers being formed by sintering and connected together, with the layer facing the electrolyte forming the active layer and being made as a fine layer of spherical bodies of the same or approximately the same size and the layer that covers the active layer on the back being made as a coarse layer of spherical bodies that are larger than the spherical bodies in the active layer.

摘要翻译： 本发明涉及一种具有多孔芯结构的多层电极，该多孔芯结构通过烧结制成，并由用于电解槽的导电材料，特别是固体电解质组成，其中多孔芯结构包含至少两层由金属制成的球体 密集地堆积在一起，所述层通过烧结形成并连接在一起，其中面向电解质的层形成有源层，并且被制成具有相同或大致相同尺寸的球形体的细小层和覆盖有源层的层 在背面被制成比活性层中的球形体大的球形体的粗糙层。

公开(公告)号：US5807468A

公开(公告)日：1998-09-15

申请号：US831791

申请日：1997-04-09

申请人： Takumi Sakamoto ,  Takeshi Suto ,  Takahiro Aoki ,  Nobuyuki Nishiyama ,  Akihisa Inoue ,  Hisamichi Kimura ,  Yasusi Takahagi ,  Takeshi Kamoshida ,  Kazuya Saito

发明人： Takumi Sakamoto ,  Takeshi Suto ,  Takahiro Aoki ,  Nobuyuki Nishiyama ,  Akihisa Inoue ,  Hisamichi Kimura ,  Yasusi Takahagi ,  Takeshi Kamoshida ,  Kazuya Saito

IPC分类号： C25B11/08 ,  C22C5/04 ,  C22C30/02 ,  C22C45/00 ,  C25B11/04

CPC分类号： C22C45/003 ,  C25B11/04

摘要： An electrode having an excellent corrosion resistance and long service life even in a severe corrosive environment such as in NaCl solutions for anode electrolysis in which chlorine gas or the like is produced at a high potential from the alloy surface. The electrode of the invention is provided using a precious metal-based amorphous alloy which has a good plasticity processibility and is applicable to a large-sized component. The object is implemented by provision of an electrode material for anode electrolysis which utilizes a precious metal-based amorphous alloy which satisfies the general formula NM.sub.100-a-b-c Ni.sub.a Cu.sub.b P.sub.c wherein NM comprises one or two precious metal elements selected from Pd and Pt; a, b and c being atomic percent, satisfy that 30.ltoreq.a+b.ltoreq.45,3.ltoreq.b/a.ltoreq.7, and 18.ltoreq.c.ltoreq.25, respectively; Pt is contained from 10 to 30 atom percent (at. %); and wherein a temperature width .DELTA.Tx in the supercooled liquid region (.DELTA.Tx=Tx-Tg) has a width of 70 K or more.

摘要翻译： 即使在严重的腐蚀环境中，例如在从合金表面产生高电位的氯气等的阳极电解的NaCl溶液中，也具有优异的耐腐蚀性和使用寿命长的电极。 本发明的电极使用具有良好塑性加工性的贵金属类非晶态合金，可应用于大型部件。 该目的通过提供用于阳极电解的电极材料来实现，其利用满足通式NM100-a-b-cNiaCubPc的贵金属基非晶态合金，其中NM包含一种或两种选自Pd和Pt的贵金属元素; a，b和c分别为原子百分比，分别满足30

公开(公告)号：US5796799A

公开(公告)日：1998-08-18

申请号：US548091

申请日：1995-10-25

申请人： Hiroko Kobayashi ,  Takashi Sasaki ,  Kiyoshi Hirai ,  Shinichi Yasui ,  Mamoru Nagao ,  Hiroyuki Harada

发明人： Hiroko Kobayashi ,  Takashi Sasaki ,  Kiyoshi Hirai ,  Shinichi Yasui ,  Mamoru Nagao ,  Hiroyuki Harada

IPC分类号： G21D1/00 ,  G21C19/317 ,  G21D3/08

CPC分类号： G21C17/022 ,  C25B1/10 ,  C25B11/04 ,  C25B15/02 ,  G21C19/307 ,  G21D3/08 ,  B01D2311/2684 ,  Y02E30/40 ,  Y02E60/366 ,  Y02E70/10

摘要： An apparatus for controlling dissolved oxygen concentration in primary and secondary cooling water in boiling water and pressurized water atomic reactors is disclosed. The apparatus contains an electrolytic cell having an anode chamber and a cathode chamber separated from one another by a diaphragm of a solid polymer electrolyte membrane. The diaphragm contains: (a) an ion exchange membrane and (b) a pair of multilayered electrodes chemically plated to both surfaces of the ion exchange membrane. The electrolytic cell is operatively connected to a circular route for cooling water in the reactor, and hydrogen gas generated through electrolysis of deionized water in the cathode side of the cell is introduced into the circular route for the cooling water to control the dissolved oxygen concentration of the cooling water.

摘要翻译： 公开了一种用于控制沸水和加压水原子反应堆中的一次和二次冷却水中的溶解氧浓度的装置。 该装置包含具有通过固体聚合物电解质膜的隔膜彼此分离的阳极室和阴极室的电解池。 隔膜包含：（a）离子交换膜和（b）一对化学镀在离子交换膜的两个表面上的多层电极。 电解池可操作地连接到循环路径，用于冷却反应器中的水，并且将通过电解阴极侧的去离子水产生的氢气引入冷却水的循环路径中以控制溶解氧浓度 冷却水。

公开(公告)号：US5266731A

公开(公告)日：1993-11-30

申请号：US731807

申请日：1991-07-17

申请人： William M. Ayers ,  Mary H. Dean

发明人： William M. Ayers ,  Mary H. Dean

IPC分类号： C07C209/48 ,  C25B3/04 ,  C25B11/04

CPC分类号： C07C209/48 ,  C25B11/04 ,  C25B3/04

摘要： Described are processes for producing amines from nitriles. The processes include electrocatalytic hydrogenations of nitriles in the presence of transition metal-oxide and/or transition metal-hydroxide cathodes to thereby form amines. Preferred modes of the invention provide highly advantageous processes for producing hexamethylenediamine from adiponitrile.

摘要翻译： 描述了由腈生产胺的方法。 这些方法包括在过渡金属氧化物和/或过渡金属氢氧化物阴极存在下腈的电催化氢化，从而形成胺。 本发明的优选方式提供了从己二腈生产己二胺的非常有利的方法。

公开(公告)号：US4867909A

公开(公告)日：1989-09-19

申请号：US751107

申请日：1985-07-02

申请人： Susan J. Babinec ,  Greg K. Rickle

发明人： Susan J. Babinec ,  Greg K. Rickle

IPC分类号： C25B11/04 ,  H01B1/12 ,  H01M4/90

CPC分类号： H01B1/12 ,  C25B11/04 ,  H01M4/9008

摘要： The invention is an article comprising at least partially a catalytic, metal-containing, electrically conducting coordination polymer. In addition, this invention includes a process of manufacturing the article comprising applying a mixture containing a catalytic, metal-containing, electrically conducting coordination polymer to a substrate and drying said fluid to form a coating. This invention also encompasses an electrolytic cell comprising a cell body and a cathode spaced apart from an anode, said anode comprising a catalytic, metal-containing, electrically conducting coordination polymer. Another aspect of this invention is a process for generating reduction-oxidation reaction products comprising electrolyzing a solution in the above described electrolytic cell.

摘要翻译： 本发明是至少部分地包含催化，含金属的导电配位聚合物的制品。 此外，本发明包括一种制造该制品的方法，包括将含有催化，含金属的导电配位聚合物的混合物施加到基底上并干燥所述流体以形成涂层。 本发明还包括电解槽，其包含电池体和与阳极间隔开的阴极，所述阳极包含催化的含金属的导电配位聚合物。 本发明的另一方面是一种生成还原氧化反应产物的方法，包括电解上述电解池中的溶液。

公开(公告)号：US4806212A

公开(公告)日：1989-02-21

申请号：US31849

申请日：1987-03-27

申请人： Bernhard Wessling ,  Christian Funder ,  Harald Volk ,  Olaf Siemers ,  Holger Merkle ,  Manfred Hilleberg

发明人： Bernhard Wessling ,  Christian Funder ,  Harald Volk ,  Olaf Siemers ,  Holger Merkle ,  Manfred Hilleberg

IPC分类号： C23F13/02 ,  C25B11/04 ,  E04B1/70 ,  G01N27/30 ,  C25F5/00

CPC分类号： E04B1/7007 ,  C23F13/02 ,  C25B11/04 ,  C23F2201/02

摘要： An electrode based on conductive material and macromolecular materials as the binder, which is stable under electrolysis conditions and is particularly suitable for drying masonry, comprising(A) a thermoplastic polar polymer, polycondensate or polyadduct or a mixture thereof, which is wettable by an electrolysis medium and is stable with respect to an electrochemical process taking place on the electrode, and(B) a mixture in a weight ratio of 1:4 to 4:1 of(a) conductive carbon black with a BET-surface of more than 600 m.sup.2 /g and/or an intrinsically conductive polymer and(b) carbon black with a BET-surface of less than 600 m.sup.2 /g and/or graphite and/or transition metal oxides and/or an intrinsically conductive polymer.

摘要翻译： 一种基于导电材料和大分子材料作为粘合剂的电极，其在电解条件下是稳定的并且特别适用于干燥砌筑物，其包含（A）热塑性极性聚合物，缩聚物或多元加成物或其混合物，其可通过电解 相对于在电极上发生的电化学过程是稳定的，和（B）（a）导电炭黑的重量比为1:4至4:1的混合物，BET表面积大于600 m2 / g和/或本征导电聚合物和（b）BET表面积小于600m 2 / g的炭黑和/或石墨和/或过渡金属氧化物和/或固有导电聚合物。