Thieno[3,2-b]pyridine-5(4H)-one derivative compound, preparation method thereof and use thereof

    公开(公告)号:US11306103B2

    公开(公告)日:2022-04-19

    申请号:US16768251

    申请日:2017-12-27

    Abstract: The present invention relates to a novel thieno[3,2-b]pyridine-5(4H)-one derivative compound, a preparation method thereof, and a use thereof. The novel thieno[3,2-b]pyridine-5(4H)-one derivative compound according to the present invention is synthesized via an aza-[3+3] cyclization addition reaction using BOP, wherein the compound is obtained by synthesizing a 4-arylthiophen-3-amine in which aryl groups such as 4-piperidyl-C6H4, 4-pyrrolidyl-C6H4, 4-MeOC6H4, 3,4,5-(MeO)3C6H4, C6H5, 4-C6H5C6H4, and 4-F3COC6H4 are introduced via a synthesis process by a bromination reaction, a hydrolysis reaction, a decarboxylation reaction, and a Suzuki coupling reaction of methyl 3-aminothiophene carboxylate, and by synthesizing 4-arylthiophen-3-amine and mono-methyl fumarate via a formal aza-[3+3] cyclization addition reaction using BOP and conjugation. Accordingly, novel thieno[3,2-b]pyridine-5(4H)-one derivative compounds according to the present invention have fluorescence properties with a wide range of emission wavelengths and thus may be utilized in various industrial fields such as physics, chemistry, and biomedical research.

    MULTIFUNCTIONAL RECOVERY APPARATUS OF SHORE ADHESION OILS

    公开(公告)号:US20210381183A1

    公开(公告)日:2021-12-09

    申请号:US17330164

    申请日:2021-05-25

    Abstract: This application relates to a multifunctional recovery apparatus of shore adhesion oils. The multifunctional recovery apparatus of shore adhesion oils removing and recovering oil spilling and sticking at a shore is mounted on a four-wheel vehicle. A skimmer assembly separating oil sticking to the surface of rocks at a shore, and absorbing and recovering an oil spill at the shore is installed at the front of the four-wheel vehicle. The skimmer assembly includes a rotary skimmer having a rotary roller separating oil, and a vacuum suction skimmer suctioning oil floating on a water surface. The rotary skimmer and the vacuum suction skimmer may be selectively or simultaneously used, if necessary.

    HYDRAULIC HEIGHT ADJUSTMENT DEVICE FOR INSTALLING ULTRA-HEAVY STRUCTURE

    公开(公告)号:US20190292028A1

    公开(公告)日:2019-09-26

    申请号:US16438744

    申请日:2019-06-12

    Abstract: The present invention relates to a hydraulic height adjusting device for installing a heavy-weight structure to secure stable horizontal bearing power against a horizontal load of a heavy-weight upper structure. The present invention includes a lower frame which is installed on a top surface of the carrier and is provided with a plurality of receiving portions formed in an upwardly opened shape; and a hydraulic cylinder which is disposed in and engaged to the respective receiving portions of the lower frame, the hydraulic cylinder being moved in a vertical direction to adjust the height of the upper structure, in a state in which an upper end thereof supports the upper structure. The receiving portion is provided with a support guide which is interposed between an inner wall of the receiving portion and the hydraulic cylinder to annually enclose the hydraulic cylinder and thus prevent the hydraulic cylinder from being tilted.

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