公开(公告)号：US08486596B2

公开(公告)日：2013-07-16

申请号：US12492511

申请日：2009-06-26

申请人： Masaki Watanabe ,  Hiroshi Yamashita ,  Tsuyoshi Sugimoto ,  Naohiro Watanabe ,  Shinichi Wakamatsu

发明人： Masaki Watanabe ,  Hiroshi Yamashita ,  Tsuyoshi Sugimoto ,  Naohiro Watanabe ,  Shinichi Wakamatsu

IPC分类号： G03G9/087

CPC分类号： G03G9/0806 ,  G03G9/0819 ,  G03G9/0825 ,  G03G9/0827 ,  G03G9/08711 ,  G03G9/08755 ,  G03G9/08793 ,  G03G2215/0604 ,  G03G2215/1623 ,  G03G2221/183

摘要： A toner produced by a method including dissolving or dispersing toner components comprising a colorant and at least one of a binder resin and a precursor thereof in an organic solvent to prepare a toner components liquid, dispersing the toner components liquid in an aqueous medium including a surfactant, a particulate resin A having the same polarity as the surfactant and a volume average particle diameter of from 5 to 50 nm, and a particulate resin B having a volume average particle diameter of from 10 to 500 nm to form liquid droplets, and removing the organic solvent from the liquid droplets. The particulate resin B is incompatible with the binder resin and swells in the organic solvent.

摘要翻译： 一种通过包括将包含着色剂和粘合剂树脂及其前体中的至少一种的调色剂组分溶解或分散在有机溶剂中以制备调色剂组分液体的方法制备的调色剂，将调色剂组分液体分散在包含表面活性剂的水性介质中 ，具有与表面活性剂极性相同的体积平均粒径为5〜50nm的粒状树脂A和体积平均粒径为10〜500nm的粒状树脂B形成液滴，除去 来自液滴的有机溶剂。 颗粒状树脂B与粘合剂树脂不相容并在有机溶剂中溶胀。

公开(公告)号：US08293442B2

公开(公告)日：2012-10-23

申请号：US12564595

申请日：2009-09-22

申请人： Masaki Watanabe ,  Naohito Shimota ,  Hiroshi Yamashita ,  Naohiro Watanabe ,  Tsuneyasu Nagatomo ,  Tsuyoshi Sugimoto ,  Shinichi Wakamatsu ,  Kenya Itoh ,  Mikio Yamahiro

发明人： Masaki Watanabe ,  Naohito Shimota ,  Hiroshi Yamashita ,  Naohiro Watanabe ,  Tsuneyasu Nagatomo ,  Tsuyoshi Sugimoto ,  Shinichi Wakamatsu ,  Kenya Itoh ,  Mikio Yamahiro

IPC分类号： G03G9/087

CPC分类号： G03G9/08702 ,  G03G9/0821 ,  G03G9/0827 ,  G03G9/08708 ,  G03G9/08726 ,  G03G9/08755 ,  G03G9/08773 ,  G03G9/08791 ,  G03G9/08793 ,  G03G2215/0129 ,  G03G2215/0604 ,  Y10T428/2982

摘要： Disclosed is a resin particle having a volume average particle diameter of 10 nm to 500 nm, obtained by polymerizing an addition polymerizable monomer containing a silsesquioxane (a) represented by Formula (I) or by copolymerizing the silsesquioxane (a) with an addition polymerizable monomer (b), where R1 to R7 each independently represent a group selected from the group consisting of hydrogen, alkyl having 1 to 40 carbon atoms, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl; any hydrogen in the alkyl group is optionally substituted by fluorine and any —CH2— is optionally substituted by —O—, —CH═CH—, cycloalkylene or cycloalkenylene; any hydrogen in alkylene in the arylalkyl group is optionally substituted by fluorine and any —CH2— is optionally substituted by —O— or —CH═CH—; and A1 represents an addition polymerizable functional group.

摘要翻译： 公开了通过使含有由式（I）表示的倍半硅氧烷（a）的加成聚合性单体或将倍半硅氧烷（a）与可加聚单体共聚而得到的体积平均粒径为10nm〜500nm的树脂粒子 （b），其中R 1至R 7各自独立地表示选自氢，具有1至40个碳原子的烷基，取代或未取代的芳基和取代或未取代的芳基烷基的基团; 烷基中的任何氢任选被氟取代，任何-CH 2 - 任选被-O - ， - CH = CH-，亚环烷基或环亚烯基取代; 芳烷基中亚烷基中的任何氢任选被氟取代，任何-CH 2 - 任选被-O-或-CH = CH-取代; A1表示可加成聚合官能团。

公开(公告)号：US20110076607A1

公开(公告)日：2011-03-31

申请号：US12994167

申请日：2009-05-22

申请人： Tsuyoshi Sugimoto ,  Hiroshi Yamashita ,  Naohiro Watanabe ,  Shinichi Wakamatsu ,  Masaki Watanabe ,  Satoshi Ogawa ,  Masana Shiba ,  Junichi Awamura ,  Naohito Shimota

发明人： Tsuyoshi Sugimoto ,  Hiroshi Yamashita ,  Naohiro Watanabe ,  Shinichi Wakamatsu ,  Masaki Watanabe ,  Satoshi Ogawa ,  Masana Shiba ,  Junichi Awamura ,  Naohito Shimota

IPC分类号： G03G9/00 ,  G03G15/08

CPC分类号： G03G9/08782 ,  G03G9/0806 ,  G03G9/08755 ,  G03G9/08795 ,  G03G9/08797

摘要： A toner including at least one polyester resin serving as a binder resin, a colorant, a releasing agent, and a fixing aid, wherein the fixing aid includes a fatty acid amide-based compound, and the fatty acid amide-based compound is at least one of a fatty acid amide compound having a mono- or higher valent amide bond and a fatty acid amide-based compound having a mono- or higher valent amino group or a hydroxyl group.

摘要翻译： 包含至少一种用作粘合剂树脂的聚酯树脂，着色剂，脱模剂和固定助剂的调色剂，其中所述固定助剂包括脂肪酸酰胺类化合物，所述脂肪酸酰胺类化合物至少为 具有一价或多价酰胺键的脂肪酸酰胺化合物和具有一价以上的氨基或羟基的脂肪酸酰胺系化合物之一。

公开(公告)号：US20100075243A1

公开(公告)日：2010-03-25

申请号：US12564395

申请日：2009-09-22

申请人： Naohito SHIMOTA ,  Naohiro Watanabe ,  Hiroshi Yamashita ,  Tsuyoshi Sugimoto ,  Masaki Watanabe ,  Satoshi Kojima ,  Shinichi Wakamatsu ,  Tsuneyasu Nagatomo

发明人： Naohito SHIMOTA ,  Naohiro Watanabe ,  Hiroshi Yamashita ,  Tsuyoshi Sugimoto ,  Masaki Watanabe ,  Satoshi Kojima ,  Shinichi Wakamatsu ,  Tsuneyasu Nagatomo

IPC分类号： G03G13/20 ,  G03G9/087

CPC分类号： G03G9/0804 ,  G03G9/0819 ,  G03G9/0821 ,  G03G9/08755 ,  G03G9/08782 ,  G03G2215/0129 ,  G03G2215/0174

摘要： A toner for electrophotography, including a release agent; a binder resin; a colorant; and an external additive, wherein the binder resin is a polyester resin, and wherein the toner has a loss on heat not greater than 0.40% by weight at 165° C. and a difference between a loss on heat at 200° C. and the loss on heat at 165° C. not greater than 0.50% by weight, and includes a n-paraffin in an amount not less than 3% by weight.

摘要翻译： 用于电子照相的调色剂，包括脱模剂; 粘合剂树脂; 着色剂 和外部添加剂，其中所述粘合剂树脂是聚酯树脂，并且其中所述调色剂在165℃下的热损失不大于0.40重量％，并且在200℃下的热损失与 在165℃下的热损失不大于0.50重量％，并且包括不小于3重量％的正链烷烃。

公开(公告)号：US20090233204A1

公开(公告)日：2009-09-17

申请号：US12403569

申请日：2009-03-13

申请人： Naohiro WATANABE ,  Hiroshi Yamashita ,  Shinichi Wakamatsu ,  Tsuyoshi Sugimoto

发明人： Naohiro WATANABE ,  Hiroshi Yamashita ,  Shinichi Wakamatsu ,  Tsuyoshi Sugimoto

IPC分类号： G03G9/08

CPC分类号： G03G9/08755 ,  G03G9/0804 ,  G03G9/0808 ,  G03G9/0819 ,  G03G9/0825 ,  G03G9/08795 ,  G03G9/08797

摘要： Provided is a toner for image formation, granulated by dispersing, emulsifying, or both dispersing and emulsifying an oil phase containing toner constituting materials in an aqueous medium. The toner constituting materials contain a binder resin, a colorant and a pigment dispersant which is a polyester derivative having an acid value of 28 to 50 mgKOH/g and an amine value of 1 to 50 mgKOH/g, and satisfy the following Expressions 1 and 2, where Expression 1 represents a mass ratio, α is a glass transition temperature of the binder resin, and β is a glass transition temperature of a mixture of the binder resin and the pigment dispersant in the ratio of Expression 1. Binder resin:Pigment dispersant=100:5  Expression 1 0° C.≦α−β≦10° C.  Expression 2

摘要翻译： 本发明提供一种用于成像的调色剂，通过分散，乳化或分散和乳化含有调色剂构成材料的油相在水性介质中造粒。 调色剂构成材料含有粘合剂树脂，着色剂和颜料分散剂，它是酸值为28至50mgKOH / g，胺值为1至50mgKOH / g的聚酯衍生物，并满足下列表达式1和 2，其中表达式1表示质量比，α是粘合剂树脂的玻璃化转变温度，β是粘合剂树脂和颜料分散剂的混合物的玻璃化转变温度。 line-formula description =“In-line Formulas”end =“lead”？>粘合剂树脂：颜料分散剂= 100：5表达式1 <？in-line-formula description =“In-line Formulas”end =“tail”？ > <？in-line-formula description =“In-line Formulas”end =“lead”？> 0°C <= alpha-beta <= 10°C表达式2 <？in-line-formula description = 在线公式“end =”tail“？>

公开(公告)号：US08932788B2

公开(公告)日：2015-01-13

申请号：US12245973

申请日：2008-10-06

申请人： Shinichi Wakamatsu ,  Hiroshi Yamashita ,  Naohiro Watanabe ,  Tsuyoshi Sugimoto

发明人： Shinichi Wakamatsu ,  Hiroshi Yamashita ,  Naohiro Watanabe ,  Tsuyoshi Sugimoto

IPC分类号： G03G9/09 ,  G03G9/08 ,  G03G9/087

CPC分类号： G03G9/0819 ,  G03G9/0804 ,  G03G9/0806 ,  G03G9/0821 ,  G03G9/0823 ,  G03G9/08726 ,  G03G9/08755 ,  G03G9/08764 ,  G03G9/08793

摘要： The present invention provides a toner containing at least a binder resin and a pigment, wherein the amount of the pigment in the toner is 3.0% by mass to 8.5% by mass, the volume average particle diameter of the toner is 2.0 μm to 6.0 μm, and a monochrome image, which has been fixed on a recording medium so that the amount of the toner adhered onto the recording medium is 0.25 mg/cm2, has a reflection density of 1.2 to 2.5.

摘要翻译： 本发明提供一种含有至少粘合剂树脂和颜料的调色剂，其中调色剂中颜料的量为3.0质量％至8.5质量％，调色剂的体积平均粒径为2.0μm至6.0μm 和已经固定在记录介质上的单色图像，使得粘附到记录介质上的调色剂的量为0.25mg / cm 2，反射密度为1.2至2.5。

公开(公告)号：US08178268B2

公开(公告)日：2012-05-15

申请号：US12567831

申请日：2009-09-28

申请人： Naohiro Watanabe ,  Shinichi Wakamatsu ,  Naohito Shimota ,  Hiroshi Yamashita ,  Tsuyoshi Sugimoto ,  Masaki Watanabe ,  Tsuneyasu Nagatomo

发明人： Naohiro Watanabe ,  Shinichi Wakamatsu ,  Naohito Shimota ,  Hiroshi Yamashita ,  Tsuyoshi Sugimoto ,  Masaki Watanabe ,  Tsuneyasu Nagatomo

IPC分类号： G03G9/00

CPC分类号： G03G9/0804 ,  G03G9/0819 ,  G03G9/0827 ,  G03G9/08755 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/092 ,  G03G9/0924

摘要： A magenta toner, produced by a method including suspending an oily liquid comprising a binder resin and a colorant in an aqueous medium, wherein the colorant comprises a naphthol pigment and a quinacridone pigment, and the quinacridone pigment comprises a pigment having a specific formula.

摘要翻译： 通过包括将包含粘合剂树脂和着色剂的油性液体悬浮在水性介质中的方法制造的品红色调色剂，其中着色剂包括萘酚颜料和喹吖啶酮颜料，并且所述喹吖啶酮颜料包含具有特定式的颜料。

公开(公告)号：US08163455B2

公开(公告)日：2012-04-24

申请号：US12403569

申请日：2009-03-13

申请人： Naohiro Watanabe ,  Hiroshi Yamashita ,  Shinichi Wakamatsu ,  Tsuyoshi Sugimoto

发明人： Naohiro Watanabe ,  Hiroshi Yamashita ,  Shinichi Wakamatsu ,  Tsuyoshi Sugimoto

IPC分类号： G03G9/00

CPC分类号： G03G9/08755 ,  G03G9/0804 ,  G03G9/0808 ,  G03G9/0819 ,  G03G9/0825 ,  G03G9/08795 ,  G03G9/08797

摘要： Provided is a toner for image formation, granulated by dispersing, emulsifying, or both dispersing and emulsifying an oil phase containing toner constituting materials in an aqueous medium. The toner constituting materials contain a binder resin, a colorant and a pigment dispersant which is a polyester derivative having an acid value of 28 to 50 mgKOH/g and an amine value of 1 to 50 mgKOH/g, and satisfy the following Expressions 1 and 2, where Expression 1 represents a mass ratio, α is a glass transition temperature of the binder resin, and β is a glass transition temperature of a mixture of the binder resin and the pigment dispersant in the ratio of Expression 1. Binder resin:Pigment dispersant=100:5  Expression 1 0° C.≦α−β≦10° C.  Expression 2

摘要翻译： 本发明提供一种用于成像的调色剂，通过分散，乳化或分散和乳化含有调色剂构成材料的油相在水性介质中造粒。 调色剂构成材料含有粘合剂树脂，着色剂和颜料分散剂，它是酸值为28至50mgKOH / g，胺值为1至50mgKOH / g的聚酯衍生物，并满足下列表达式1和 2，其中，表达式1表示质量比，α是粘合剂树脂的玻璃化转变温度，＆lt; bgr; 粘合剂树脂和颜料分散剂的混合物的玻璃化转变温度是表达式1的比例。粘合剂树脂：颜料分散剂= 100:5表达式0℃0℃＆lt;α-＆bgr＆ 表达式2

公开(公告)号：US20100035170A1

公开(公告)日：2010-02-11

申请号：US12509923

申请日：2009-07-27

申请人： Tsuyoshi Sugimoto ,  Naohito Shimota ,  Hiroshi Yamashita ,  Naohiro Watanabe ,  Shinichi Wakamatsu ,  Masaki Watanabe

发明人： Tsuyoshi Sugimoto ,  Naohito Shimota ,  Hiroshi Yamashita ,  Naohiro Watanabe ,  Shinichi Wakamatsu ,  Masaki Watanabe

IPC分类号： G03G13/20 ,  G03G9/08 ,  G03G9/087

CPC分类号： G03G9/08755 ,  G03G9/0804 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/09733 ,  G03G9/09791

摘要： A toner according to the present invention contains at least a polyester resin as a binder resin, a colorant, a releasing agent, a fixing-assisting component, and a fatty acid, wherein the fixing-assisting component has a melting point of 60° C. to 120° C. and contains at least one of an esterified compound obtained by esterification of the fatty acid and an amide compound obtained by amidation of the fatty acid.

摘要翻译： 根据本发明的调色剂至少含有作为粘合剂树脂的聚酯树脂，着色剂，脱模剂，定影助剂和脂肪酸，其中定影助剂的熔点为60℃ 至120℃，并且含有通过酯化脂肪酸获得的酯化化合物和通过脂肪酸酰胺化获得的酰胺化合物中的至少一种。

公开(公告)号：US07455942B2

公开(公告)日：2008-11-25

申请号：US11227566

申请日：2005-09-16

申请人： Tsuneyasu Nagatomo ,  Akihiro Kotsugai ,  Hiroshi Yamashita ,  Masayuki Ishii ,  Hiroto Higuchi ,  Osamu Uchinokura ,  Satoshi Mochizuki ,  Fumihiro Sasaki ,  Hisashi Nakajima ,  Hideki Sugiura ,  Yasuo Asahina ,  Shinya Nakayama ,  Koichi Sakata ,  Tomoyuki Ichikawa ,  Takuya Saito ,  Sonoh Matsuoka

发明人： Tsuneyasu Nagatomo ,  Akihiro Kotsugai ,  Hiroshi Yamashita ,  Masayuki Ishii ,  Hiroto Higuchi ,  Osamu Uchinokura ,  Satoshi Mochizuki ,  Fumihiro Sasaki ,  Hisashi Nakajima ,  Hideki Sugiura ,  Yasuo Asahina ,  Shinya Nakayama ,  Koichi Sakata ,  Tomoyuki Ichikawa ,  Takuya Saito ,  Sonoh Matsuoka

IPC分类号： G03G9/08

CPC分类号： G03G9/097

摘要： It is an object of the present invention to provide a toner that can sustain favorable transferability and cleaning ability for prolonged periods; prevent photoconductor filming; exhibit no variation in image nonuniformity or external additive immersion induced by developer agitation at the time of use; excels in stability with flowability and charge stability over prolonged periods. Therefore, provided is the toner of which the quantity of aggregate of residual external additives found on the sieve of 635-mesh and 452 cm2 of mesh area, after 0.2 g of the toner on the sieve is blasted with air at a blow pressure of 0.2 MPa from 160 mm above the sieve while being air-suctioned at a suction force of 5 mmHg, and then air-suctioned at a suction force of 20 mmHg, is 4,500 or less and 5 or more.

摘要翻译： 本发明的一个目的是提供一种能够延长期间的转印性和清洁能力的调色剂。 防止感光膜成膜; 在使用时不显示由显影剂搅拌引起的图像不均匀性或外部添加剂浸渍的变化; 在长时间内具有流动性和电荷稳定性的稳定性。 因此，提供了在筛上的0.2g调色剂之后，在筛网上存在635目筛和452cm 2网眼面积的残余外部添加剂骨料数量的调色剂 在空气中以160mm的筛子空气吹压压力为0.2MPa，同时以5mmHg的抽吸力空气抽吸，然后以20mmHg的抽吸力空气抽吸为4,500以下且5以上。