Abstract:
The cathodic protection system of a concrete structure (22) uses sacrificial anodes such as zinc, aluminum and alloys thereof embedded in mortar. A humectant is employed to impart high ionic conductivity to the mortar in which the anode is encapsulated. Lithium nitrate and lithium bromide and combinations thereof are preferred as the humectant. The anode (10) is surrounded by a compressive, conductive matrix (12) incorporating a void volume between 15% and 50% to accommodate the sacrificial corrosion products of the anode. A void space of at least 5% of the total volume of the anode (12) may be provided opposite to the active face of the anode. Synthetic fibers such as polypropylene, polyethylene, cellulose, nylon and fiberglass have been found to be useful for forming the matrix. A tie wire is used to electrically connect the anode to the reinforcing bar.
Abstract:
Re-usable, energy-efficient apparatus for the restoration of corrosion-damaged reinforced concrete and a method for controlling the same. The apparatus includes a combination electrode device in a sandwich construction that includes a dimensionally stable electrode, a reusable electrolyte reservoir, an ion exchanger element, a reference electrode, a power-switching device for anodic regulation, and a measuring system for determining the capacity of the ion exchanger element to take up ions. Use of this combination electrode device prevents the formation of active chlorine during extraction of chlorine from reinforced concrete.
Abstract:
A method is described for the electrochemical protection of reinforcement in concrete in harsh environments, for instance in contact with, or in close proximity to, seawater. On concrete, a composition comprising graphite dispersed in a curable mineralic binder in the form of water glass or another water-soluble inorganic silicate, a dispersion agent, optionally together with conventional additives is applied. The application is performed by spraying or brushing. An impregnation is optionally performed, either concurrent with the application of the composition or thereafter. If necessary a post treatment is performed. Further, the use of the composition for electromechanical protection or reinforcement in concrete in connection with, for instance, quay constructions, bridges, bridge piers and similar constructions is described.
Abstract:
Cathodic protection of an existing concrete structure, including a steel member at least partly buried, such as steel rebar, in the concrete structure, is provided by embedding anodes into a fresh concrete layer applied over an excavated patch and/or as a covering overlay. The anodes are embedded at spaced positions or as an array in the layer and connected to the rebar. A corrosion inhibitor is added into the fresh concrete at least at the interface and more preferably in admixture with the fresh concrete which acts to reduce the flow of ionic current to the steel or between the anode member and the steel in the fresh covering material without significantly increasing the resistivity of the fresh covering material and without inhibiting the ionic current between the anode member and the fresh covering material. In this way the current to the steel in the existing concrete is maximized to maximize the cathodic protection to the existing steel which is the primary target.
Abstract:
A semiconductor system is provided that uses semiconductive organic polymers, electronics and semiconductor technology to provide a wide array of semiconductor components and a system of preventing corrosion of a surface of a metal structure in contact with a corrosive environment involving: (a) a semiconductive organic polymer coating in conductive contact with at least part of the surface; and (b) an electronic filter for filtering corrosive noise and a method of preventing corrosion using the system.
Abstract:
Coating compositions and methods of their use are described herein for the reduction of corrosion in imbedded metal structures. The coatings are applied as liquids to an external surface of a substrate in which the metal structures are imbedded. The coatings are subsequently allowed to dry. The liquid applied coatings provide galvanic protection to the imbedded metal structures. Continued protection can be maintained with periodic reapplication of the coating compositions, as necessary, to maintain electrical continuity. Because the coatings may be applied using methods similar to standard paints, and because the coatings are applied to external surfaces of the substrates in which the metal structures are imbedded, the corresponding corrosion protection may be easily maintained. The coating compositions are particularly useful in the protection of metal-reinforced concrete.
Abstract:
The invention provides a reinforced concrete having improved corrosion resistance in which the content of voids in the concrete at the surface of the steel reinforcement is below 0.8%, preferably below 0.5%, more preferably below 0.2% by area of steel and in which there is a layer of solid alkali, preferably at least one micron in thickness on the steel surface. The reinforced concrete preferably has a chloride threshold level of at least 0.5% preferably at least 0.8% by weight of the cement. The invention also provides a process for reducing corrosion of steel reinforcement in concrete which comprises forming a reinforced concrete in which the voids at the steel surface are below 0.5% by volume and in which there is a layer of solid alkali on the steel surface the layer being at least 1 micron in thickness and covering at least 20% of the steel surface.
Abstract:
A steel-reinforced structure supplied with an aqueous solution of an inhibitor for the strucutre, is further protected against deterioration when an impressed cathodic current is applied; preferably the structure is continuously bathed in the inhibitor solution; flow of the first impressed current is maintained until flow is relatively constant at a level at least one-half the level at which the first impressed current was initiated. The concentration of ions is sensed by measurement of the current flow while maintaining a chosen voltage. The inhibitor solution may be used in conjunction with an electroosmotic current to drive ions into the concrete and towards the steel; this may be done prior to applying the cathodic impressed current, or concurrently therewith by providing secondary electrodes. Program controller means in the power station switches from one mode of delivery to another when current usage, measured by current density, is deemd to have become uneconomical.
Abstract:
There is described a method of cathodic protection, electrochemical chloride extraction and realkalisation in reinforced concrete or similar materials, and also reinforcement and crack prevention in concrete (1), comprising the impressing of a direct voltage between the reinforcement in the concrete (1) and a conductive device which is brought into contact with the surface of the concrete (1), and wherein the crack preventing effect is obtained by embedding the device in fresh concrete. The method is characterised in that as conductive device/current distributors there is used a mat (3) of optionally coated, conductive carbon fibers produced by blowing, pressing, weaving or knitting so that the fibers lie in almost every direction, and wherein the fibers are of different thickness, wherein the mat further comprises electric conductors (4) in the form of bands or wires of conductive material which are placed over or under the mat (3) or are incorporated therein.
Abstract:
A concrete structure is reinforced with steel rebars coated with essentially pure aluminum in the range from about 0.25 mm to 2 mm thick upon which aluminum coating is an aluminum oxide layer in the range from 0.1 &mgr;m to 100 &mgr;m thick. This layer of aluminum oxide and/or hydrated aluminum oxide is referred to as a combined aluminum oxide layer, and it is in direct contact with the concrete. The Al-coated rebars may be protected in a galvanic circuit using magnesium or other metal baser than aluminum as a sacrificial anode, but more preferably the rebars are cathodically protected with an impressed cathodic current the current density of which is derived by sensing the corrosion potential at a sensing member of essentially pure aluminum embedded in the concrete, or in concrete outside a zone immediately surrounding the rebars, measuring the corrosion potential at the sensing member relative to a reference electrode until the value stabilizes at a measured stable potential; then providing an impressed current at a potential in the range from about 150 mV to less than 300 mV lower than the corrosion potential of the sensing member.