公开(公告)号：US08754187B2

公开(公告)日：2014-06-17

申请号：US13915046

申请日：2013-06-11

申请人： Corning Incorporated

发明人： Mingqian He ,  Jianguo Wang

IPC分类号： C08G73/10 ,  C08G73/06 ,  C08G73/00

CPC分类号： G02B1/04 ,  C07D207/416 ,  C07D307/68 ,  G02F1/0018 ,  G02F1/3611 ,  G02F1/3614 ,  G02F1/3615

摘要： The present invention relates generally to mercaptofunctional high μβ EO chromophores and EO polymers, and particularly to mercaptofunctional high μβ EO chromophores and EO polymers useful for making electro-optical devices and systems. Mercaptofunctional high μβ EO chromophores are covalently bonded to poly(imido sulfide) polymers producing high Tg, low optical loss, covalently bonded, high μβ EO chromophore containing polymers. Methods of synthesizing these EO materials using mild polymerization conditions are also described.

摘要翻译： 本发明一般涉及巯基官能团高μ＆bgr; EO发色团和EO聚合物，特别是巯基官能团高μ＆bgr; EO发色团和EO聚合物可用于制造电光器件和系统。 巯基功能高μ＆bgr; EO发色团与聚（亚氨基硫醚）聚合物共价键合，产生高Tg，低光损耗，共价键合，高μ＆bgr; 含EO发色团的聚合物。 还描述了使用温和聚合条件合成这些EO材料的方法。

公开(公告)号：US08575354B1

公开(公告)日：2013-11-05

申请号：US13920502

申请日：2013-06-18

申请人： Corning Incorporated

发明人： Mingqian He ,  Thomas Mark Leslie ,  Feixia Zhang

IPC分类号： C07D263/08 ,  C07D495/22

CPC分类号： H01L51/0068 ,  C07D495/04 ,  C07D495/14 ,  C07D495/22 ,  C07F7/2208 ,  C08G61/123 ,  C08G61/126 ,  C08G2261/3243 ,  C08G2261/364 ,  C09K19/3491 ,  C09K19/40 ,  Y02P20/55

摘要： Disclosed are compounds having one of the following formulae: wherein X is an aromatic nucleophilic substitution leaving group; R1 is hydrogen, an alkyl group, or an aryl group; and Q1 is a carboxyl protecting group or an aldehyde protecting group. Also disclosed are fused thiophenes that can be prepared using these compounds, as well as stannylthio-containing thiophene, thienothiophene, and dithienothiophene compounds that can be used to prepare fused thiophenes. Methods for making and using the aforementioned compounds, fused thiophenes, and stannylthio-containing thiophene, thienothiophene, and dithienothiophene compounds are also disclosed.

摘要翻译： 公开了具有下式之一的化合物：其中X是芳族亲核取代基离去基团; R1是氢，烷基或芳基; 并且Q1是羧基保护基或醛保护基。 还公开了可以使用这些化合物制备的稠合噻吩，以及可用于制备稠合噻吩的含有硫代硫基的噻吩，噻吩并噻吩和二噻吩并噻吩化合物。 还公开了制备和使用上述化合物，熔融噻吩和含有甲锡烷基的噻吩，噻吩并噻吩和二噻吩并噻吩化合物的方法。