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    Means and method for dyeing keratin fibres
    73.
    发明申请
    Means and method for dyeing keratin fibres 失效
    染色角蛋白纤维的方法和方法

    公开(公告)号：US20060070190A1

    公开(公告)日：2006-04-06

    申请号：US10529979

    申请日：2004-01-30

    申请人： Cécile Pasquier ,  Caroline Kiener ,  Hans-Juergen Braun

    发明人： Cécile Pasquier ,  Caroline Kiener ,  Hans-Juergen Braun

    IPC分类号： A61K8/00 ,  A61Q5/10

    CPC分类号： A61K8/49 ,  A61Q5/10

    摘要： The object of the present patent application is an agent for coloring keratin fibers based on oxidative dye precursors and containing (a) at least one hydrazone derivative of formula (I) or a physiologically compatible salt thereof, (b) at least one coupler or a physiologically compatible salt thereof, and (c) a persulfate salt as oxidant; a multicomponent kit and a method for coloring keratin fibers by use of said agent.

    摘要翻译： 本专利申请的目的是基于氧化染料前体着色角蛋白纤维的试剂，并含有（a）至少一种式（I）的腙衍生物或其生理上相容的盐，（b）至少一种成色剂或 其生理上相容的盐，和（c）过硫酸盐作为氧化剂; 多组分试剂盒和通过使用所述试剂对角蛋白纤维着色的方法。

    Agent for dyeing fibers comprising an indoline/indolium derivative
    74.
    发明授权
    Agent for dyeing fibers comprising an indoline/indolium derivative 有权
    用于染色包含二氢吲哚/吲哚衍生物的纤维的试剂

    公开(公告)号：US06652601B2

    公开(公告)日：2003-11-25

    申请号：US09959112

    申请日：2001-10-17

    申请人： Guido Sauter ,  Hans-Juergen Braun ,  Nadia Reichlin

    发明人： Guido Sauter ,  Hans-Juergen Braun ,  Nadia Reichlin

    IPC分类号： A61K713

    CPC分类号： A61Q5/10 ,  A61K8/492 ,  A61K2800/88 ,  Y10S8/917 ,  Y10S8/918

    摘要： The object of the present invention is an agent for dyeing fibers obtained by mixing two components and characterized in that one component (component A2) contains at least one carbonyl compound and the other component (component A1) contains at least one indoline derivative of formula (I) or a 3H-indoline derivative of formula (Ia) as well as a multicomponent kit for dyeing and later decolorizing fibers, said kit containing both an agent according to the invention for producing a coloration on the fiber and an agent for the reductive removal of said coloration.

    摘要翻译： 本发明的目的是将两种成分混合而得到的纤维染色剂，其特征在于，一种成分（A2成分）含有至少一种羰基化合物，另一种成分（成分A1）含有至少一种式 I）或式（Ia）的3H-二氢吲哚衍生物以及用于染色和随后脱色纤维的多组分试剂盒，所述试剂盒包含根据本发明的用于在纤维上产生着色的试剂和用于还原性去除剂 的着色。

    Cationic pyrrolo-pyrrol-derivatives, method for producing them and colorants for keratin fibers, containing these compounds
    75.
    发明授权
    Cationic pyrrolo-pyrrol-derivatives, method for producing them and colorants for keratin fibers, containing these compounds 有权
    阳离子吡咯 - 吡咯衍生物，其制备方法和含有这些化合物的角蛋白纤维着色剂

    公开(公告)号：US06570019B2

    公开(公告)日：2003-05-27

    申请号：US09958565

    申请日：2001-10-10

    申请人： Cécile Pasquier ,  Patrick Wyss ,  Hans-Juergen Braun

    发明人： Cécile Pasquier ,  Patrick Wyss ,  Hans-Juergen Braun

    IPC分类号： C07D48704

    CPC分类号： A61Q5/065 ,  A61K8/492 ,  C07D487/04 ,  C09B57/004

    摘要： The object of the present invention are diketopyrrolopyrroles of the general formula (I) wherein, independently of one another, Q1 and Q2 represent an optionally substituted, aromatic, isocyclic or heterocyclic group with 5 to 14 atoms in the ring, the heterocyclic group containing at least one oxygen, nitrogen or sulfur atom, and the R1 and R2 groups, independently of one another represent hydrogen or a Y—B+A− group, with the proviso that at least one of the R1 and R2 groups is not hydrogen; B+ is an aromatic, aliphatic, alicyclic, aromatic heterocyclic or non-aromatic heterocyclic, quaternary ammonium group or a quaternary phosphonium group; Y is an optionally substituted linear or branched C1 to C6 alkylene group and A− is an anion; a method for their synthesis as well as agents, containing compounds of formula (I), for dyeing keratin fibers.

    摘要翻译： 本发明的目的是通式（I）的二酮吡咯并吡咯，其中彼此独立地是Q1和Q2表示在环中具有5至14个原子的任选取代的，芳族的，环或杂环基，杂环基含有 至少一个氧，氮或硫原子，并且R 1和R 2基团彼此独立地表示氢或Y-B + A-基团，条件是R 1和R 2基团中的至少一个不是氢; B +是芳族，脂族，脂环族，芳族杂环或非芳族杂环，季铵基或季鏻基; Y是任选取代的直链或支链C1至C6亚烷基，A-是阴离子; 它们的合成方法以及包含用于染色角蛋白纤维的式（I）化合物的试剂。

    Oxidative hair dye precursor compositions containing 4-5-diaminopyrazole, 5-amino-2-methylphenol and m-phenylenediamine compounds and method of dyeing hair
    76.
    发明授权
    Oxidative hair dye precursor compositions containing 4-5-diaminopyrazole, 5-amino-2-methylphenol and m-phenylenediamine compounds and method of dyeing hair 有权
    含有4-5-二氨基吡唑，5-氨基-2-甲基苯酚和间苯二胺化合物的氧化染发前体组合物和染发方法

    公开(公告)号：US06554871B2

    公开(公告)日：2003-04-29

    申请号：US09788945

    申请日：2001-02-20

    申请人： Hans-Juergen Braun

    发明人： Hans-Juergen Braun

    IPC分类号： A61K713

    CPC分类号： C07D231/38

    摘要： The oxidation dye precursor-containing composition for oxidative dyeing of hair, includes from 0.1 to 10% by weight of a combination of at least one 4,5-diaminopyrazole compound selected from the group consisting of 4,5-diamino-1-methyl-1H-pyrazole, 4,5-diamino-1-ethyl-1H-pyrazole, 4,5-diamino-1-isopropyl-1H-pyrazole, 4,5-diamino-1-(2′-hydroxyethyl)-1H-pyrazole, 4,5-diamino-1-benzyl-1H-pyrazole and 4,5-diamino-1-(4′-methylbenzyl)-1H-pyrazole; at least one 5-amino-2-methylphenol compound selected from the group consisting of 5-amino-2-methylphenol, 5-[(2′-hydroxyethyl)amino]-2-methylphenol and 5-methyl-amino-2-methyl-phenol; and at least one m-phenylenediamine compound selected from the group consisting of m-phenylenediamine, 2,4-diamino-1-(2′-hydroxyethoxy)benzene, 2,4-diamino-1-(2′,3′-dihydroxypropoxy)benzene, 1,3-bis-(2′,4′-diaminophenoxy)propane, 2-amino-4-[(2′-hydroxyethyl)amino]anisole and 1,5-bis-(2′-hydroxyethoxy)-2,4-diaminobenzene. The composition is advantageously mixed with an oxidant to form a ready-to-apply hair dyeing mixture for dyeing hair.

    摘要翻译： 含氧化染料前体的头发氧化染色组合物包括0.1至10重量％的至少一种4,5-二氨基吡唑化合物的组合，所述组合物选自4,5-二氨基-1-甲基 - 1H-吡唑，4,5-二氨基-1-乙基-1H-吡唑，4,5-二氨基-1-异丙基-1H-吡唑，4,5-二氨基-1-（2'-羟乙基）-1H-吡唑 ，4,5-二氨基-1-苄基-1H-吡唑和4,5-二氨基-1-（4'-甲基苄基）-1H-吡唑; 选自5-氨基-2-甲基苯酚，5 - [（2'-羟乙基）氨基] -2-甲基苯酚和5-甲基 - 氨基-2-甲基的至少一种5-氨基-2-甲基苯酚化合物 -苯酚; 和至少一种选自间苯二胺，2,4-二氨基-1-（2'-羟基乙氧基）苯，2,4-二氨基-1-（2'，3'-二羟基丙氧基） ）苯，1,3-双 - （2'，4'-二氨基苯氧基）丙烷，2-氨基-4 - [（2'-羟乙基）氨基]苯甲醚和1,5-双 - （2'-羟基乙氧基） 2,4-二氨基苯。 该组合物有利地与氧化剂混合以形成用于染色头发的即用型染发混合物。

    Dye compositions and methods of dyeing keratin fibers
    77.
    发明授权
    Dye compositions and methods of dyeing keratin fibers 有权
    染色组合物和染色角蛋白纤维的方法

    公开(公告)号：US06379400B1

    公开(公告)日：2002-04-30

    申请号：US09581367

    申请日：2000-06-12

    申请人： Hans-Juergen Braun ,  Pascal André Semadeni

    发明人： Hans-Juergen Braun ,  Pascal André Semadeni

    IPC分类号： A61K713

    CPC分类号： A61K8/418 ,  A61Q5/065 ,  A61Q5/10

    摘要： The dye composition has a pH of 3 to 12 and contains water, alcohols and/or mixtures thereof as a solvent; from 0.01 to 10 percent by weight of at least one dye compound of formula (I), wherein R1 represents hydrogen or a methyl group and Y is an amino group of the formula —NHR2, and R2 is either a cyclopropyl group, a methoxyethyl group or a methoxypropyl group; OR wherein R1 represents hydrogen or a linear or branched alkyl group with 1 to 4 carbon atoms and Y represents a heterocyclic ring of formula (II): wherein X is a nitrogen atom or an oxygen atom and m is 1, 2 or 3 and n is 0 or 1; and from 0.5 to 30 percent by weight of at least one anionic, cationic, amphoteric and nonionic and/or zwitterionic surface-active substances and/or from 0.1 to 25 percent by weight of at least one thickener and/or from 0.1 to 5 percent by weight of at least one care material. A method of dyeing fibers using the composition is also described.

    摘要翻译： 染料组合物的pH为3〜12，含有作为溶剂的水，醇和/或其混合物; 0.01至10重量％的至少一种式（I）染料化合物，其中R1表示氢或甲基，Y表示式-NHR2的氨基，R2为环丙基，甲氧基乙基 或甲氧基丙基; OR，其中R 1表示氢或具有1至4个碳原子的直链或支链烷基，Y表示式（II）的杂环：其中X为氮原子或氧原子，m为1,2或3，n为 是0或1; 和0.5至30重量％的至少一种阴离子，阳离子，两性和非离子和/或两性离子表面活性物质和/或0.1至25重量％的至少一种增稠剂和/或0.1至5重量％ 的至少一种护理材料。 还描述了使用该组合物染色纤维的方法。

    Hair keratin-reducing mono, di- and triglycerides of cysteine and compositions
    78.
    发明授权
    Hair keratin-reducing mono, di- and triglycerides of cysteine and compositions 失效
    头发角蛋白降低的半胱氨酸和组合物的单，二和甘油三酯

    公开(公告)号：US5503826A

    公开(公告)日：1996-04-02

    申请号：US330363

    申请日：1994-10-27

    申请人： Guenther Lang ,  Hans-Juergen Braun ,  Gerhard Maresch

    发明人： Guenther Lang ,  Hans-Juergen Braun ,  Gerhard Maresch

    IPC分类号： A61K8/00 ,  A61K8/44 ,  A61Q5/04 ,  C07C323/58 ,  A61K7/09 ,  A61K7/06

    CPC分类号： A61Q5/04 ,  A61K8/447 ,  C07C323/58

    摘要： The new keratin-reducing substances useful in compositions for permanent shaping of hair are glyceryl esters of cysteine, especially the monoglyceryl esters. As monoglyceryl esters of cysteine 2-amino-3-mercaptopropionic acid-(2',3'-dihydroxypropyl)ester and 2-amino-3-mercaptopropionic acid-(1',3'-dihydroxyisopropyl)ester are particularly preferred. A preferred embodiment of the compositions for permanent shaping of hair consists of a ready-to-use mixture of a water-free component including at least one glyceryl ester of cysteine and at least one other component which is kept physically separately from the water-free component until the mixture is prepared. The compositions also can include other conventional ingredients normally used in permanent shaping compositions such as surfactants and thickeners. The compositions have a preferred pH range of 6.0 to 8.5 and contain from 8 to 28 percent by weight of the glyceryl esters of cysteine.

    摘要翻译： 用于头发永久成型的组合物中的新的角蛋白还原物质是半胱氨酸的甘油酯，特别是单甘油酯。 作为半胱氨酸2-甘氨酸酯，2-氨基-3-巯基丙酸 - （2'，3'-二羟基丙基）酯和2-氨基-3-巯基丙酸 - （1'，3'-二羟基异丙基）酯是特别优选的。 用于永久成型头发的组合物的优选实施方案是由包含至少一种半胱氨酸甘油酯和至少一种其它成分的无水组分的即用混合物组成的物质与水分离物质分开 组分直到制备混合物。 组合物还可以包括通常用于永久成型组合物如表面活性剂和增稠剂的其它常规成分。 组合物具有6.0至8.5的优选pH范围并且含有8至28重量％的半胱氨酸的甘油酯。