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    Agent for coloring fibers and method for temporarily coloring fibers
    1.
    发明授权
    Agent for coloring fibers and method for temporarily coloring fibers 有权
    纤维染色剂和暂时着色纤维的方法

    公开(公告)号：US06669739B2

    公开(公告)日：2003-12-30

    申请号：US10019421

    申请日：2001-12-21

    申请人： Guido Sauter ,  Hans-Juergen Braun ,  Nadia Reichlin

    发明人： Guido Sauter ,  Hans-Juergen Braun ,  Nadia Reichlin

    IPC分类号： A61K713

    CPC分类号： D06P5/138 ,  A61K8/415 ,  A61K8/43 ,  A61K8/49 ,  A61K8/492 ,  A61Q5/065

    摘要： The object of the present invention is a preparation for coloring fibers, which is prepared before use by mixing an acidic component (A1), containing at least one enamine of Formula (I)/(Ia) with a component (A2), containing a Schiff's base of Formula (II) as well as a method for temporarily coloring fibers, for which the coloration, obtained with the aforementioned coloring agent, can be removed once again at any time by a sulfite-containing decolorizing agent.

    摘要翻译： 本发明的目的是通过将含有至少一种式（I）/（Ia）的烯胺的酸性组分（A1）与组分（A2）混合的酸性组分（A1）与含有 式（II）的希夫碱基以及暂时着色纤维的方法，用上述着色剂获得的着色可随时通过含亚硫酸盐脱色剂再次除去。

    5-aryl-1,3,3-trimethyl-2-methylene-indoline derivatives and salts thereof, methods for the production and use of said compounds for the temporary coloration of fibers
    2.
    发明授权
    5-aryl-1,3,3-trimethyl-2-methylene-indoline derivatives and salts thereof, methods for the production and use of said compounds for the temporary coloration of fibers 失效
    5-芳基-1,3,3-三甲基-2-亚甲基 - 二氢吲哚衍生物及其盐，用于制备和使用所述化合物用于纤维的暂时着色的方法

    公开(公告)号：US07056348B2

    公开(公告)日：2006-06-06

    申请号：US10297369

    申请日：2002-01-24

    申请人： Guido Sauter ,  Hans-Juergen Braun ,  Nadia Reichlin

    发明人： Guido Sauter ,  Hans-Juergen Braun ,  Nadia Reichlin

    IPC分类号： A61K7/13

    CPC分类号： C07D209/08 ,  A61K8/492 ,  A61Q5/10 ,  C07D401/04 ,  C07D405/04 ,  C07D405/14 ,  C07D409/04 ,  C07F5/025 ,  Y10S8/917 ,  Y10S8/918

    摘要： A method for the synthesis of 5-aryl-1,3,3,-trimethyl-2-methylene-indoline derivatives of Formula (I) or its salts of Formula (Ia) wherein 1 mole of a 5-aryl-2,3,3-trimethyl-3H-indole derivative of Formula (VII) is reacted for 1 to 44 hours at a temperature of 20° to 180° C. in an apolar, aprotic or polar, protic or polar aprotic solvent with 1 to 50 moles of a compound of Formula R1-A; new compounds of Formulas (I)/(Ia) and (V), obtainable by this method as well as an agent containing at least one compound of Formula (I)/(Ia) and a carbonyl/imine compound for dyeing keratinic fibers and a method for temporarily dyeing keratin fibers, for which the keratin fiber is dyed with the aforementioned agent and the dyeing, so obtained, is removed again at any later time by a sulfite preparation.

    摘要翻译： 合成式（I）的5-芳基-1,3,3 - 三甲基-2-亚甲基 - 二氢吲哚衍生物或其式（Ia）的盐的方法，其中将1摩尔5-芳基-2,3 ，式（VII）的3-三甲基-3H-吲哚衍生物在20〜180℃的温度下反应1〜44小时，在非极性，非质子或极性的质子或极性非质子溶剂中反应1〜50摩尔 的式R1-A的化合物; 可通过该方法获得的式（I）/（Ia）和（V）的新化合物以及含有至少一种式（I）/（Ia）化合物和用于染色角蛋白纤维的羰基/亚胺化合物的试剂， 用上述试剂染色角蛋白纤维和进行染色的角蛋白纤维暂时染色的方法，在随后的时间用亚硫酸盐制剂再次除去。

    Agent for dyeing fibers comprising an indoline/indolium derivative
    3.
    发明授权
    Agent for dyeing fibers comprising an indoline/indolium derivative 有权
    用于染色包含二氢吲哚/吲哚衍生物的纤维的试剂

    公开(公告)号：US06652601B2

    公开(公告)日：2003-11-25

    申请号：US09959112

    申请日：2001-10-17

    申请人： Guido Sauter ,  Hans-Juergen Braun ,  Nadia Reichlin

    发明人： Guido Sauter ,  Hans-Juergen Braun ,  Nadia Reichlin

    IPC分类号： A61K713

    CPC分类号： A61Q5/10 ,  A61K8/492 ,  A61K2800/88 ,  Y10S8/917 ,  Y10S8/918

    摘要： The object of the present invention is an agent for dyeing fibers obtained by mixing two components and characterized in that one component (component A2) contains at least one carbonyl compound and the other component (component A1) contains at least one indoline derivative of formula (I) or a 3H-indoline derivative of formula (Ia) as well as a multicomponent kit for dyeing and later decolorizing fibers, said kit containing both an agent according to the invention for producing a coloration on the fiber and an agent for the reductive removal of said coloration.

    摘要翻译： 本发明的目的是将两种成分混合而得到的纤维染色剂，其特征在于，一种成分（A2成分）含有至少一种羰基化合物，另一种成分（成分A1）含有至少一种式 I）或式（Ia）的3H-二氢吲哚衍生物以及用于染色和随后脱色纤维的多组分试剂盒，所述试剂盒包含根据本发明的用于在纤维上产生着色的试剂和用于还原性去除剂 的着色。

    Dye compositions containing quinolinium salts
    4.
    发明授权
    Dye compositions containing quinolinium salts 失效
    含有喹啉盐的染料组合物

    公开(公告)号：US06977001B2

    公开(公告)日：2005-12-20

    申请号：US10361380

    申请日：2003-02-10

    申请人： Guido Sauter ,  Hans-Juergen Braun ,  Nadia Duc-Reichlin

    发明人： Guido Sauter ,  Hans-Juergen Braun ,  Nadia Duc-Reichlin

    IPC分类号： A61K8/49 ,  A61Q5/10 ,  A61K7/13

    CPC分类号： A61K8/4926 ,  A61Q5/10

    摘要： The dye composition (A) for dyeing fibers, especially keratin fibers, such as human hair, is made by mixing a first component (A1) and a second component (A2) and adding an alkalizing agent or an acidifying agent, as needed. The second component (A2) consists of at least one compound with a nucleophilic reaction center and the first component (A1) consists of at least one 1-alkyl quinolinium derivative of formula (Ia) or (Ib): A multicomponent kit consisting of the first and second components packaged separately is also described as well as a method of dyeing fibers using the multicomponent kit.

    摘要翻译： 通过混合第一成分（A1）和第二成分（A2），根据需要添加碱化剂或酸化剂，来制造染色纤维，特别是角蛋白纤维如人发的染料组合物（A）。 第二组分（A2）由至少一种具有亲核反应中心的化合物组成，第一组分（A1）由至少一种式（Ia）或（Ib）的1-烷基喹啉衍生物组成：一种多组分试剂盒，由 还描述了单独包装的第一和第二组分以及使用多组分试剂盒染色纤维的方法。

    Agent and method for dyeing keratin fibers
    6.
    发明授权
    Agent and method for dyeing keratin fibers 失效
    用于染色角蛋白纤维的剂和方法

    公开(公告)号：US06835212B2

    公开(公告)日：2004-12-28

    申请号：US10181572

    申请日：2002-07-18

    申请人： David Rozzell ,  Guido Sauter ,  Hans-Juergen Braun

    发明人： David Rozzell ,  Guido Sauter ,  Hans-Juergen Braun

    IPC分类号： A61K713

    CPC分类号： A61K8/34 ,  A61K8/415 ,  A61K8/492 ,  A61K8/66 ,  A61Q5/10

    摘要： The agent for dyeing keratin fibers contains one or more aryl and/or benzyl alcohols, one or more oxidizing enzymes, especially vanillyl oxidase, derivatives of vanillyl oxidase or galactose oxidase, and a nucleophilic compound that forms a dye for dyeing keratin fibers in the presence of the alcohols and enzymes. A method for dyeing keratin fibers with this agent is also disclosed. Two-component kits for performing the method of dyeing keratin fibers include a first compenent (A) and a second component (B) separate from the first component. The first component (A) includes the nucleophilic compound, the alcohol and optionally the oxidizing enzyme. The second component (B) includes the oxidizing enzyme when it is not included in the first component or more alcohol.

    摘要翻译： 用于染色角蛋白纤维的试剂含有一种或多种芳基和/或苄醇，一种或多种氧化酶，特别是香草基氧化酶，香草基氧化酶或半乳糖氧化酶的衍生物，以及形成用于染色角蛋白纤维的染料的亲核性化合物 的醇和酶。 还公开了用该试剂染色角蛋白纤维的方法。 用于进行角蛋白纤维染色方法的双组分试剂包括与第一组分分离的第一组分（A）和第二组分（B）。 第一组分（A）包括亲核化合物，醇和任选的氧化酶。 第二组分（B）当不包括在第一组分或更多醇中时包括氧化酶。