公开(公告)号：US20020177676A1

公开(公告)日：2002-11-28

申请号：US09805277

申请日：2001-03-13

Inventor： Kent E. Mitchell ,  Gary L. Glass ,  L. Matthew Kirchman ,  Robert K. Provence ,  Leigh A. Ford ,  Randall S. Muninger

IPC: C08F004/44 ,  B01J031/00

CPC classification number: C08F110/02 ,  C08F4/6492 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/904 ,  Y10S526/943

Abstract: Methods are disclosed for preparing a highly active solid metallocene-containing catalyst system and its use in the polymerization of olefins. The catalyst system is prepared by creating a catalyst system solution by combining an aluminoxane with a metallocene having a substituent which has olefinic unsaturation in an aliphatic liquid to form a liquid catalyst system, conducting prepolymerization of an olefin in the liquid catalyst system, preferably in multiple stages, and separating the resulting solid metallocene-containing catalyst system from the reaction mixture. Also polymerization of olefins using the inventive solid catalyst system is disclosed.

Abstract translation: 公开了用于制备高活性固体茂金属催化剂体系及其在烯烃聚合中的应用的方法。 催化剂体系是通过将铝氧烷与具有在脂族液体中具有烯属不饱和键的取代基的茂金属组合形成液体催化剂体系，在液体催化剂体系中进行预聚合，优选多次 并将所得固体茂金属的催化剂体系与反应混合物分离。 还公开了使用本发明的固体催化剂体系的烯烃的聚合。

公开(公告)号：US20020165085A1

公开(公告)日：2002-11-07

申请号：US10052326

申请日：2002-01-18

Applicant: Saudi Basic Industries Corporation

Inventor： Orass Hamed ,  Akhlaq Moman ,  Atieh Abu-Raqabah

IPC: C08F004/44

CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/65925 ,  C08F110/02 ,  C08F210/16 ,  C08F4/65904 ,  C08F4/65916 ,  C08F2500/05 ,  C08F210/14

Abstract: A solid catalyst component comprises a transition metal-containing metallocene compound, a non-cyclopentadienyl transition metal compound, a magnesium compound and a polymeric material which acts as a support. The catalyst component is combined with co-catalyst organoaluminum compound or a mixture of organoaluminum compounds to provide a catalyst composition useful for olefin polymerization, e.g., to produce linear low, medium and high density polyethylenes or copolymerization of ethylene with alpha-olefins. Product polyolefin polymers have a varied range of molecular weight distributions. The catalyst composition is prepared by a process comprising combining polymer support particles, magnesium compound, transition metal-containing metallocene compound, and non-cyclopentadienyl transition metal compound to provide a solid catalyst component, and, combining the solid catalyst component with a cocatalyst compound to provide a polyolefin polymerization catalyst composition.

Abstract translation: 固体催化剂组分包含含过渡金属的茂金属化合物，非环戊二烯基过渡金属化合物，镁化合物和作为载体的聚合物。 将催化剂组分与助催化剂有机铝化合物或有机铝化合物的混合物组合以提供可用于烯烃聚合的催化剂组合物，例如产生线性低，中和高密度聚乙烯或乙烯与α-烯烃的共聚。 产品聚烯烃聚合物具有不同范围的分子量分布。 催化剂组合物通过包括将聚合物载体颗粒，镁化合物，含过渡金属的茂金属化合物和非环戊二烯基过渡金属化合物组合以提供固体催化剂组分的方法制备，并将固体催化剂组分与助催化剂化合物组合 提供聚烯烃聚合催化剂组合物。

公开(公告)号：US20020161143A1

公开(公告)日：2002-10-31

申请号：US10062389

申请日：2002-01-31

Inventor： Terry J. Burkhardt ,  Udo M. Stehling ,  James R. Hart ,  William T. Haygood JR. ,  Robert T. Li ,  James C. Vizzini ,  Matthew C. Kuchta

IPC: C08F004/44

CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/15 ,  C08F2500/21

Abstract: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: 1 wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten, preferably zirconium, hafnium or titanium, most preferably zirconium; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C10 alkenyl group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or hydrocarbyl, tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; preferably R1 and R2 are identical and are a C1-C3 alkyl or alkoxy group, a C6-C8 aryl or aryloxy group, a C2-C4 alkenyl group, a C7-C10 arylalkyl group, a C7-C12 alkylaryl group, or a halogen atom, preferably chlorine; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a nullNRnull2, nullSRnull1, nullORnull, nullOSiRnull3 or nullPRnull2 radical, wherein Rnull is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; preferably R3 is not a hydrogen atom; preferably each R3 is identical and is a fluorine, chlorine or bromine, atom, a C1-C4 alkyl group which may be halogenated, a C6-C8 aryl group which may be halogenated, a nullNRnull2, nullSRnull, nullORnull, nullOSiRnull3 or nullPRnull2 radical, wherein Rnull is one of a chlorine atom, a C1-C4 alkyl group, or a C6-C8 aryl group; more preferably, R3 are identical and are each a C3 alkyl group, most preferably isopropyl groups; alternatively, R3 is a C1 or C2 alkyl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings, preferably a 4-8 membered ring , more preferably a 6-membered ring; 2 nullB(R14)null, nullAl(R14)null, nullGenull, nullSnnull, nullOnull, nullSnull, nullSOnull, nullSO2-, nullN(R14)null, nullCOnull, nullP(R14)null, or nullP(O)(R14)null, or an amidoborane radical; wherein: R14, R15and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; preferably, R14, R15and R16 are identical and are a hydrogen atom, a halogen atom, a C1-C4 alkyl group, a CF3 group, a C6-C8 aryl group, a C6-C10 fluoroaryl group, more preferably a pentafluorophenyl group, a C1-C4 alkoxy group, in particular a methoxy group, a C2-C4 alkenyl group, a C7-C10 arylalkyl group, a C8-C12 arylalkenyl group, or a C7-C12alkylaryl group; or, R13 is represented by the formula: 3 wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; preferably, R17 to R24 are hydrogen. M2 is one or more carbons, silicon, germanium or tin, preferably silicon; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group IVA radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size, preferably a tertiary butyl group.

Abstract translation: 本发明涉及茂金属组合物及其在制备用于烯烃聚合的催化剂体系，特别是丙烯聚合中的用途。 金属茂组合物可以由下式表示：其中M1选自钛，锆，铪，钒，铌，钽，铬，钼和钨，优选锆，铪或钛，最优选锆; R1和R2相同或不同，为氢原子，C1-C10烷基，C1-C10烷氧基，C6-C10芳基，C6-C10芳氧基，C2-C10链烯基 ，C 2 -C 40烯基，C 7 -C 40芳基烷基，C 7 -C 40烷基芳基，C 8 -C 40芳基烯基，OH基或卤素原子，或任选被一个或多个烃基 ，三（烃基）甲硅烷基或烃基，三（烃基）甲硅烷基烃基，所述二烯具有至多30个不计氢的原子; 优选R1和R2相同，为C1-C3烷基或烷氧基，C6-C8芳基或芳氧基，C2-C4烯基，C7-C10芳基烷基，C7-C12烷基芳基或卤素 原子，优选氯; R 3相同或不同，各自为氢原子，卤素原子，可被卤化的C 1 -C 10烷基，可被卤化的C 6 -C 10芳基，C 2 -C 10烯基，C 7 -C 40 - 芳基烷基，C7-C40烷基芳基，C8-C40芳基烯基，-NR'2，-SR'1，-OR'，-OSiR'3或-PR'2基，其中R'为 卤素原子，C1-C10烷基或C

公开(公告)号：US20020156208A1

公开(公告)日：2002-10-24

申请号：US10127984

申请日：2002-04-22

Inventor： Joseph C. Floyd ,  Moses Olukayode Jejelowo ,  Donna Jean Crowther ,  George Alan Vaughan ,  Ching Tai Lue

IPC: C08F004/44

CPC classification number: C08F210/16 ,  C08F4/61916 ,  C08F4/61922 ,  C08F10/02 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/06

Abstract: The invention comprises an olefin polymerization process comprising contacting ethylene alone or with one or more olefinically unsaturated comonomers with a Group 3-6 metallocene catalyst compound comprising one null-bonded ring having a C3 or greater hydrocarbyl, hydrocarbylsilyl or hydrocarbylgermyl substituent said substituent bonded to the ring through a primary carbon atom; and, where the compound contains two null-bonded rings, the total number of substituents on the rings is equal to a number from 3 to 10, said rings being asymmetrically substituted where the number of substituents is 3 or 4. The invention process is particularly suitable for preparing ethylene copolymers having an MIR less than about 35, while retaining narrow CD even at high comonomer incorporation rates, and with certain embodiments providing ethylene copolymers having improved melt strength with the low MIR.

Abstract translation: 本发明包括烯烃聚合方法，包括使乙烯单独或与一种或多种烯属不饱和共聚单体与3-6族茂金属催化剂化合物接触，所述组合物包含一个具有C3或更多烃基，烃基甲硅烷基或烃基锗原子取代基的π键合环，所述取代基与 环通过伯碳原子; 并且当化合物含有两个π键合环时，环上的取代基的总数等于3至10的数，所述环是不对称取代的，其中取代基的数目为3或4.本发明方法特别 适于制备具有小于约35的MIR的乙烯共聚物，同时保持窄的CD，即使在高共聚单体掺入速率下，并且在某些实施方案中提供具有改进的熔融强度与低MIR的乙烯共聚物。

公开(公告)号：US20020147284A1

公开(公告)日：2002-10-10

申请号：US10066626

申请日：2002-02-06

Inventor： Jean Malinge ,  Claude Brun ,  Jean-Loup Lacombe

IPC: C08F004/44 ,  B01J031/00

CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/6555 ,  C08F4/6546 ,  C08F2500/07 ,  C08F2500/04 ,  C08F210/14

Abstract: A copolymer of ethylene and an alpha-olefin contains from 3 to 12 carbon atoms, wherein 0.1 to 1.5 mol % of the units originate from the alpha-olefin. The copolymer has a relative density ranging from 0.960 to 0.940, a transition metal content lower than 6 ppm, an Mw/Mn ratio higher than 7, an Mz/Mw ratio higher than 3.3 and an Mz higher than 300,000. The copolymer is prepared from the polymerization or co-polymerization of at least one olefin in the presence of a solid catalytic component or a prepolymerized catalyst.

Abstract translation: 乙烯和α-烯烃的共聚物含有3至12个碳原子，其中0.1至1.5摩尔％的单元源自α-烯烃。 共聚物的相对密度为0.960〜0.940，过渡金属含量低于6ppm，Mw / Mn比高于7，Mz / Mw比高于3.3，Mz高于30万。 共聚物由固体催化组分或预聚合催化剂存在下由至少一种烯烃的聚合或共聚制备。

公开(公告)号：US20020137859A1

公开(公告)日：2002-09-26

申请号：US09926742

申请日：2001-12-11

Inventor： Kiyohiko Yokota ,  Noriyuki Tani

IPC: C08F004/44

CPC classification number: C08F210/06 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/00 ,  C08F210/02 ,  C08F210/16 ,  C08F4/65927 ,  C08F212/08 ,  C08F2500/03 ,  C08F210/14

Abstract: The invention provides a method for producing null-olefin-aromatic vinyl compound copolymers of high quality at high productivity. The method for producing an null-olefin-aromatic vinyl compound copolymer including copolymerizing an null-olefin and an aromatic vinyl compound in the presence of a copolymerization catalyst formed of a transition metal compound component (A) and a co-catalyst component (B) wherein the component (A) employs a transition metal compound having two cross-linking groups wherein at least one of the cross-linking groups is a cross-linking group exclusively formed of a carbon-carbon bond.

Abstract translation: 本发明提供了一种生产高品质的α-烯烃 - 芳族乙烯基化合物共聚物的方法。 在由过渡金属化合物组分（A）和助催化剂组分（B）形成的共聚催化剂存在下，制备α-烯烃 - 芳族乙烯基化合物共聚物的方法，包括使α-烯烃和芳族乙烯基化合物共聚， 其中组分（A）使用具有两个交联基团的过渡金属化合物，其中至少一个交联基团是仅由碳 - 碳键形成的交联基团。

公开(公告)号：US20020132944A1

公开(公告)日：2002-09-19

申请号：US10096766

申请日：2002-03-13

Inventor： Agapios K. Agapiou ,  Chi-I Kuo

IPC: C08F004/44

CPC classification number: C08F10/02 ,  C08F4/65904 ,  C08F4/65916 ,  C08F4/65927 ,  C08F210/16 ,  Y10S526/943 ,  C08F2/005 ,  C08F4/65912 ,  C08F210/14

Abstract: The present invention relates to a process for polymerizing olefin(s) in the presence of polymerization catalyst a Group 13 containing compound and a carboxylic acid. The invention also relates to a process for transitioning from one polymerization catalyst to another.

Abstract translation: 本发明涉及一种聚合催化剂存在的含13族的化合物和羧酸的烯烃聚合方法。 本发明还涉及从一种聚合催化剂转变成另一种聚合催化剂的方法。

公开(公告)号：US20020132728A1

公开(公告)日：2002-09-19

申请号：US10100529

申请日：2002-03-18

Inventor： Francis C. Rix

IPC: C08F004/44

CPC classification number: C08F10/00 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F4/65908 ,  C08F2/06 ,  C08F2500/01 ,  C08F210/06 ,  C08F2500/03

Abstract: This description addresses a process for the preparation of polyolefins from one or more olefinic monomers comprising combining under polymerization conditions said olefins with the product of combining i) an organometallic catalyst compound and ii) a cocatalyst complex comprising a trialkylsilyl-substituted carbenium cation and a suitable noncoordinating or weakly coordinating anion. These complexes exhibit good solubility in aliphatic solvents such that use in aliphatic solution based polymerization reaction processes can be conducted without the use of aromatic solvents or co-solvents and without the need for slurry means of introduction into chemical reaction environments. High number-average molecular weight polymers and copolymers at high rates of productivity were observed from the use of metallocene catalysts complexes when activated with null(3, 5-(Et3Si)2Ph)3Cnullnull null(C6F5) Bnullnull and used in a hexane-based solution polymerization.

Abstract translation: 该描述涉及从一种或多种烯烃单体制备聚烯烃的方法，其包括在聚合条件下将所述烯烃与i）有机金属催化剂化合物和ii）包含三烷基甲硅烷基取代的碳鎓阳离子的助催化剂络合物和合适的 非配位或弱配位阴离子。 这些配合物在脂肪族溶剂中表现出良好的溶解性，从而可以在不使用芳香族溶剂或助溶剂的情况下进行基于脂肪族溶液的聚合反应方法的使用，并且不需要引入化学反应环境中的浆料装置。 当用[（3,5-（Et 3 Si）2 Ph）3C] + [（C 6 F 5）B]活化时，使用茂金属催化剂配合物观察到高生产率的高数均分子量聚合物和共聚物，并用于 己烷基溶液聚合。

公开(公告)号：US20020128401A1

公开(公告)日：2002-09-12

申请号：US09473489

申请日：1999-12-28

Inventor： ROBERT CHARLES JOB ,  WALTER THOMAS REICHLE

IPC: C08F004/44

CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F210/16 ,  C08F4/6567 ,  C08F4/6548 ,  C08F4/65904 ,  C08F4/651 ,  C08F210/14 ,  C08F2500/12

Abstract: A solid self-supported cycloalkadienyl catalyst component is disclosed that includes: (i) a mixed metal alkoxide complex which is the reaction product of a magnesium alkoxide or aryloxide and at least one group IVB metal-containing alkoxide or aryloxide; and (ii) Cp, where Cp is a cyclic or polycyclic hydrocarbon having from 3-30 carbon atoms. A self-supported hybrid catalyst also is disclosed which contains the above components (i) and (ii), as well as (iii) a Ziegler-Natta catalyst species. A method of making the self-supported cycloalkadienyl catalyst and the self-supported hybrid catalyst and a method of polymerizing olefins using the catalysts also are disclosed. The catalysts are capable of producing polyolefins in high yield having a broad molecular weight distribution, or a bimodal distribution.

Abstract translation: 公开了一种固体自支撑的环烷二烯基催化剂组分，其包括：（i）作为醇盐或芳氧化镁与至少一种IVB族金属的醇盐或芳氧基的反应产物的混合金属醇盐络合物; 和（ii）Cp，其中Cp是具有3-30个碳原子的环状或多环烃。 还公开了一种自支撑的杂化催化剂，其包含上述组分（i）和（ii），以及（iii）齐格勒 - 纳塔催化剂种类。 公开了一种制备自支撑的环二烯基催化剂和自支撑的杂化催化剂的方法和使用该催化剂聚合烯烃的方法。 催化剂能够以高产率生产具有宽分子量分布或双峰分布的聚烯烃。

公开(公告)号：US20020123639A1

公开(公告)日：2002-09-05

申请号：US09761151

申请日：2001-01-17

Inventor： Jeffrey M. Sullivan ,  Daniel A. Gately

IPC: C08F004/44 ,  C07F017/00

CPC classification number: C07F17/00 ,  Y10S526/943

Abstract: A novel constrained geometry titanium(II) diene complex and ligands of such complexes are described. The novel complex has an olefin polymerization activity substantially in excess of a defined activity standard characteristic of analogous prior art constrained geometry diene complexes. Methods for the synthesis of the novel, high-activity complexes are described.

Abstract translation: 描述了新型约束几何钛（II）二烯络合物和这种络合物的配体。 该新型络合物具有基本上超过类似的现有技术约束几何二烯配合物的限定的活性标准特征的烯烃聚合活性。 描述了合成新型高活性复合物的方法。