Process for the continuous production of alkylesters of saturated
aliphatic carboxylic acids
    81.
    发明授权
    Process for the continuous production of alkylesters of saturated aliphatic carboxylic acids 失效
    连续生产饱和脂肪族羧酸烷基酯的方法

    公开(公告)号:US4502992A

    公开(公告)日:1985-03-05

    申请号:US376750

    申请日:1982-05-10

    CPC分类号: C07C69/24 C07C67/38

    摘要: A process and apparatus for the continuous production of alkylesters of saturated aliphatic carboxylic acids by reacting olefins with carbon monoxide and alkanol in the presence of a catalyst consisting of a cobalt compound and a promoter selected from the group consisting of pyridine, non-ortho-substituted alkylpyridines and mixtures at elevated pressure and elevated temperature, the reaction based on olefins having at least 8 C atoms and being carried out in a reactor wherein the flow characteristic is adjusted so that tubular flow without back-mixing predominates, and wherein the raw materials are supplied in the desired ratios at the input side of the reactor.

    摘要翻译: 一种用于在由钴化合物和助催化剂组成的催化剂存在下使烯烃与一氧化碳和链烷醇反应连续生产饱和脂肪族羧酸的烷基酯的方法和装置,该催化剂选自吡啶,非邻位取代的 烷基吡啶和混合物在升高的压力和升高的温度下进行,所述反应基于具有至少8个C原子的烯烃,并且在反应器中进行,其中调节流动特性以使得没有反混合的管状流动占优势,并且其中原料为 在反应器的输入侧以所需的比率供给。

    Preparation of fatty acid esters
    82.
    发明授权
    Preparation of fatty acid esters 失效
    脂肪酸酯的制备

    公开(公告)号:US4421691A

    公开(公告)日:1983-12-20

    申请号:US270851

    申请日:1981-06-05

    CPC分类号: C07C67/38

    摘要: A process for preparing fatty acid esters by reacting olefins, alkanols and carbon monoxide in the presence of a compound of cobalt and a promoter consisting of pyridine, non-orthosubstituted alkylpyridines or mixtures thereof. The reaction output is at first treated with a gas containing oxygen in a non-damaging manner and then reprocessed in two distillation stages. The first distillation stage is operated at a higher pressure than the second. In the first distillation stage there is produced a distillate free of cobalt and a sump product containing all of the cobalt used as catalyst. In the second distillation stage the sump product of the first distillation stage is again distilled to produce another distillate free of cobalt and a cobalt concentrate as sump product. This cobalt concentrate is incorporated into pyridine, a non-orthosubstituted alkylpyridine or a mixture thereof to form a suspension. The suspension is then treated by a mixture of carbon monoxide and hydrogen at a temperature of 100.degree. to 250.degree. C. and a pressure at least 50 bars, and this treatment product is fed back into the fatty acid ester synthesis.

    摘要翻译: 在钴化合物和由吡啶,非取代的烷基吡啶或其混合物组成的促进剂的存在下,使烯烃,aklanols和一氧化碳反应制备脂肪酸酯的方法。 首先用非破坏性方式用含氧气体处理反应产物,然后在两个蒸馏阶段再处理。 第一个蒸馏阶段的操作压力高于第二个。 在第一蒸馏阶段,产生不含钴的馏出物和含有用作催化剂的所有钴的贮槽产物。 在第二蒸馏阶段,再次蒸馏第一蒸馏阶段的贮槽产物以产生不含钴的另一种馏出物和作为贮槽产物的钴浓缩物。 将该钴浓缩物并入吡啶,非邻位取代的烷基吡啶或其混合物中以形成悬浮液。 然后将悬浮液在一氧化碳和氢气的混合物中在100至250℃的温度和至少50巴的压力下处理,并将该处理产物反馈到脂肪酸酯合成中。

    Closure for tire chains
    83.
    发明授权
    Closure for tire chains 失效
    关闭轮胎链条

    公开(公告)号:US4416319A

    公开(公告)日:1983-11-22

    申请号:US401339

    申请日:1982-07-23

    申请人: Peter Hofmann

    发明人: Peter Hofmann

    摘要: In tire chains, closures are required to lock tension-chain lines (10) in the tensioned position. A proposed closure is provided with a pull-through orifice (2) for the tension-chain line (10) and with a locking slot (3) adjacent to the pull-through orifice (2). To prevent the particular chain link (9) suspended in the locking slot (3) from working loose, the pull-through orifice (2) is equipped with an elastic insert (11) which forms at least one engagement cam projecting into the locking slot (3).

    摘要翻译: 在轮胎链条中,需要闭合件将张紧线(10)锁定在张紧位置。 所提出的闭合件设置有用于张紧线(10)的拉通孔(2)和与拉通孔(2)相邻的锁定槽(3)。 为了防止悬挂在锁定槽(3)中的特定链节(9)松动,拉通孔(2)配备有弹性插入件(11),该弹性插入件形成突出到锁定槽中的至少一个接合凸轮 (3)。