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公开(公告)号:US4358475A
公开(公告)日:1982-11-09
申请号:US242458
申请日:1981-03-11
申请人: David E. Brown , Mahmood N. Mahmood
发明人: David E. Brown , Mahmood N. Mahmood
IPC分类号: H01M4/90 , C23C18/12 , C25B1/04 , C25B11/00 , C25B11/04 , C25B11/06 , C25B11/10 , H01M4/88 , B05D5/12
CPC分类号: C25B11/0478 , Y02E60/366
摘要: This invention relates to a method of producing metal electrodes by treating a metal electrode substrate so as to coat the substrate surface with a homogeneous solution of the compounds of (i) at least one metal selected from a first group of iron, cobalt, nickel and manganese (ii) at least one other metal selected from a second group of molybdenum, tungsten and vanadium, each of which compound is capable of thermal decomposition to the corresponding metal oxide. The coated substrate is then thermally decomposed and the oxide-coated substrate is cured in a reducing atmosphere at elevated temperature. Substrates coated with Ni-Mo oxides are preferred. The electrodes thus produced exhibit very low overvoltage, are of high stability with respect to their activity and can be used as cathodes for the electrolysis of water or brine.
摘要翻译: 本发明涉及一种金属电极的制造方法,其特征在于,通过处理金属电极基板,以使(i)选自第一组铁,钴,镍中的至少一种的金属和 锰(ii)选自第二组钼,钨和钒中的至少一种其它金属,其中每种化合物能够热分解成相应的金属氧化物。 然后将涂覆的基材热分解,并且氧化物涂覆的基材在升高的温度下在还原气氛中固化。 用Ni-Mo氧化物涂覆的基材是优选的。 由此产生的电极表现出非常低的过电压,相对于它们的活性具有高稳定性,并且可以用作电解水或盐水的阴极。