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81.发明授权
公开(公告)号：US4120779A
公开(公告)日：1978-10-17
申请号：US713628
申请日：1976-08-11
CPC分类号： C10G19/00 , C10G19/08 , C10G45/00 , Y10S423/12
摘要： Sulfur-containing petroleum oil feedstocks which include heavy hydrocarbon constituents undergo simultaneous desulfurization and hydroconversion by contacting and reacting such feedstocks with sodamide in the presence of hydrogen and at elevated temperatures. The mixture of reaction products resulting from the above procedure is separated to give a sodium sulfur salt by-product, and a petroleum oil product which has been substantially desulfurized and demetallized, as well as being significantly improved as indicated by a reduced Conradson carbon content and an increased API gravity relative to the feedstock. Sodamide is regenerated from the sodium sulfur salt by-product and can be recycled for reaction with additional feedstock.
摘要翻译： 包括重质烃成分的含硫石油原料通过在氢气存在下和高温下使这些原料与sodamide接触和反应而同时进行脱硫和加氢转化。 分离由上述方法得到的反应产物的混合物，得到硫化钠盐副产物，以及基本脱硫和去金属化的石油产品，并且显着改善，如Conradson碳含量和 相对于原料的API重力增加。 钠盐从钠硫酸钠副产物中再生，可再循环用于与额外原料反应。
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公开(公告)号：US4111787A
公开(公告)日：1978-09-05
申请号：US858546
申请日：1977-12-08
CPC分类号： C10G45/16 , C10G1/006 , C10G1/083 , C10G1/086 , C10G2300/107
摘要： A catalytic slurry hydroconversion process for producing normally liquid hydrocarbons from a heavy hydrocarbonaceous oil and from coal is performed in at least two stages in series. The heavy oil is introduced into the first hydroconversion stage and the coal is introduced into any of the hydroconversion stages other than the first stage.
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83.发明授权Desulfurization and hydroconversion of residua with alkaline earth metal compounds and hydrogen 失效残渣与碱土金属化合物和氢的脱硫和加氢转化
公开(公告)号：US4087348A
公开(公告)日：1978-05-02
申请号：US733085
申请日：1976-10-18
摘要： Sulfur-containing petroleum oil feedstocks which include heavy hydrocarbon constituents undergo simultaneous desulfurization and hydroconversion by contacting such feedstocks with alkaline earth metal hydrides or alkaline earth metal oxides, particularly barium hydride or barium oxide, in the presence of hydrogen, and at elevated temperatures. The mixtures of reaction products resulting from the above procedure can be separated to give a petroleum oil product which has been substantially desulfurized and demetallized and significantly upgraded as demonstrated by reduced Conradson carbon content, and increased API gravity and which includes alkaline earth metal sulfide salts from which the alkaline earth metal hydrides or oxides may be regenerated.
摘要翻译： 包括重质烃成分的含硫石油原料通过在氢气存在下和在升高的温度下接触这些原料与碱土金属氢化物或碱土金属氧化物，特别是氢化钡或氧化钡同时进行脱硫和加氢转化。 由上述程序产生的反应产物的混合物可以分离，得到一种石油产品，其已被基本上脱硫和脱金属化并显着升级，如通过减少的康拉逊碳含量和增加的API重力所证明的，并且其包括碱土金属硫化物盐 碱土金属氢化物或氧化物可以再生。
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84.发明授权Hydroconversion of coal in a hydrogen donor solvent with an oil-soluble catalyst 失效在氢供体溶剂中用油溶性催化剂加氢转化煤
公开(公告)号：US4077867A
公开(公告)日：1978-03-07
申请号：US702272
申请日：1976-07-02
CPC分类号： C10G1/086 , C10G1/083 , Y10S208/951
摘要： A process for catalytically hydroconverting coal to produce coal liquids is effected by forming a mixture of an oil soluble metal compound, a hydrogen donor solvent and coal, converting the compound to a catalyst within said mixture and reacting the mixture with hydrogen. The recovered hydrogen donor solvent may be recycled to the hydroconversion zone without intervening hydrogenation. Preferred compounds are molybdenum compounds.
摘要翻译： 通过形成油溶性金属化合物，氢供体溶剂和煤的混合物，将化合物转化为所述混合物内的催化剂并使混合物与氢反应，来实现催化加氢转化煤以产生煤液体的方法。 回收的氢供体溶剂可以循环到加氢转化区而无需中间氢化。 优选的化合物是钼化合物。
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公开(公告)号：US4055483A
公开(公告)日：1977-10-25
申请号：US710800
申请日：1976-08-02
CPC分类号： B01J31/183 , B01J31/143 , B01J2531/025 , B01J2531/56 , C10G2300/107
摘要： A heavy hydrocarbonaceous oil containing a Group IB, IVB, VB, VIB, VIIB or VIII transition metal compound is upgraded by treatment with hydrogen or a hydrogen donor compound in the presence of an aluminum alkyl compound, for example, triethyl aluminum. The transition metal compound may be naturally occurring in the oil or added to the oil. A preferred transition metal compound is vanadyl phthalocyanine.
摘要翻译： 含有IB，IVB，VB，VIB，VIIB或VIII族过渡金属化合物的重质含油油通过在烷基铝化合物例如三乙基铝的存在下用氢气或氢供体化合物进行处理。 过渡金属化合物可以天然存在于油中或加入到油中。 优选的过渡金属化合物是氧钒基酞菁。
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86.发明授权
公开(公告)号：US4017381A
公开(公告)日：1977-04-12
申请号：US571955
申请日：1975-04-28
CPC分类号： C10G19/00 , C10G19/08 , C10G45/00 , Y10S423/12
摘要： Sulfur-containing petroleum oil feedstocks which include heavy hydrocarbon constituents undergo simultaneous desulfurization and hydroconversion by contacting and reacting such feedstocks with sodamide in the presence of hydrogen and at elevated temperatures. The mixture of reaction products resulting from the above procedure is separated to give a sodium sulfur salt by-product, and a petroleum oil product which has been substantially desulfurized and demetallized, as well as being significantly improved as indicated by a reduced Conradson carbon content and an increased API gravity relative to the feedstock. Sodamide is regenerated from the sodium sulfur salt by-product and can be recycled for reaction with additional feedstock.
摘要翻译： 包括重质烃成分的含硫石油原料通过在氢气存在下和高温下使这些原料与sodamide接触和反应而同时进行脱硫和加氢转化。 分离由上述方法得到的反应产物的混合物，得到硫化钠盐副产物，以及基本脱硫和去金属化的石油产品，并且显着改善，如Conradson碳含量和 相对于原料的API重力增加。 钠盐从钠硫酸钠副产物中再生，可再循环用于与额外原料反应。
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