-
公开(公告)号：US5496464A
公开(公告)日：1996-03-05
申请号：US385676
申请日：1995-02-08
Applicant: Jan Piskorz , Desmond St. A. G. Radlein , Piotr Majerski , Donald S. Scott
Inventor： Jan Piskorz , Desmond St. A. G. Radlein , Piotr Majerski , Donald S. Scott
Abstract: A process is described for hydrotreating a heavy hydrocarbon oil containing a substantial portion of material which boils above 524.degree. C. to form lower boiling materials, which comprises adding to the heavy hydrocarbon oil as solvent a paraffinic, isoparaffinic or cyclic paraffinic hydrocarbon which is also hydrogen-rich and has a critical temperature of less than 500.degree. C. to thereby form a diluted feedstock mixture and subjecting said feedstock mixture to hydrotreating in the presence of activated carbon catalyst at a temperature and pressure substantially at or greater than the critical temperature and pressure of the solvent.
Abstract translation: 描述了一种加氢处理含有大部分沸点高于524℃的大部分材料的重质烃油的方法，以形成较低沸点的材料，其包括将重质烃油作为溶剂加入石蜡，异链烷烃或环状链烷烃，其也是 富氢并且具有小于500℃的临界温度，从而形成稀释的原料混合物，并在活性炭催化剂存在下，在基本上等于或高于临界温度的温度和压力下使所述原料混合物加氢处理， 溶剂的压力。
-
82.发明授权Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol 失效将碳质原料转化成颗粒状碳和甲醇的方法
公开(公告)号：US5427762A
公开(公告)日：1995-06-27
申请号：US209605
申请日：1994-03-09
Applicant: Meyer Steinberg , Edward W. Grohse
Inventor： Meyer Steinberg , Edward W. Grohse
CPC classification number: C10L1/32 , C07C29/1518 , C09C1/48 , C10G1/06 , C10J3/463 , C10J3/54 , C10J2300/0996 , C10J2300/1665 , C10J2300/1693 , Y02P20/52
Abstract: A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.
Abstract translation: 一种从含碳原料生产无污染物颗粒碳（即，基本上为灰分，无硫和无氮的碳）的方法。 基本方法包括使循环加氢热解甲烷热解过程中形成的气流中的一种脱氧，以改善初始含碳原料的转化率。 通过将一种热解气流（优选后者）中包含的一氧化碳，二氧化碳和氢气催化转化成甲醇共同产物来进行脱氧。 因此产生了两种产品，其使用本身已知，即基本上不含污染物的颗粒炭黑和甲醇。 这些产物可以以碳黑在甲醇中的液体浆料的形式混合。
-
公开(公告)号：US5332489A
公开(公告)日：1994-07-26
申请号：US075711
申请日：1993-06-11
Applicant: Lavanga R. Veluswamy
Inventor： Lavanga R. Veluswamy
Abstract: This invention relates to a process for converting a carbonaceous material to a liquid product using a hydrogen donor solvent. More specifically, this invention relates to a process for hydroconverting carbonaceous material in which a 400.degree.-1000.degree. F. hydroconversion product fraction is further hydrocracked and a hydrocracked fraction is used as the hydrogen donor solvent. An increased quantity of liquid product is achieved by removing an ash residuum from the hydroconversion product fraction prior to the hydrocracking process.
Abstract translation: 本发明涉及使用氢供体溶剂将碳质材料转化为液体产品的方法。 更具体地说，本发明涉及一种用于加氢转化含碳材料的方法，其中将400°-1000°F加氢转化产物级分进一步加氢裂化，加氢裂化馏分用作氢供体溶剂。 通过在加氢裂化过程之前从加氢转化产物馏分中除去灰渣，可实现液体产物的增加。
-
公开(公告)号：US5256278A
公开(公告)日：1993-10-26
申请号：US843909
申请日：1992-02-27
Applicant: John R. Rindt , Melanie D. Hetland
Inventor： John R. Rindt , Melanie D. Hetland
CPC classification number: C10G1/006
Abstract: An improved multistep liquefaction process for organic carbonaceous mater which produces a virtually completely solvent-soluble carbonaceous liquid product. The solubilized product may be more amenable to further processing than liquid products produced by current methods. In the initial processing step, the finely divided organic carbonaceous material is treated with a hydrocarbonaceous pasting solvent containing from 10% and 100% by weight process-derived phenolic species at a temperature within the range of 300.degree. C. to 400.degree. C. for typically from 2 minutes to 120 minutes in the presence of a carbon monoxide reductant and an optional hydrogen sulfide reaction promoter in an amount ranging from 0 to 10% by weight of the moisture- and ash-free organic carbonaceous material fed to the system. As a result, hydrogen is generated via the water/gas shift reaction at a rate necessary to prevent condensation reactions. In a second step, the reaction product of the first step is hydrogenated.
Abstract translation: 用于有机碳质材料的改进的多步骤液化方法，其产生几乎完全溶剂可溶的含碳液体产物。 与目前的方法生产的液体产品相比，溶解产物可能更适于进一步加工。 在初始加工步骤中，细碎的有机碳质材料在含有10％和100％（重量）的工艺衍生的酚类物质的含烃粘土溶剂中处理，温度范围为300-400℃， 通常在一氧化碳还原剂和任选的硫化氢反应促进剂存在下2分钟至120分钟，其量为供给系统的无水和无灰的有机碳质材料的0至10重量％。 结果，以防止缩合反应所需的速率经由水/气转换反应生成氢。 在第二步中，将第一步骤的反应产物氢化。
-
85.发明授权
公开(公告)号：US4983279A
公开(公告)日：1991-01-08
申请号：US279089
申请日：1988-12-02
Applicant: Wolfdieter Klein , Claus Strecker , Alfons Feuchthofen , Ulrich Boenisch
Inventor： Wolfdieter Klein , Claus Strecker , Alfons Feuchthofen , Ulrich Boenisch
Abstract: A process for the hydrogenation of a liquid hydrocarbon-containing charge material, comprising the steps of: (i) supplying a high temperature high pressure liquid phase hydrogenation reactor with two separately and indirectly heated charge streams, (a) a primary charge stream comprising liquid hydrocarbon oils, oil residues, syncrudes, tars or pitches and optionally coal, and hydrogen-containing gas, and (b) a directly heated secondary gaseous charge stream comprising hydrogen-containing gas, and combining said indirectly heated primary charge stream and said indirectly and directly heated secondary charge stream prior to said liquid phase hydrogenation reactor, hydrogenating the combined streams to produce a hydrogenation product and separating the hydrogenation product in a hot separator to give a hot separator head product; wherein said indirectly heated primary and secondary charge streams are heated by separate heat exchange means by heat exchange with said hot separator head product, and said secondary charge stream, after heating by heat exchange, is directly heated with a hydrogenation gas heater.
Abstract translation: 一种用于氢化含液体烃的电荷材料的方法，包括以下步骤：（i）向高温高压液相氢化反应器提供两个单独和间接加热的电荷流，（a）包含液体 烃油，油残余物，合成油，焦油或沥青，以及任选的煤和含氢气体，和（b）包含含氢气体的直接加热的次级气态电荷流，并将所述间接加热的初级进料流和所述间接和 在所述液相氢化反应器之前直接加热次级进料流，将组合物流氢化以产生氢化产物并在热分离器中分离氢化产物，得到热分离器头产物; 其中所述间接加热的初级和次级进料流通过与所述热分离器头部产物进行热交换的单独的热交换装置加热，并且所述次级进料流在通过热交换加热之后直接用氢化气体加热器加热。
-
Patent Agency Ranking
公开(公告)号：US4931171A
公开(公告)日：1990-06-05
申请号：US404680
申请日：1982-08-03
Applicant: Douglas R. Piotter
Inventor： Douglas R. Piotter
Abstract: A process for the pyrolysis of carbonaceous materials at an elevated temperature or an elevated temperature and an elevated pressure in which a fuel is burned in the presence of a combustion supporting material, in an amount sufficient to supply at least the stoichiometric amount of oxygen for combustion of all of the fuel, to produce an effluent containing significant amounts of nitrogen and carbon dioxide and having an elected temperature, passing the effluent to a pyrolysis zone, wihtout removal of components therefrom, to thereby create an elevated temperature within the pyrolysis zone and pyrolyzing the carbonaceous material in the pyrolysis zone in the presence of the effluent from the burning step and at an elevated temperature. The burning step may additionally be carried out at a high flame velocity to produce an effluent having an elevated pressure and the carbonaceous material may thus additionally be pyrolyzed at an elevated pressure.
Abstract translation: 一种在高温或升高的温度和升高的压力下热解碳质材料的方法，其中燃料在燃烧载体材料存在下燃烧，其量足以提供至少化学计量的氧气用于燃烧 的所有燃料，以产生含有大量氮和二氧化碳并具有选定温度的流出物，将流出物通过热解区，从而除去组分，从而在热解区内产生升高的温度并热解 在来自燃烧步骤和升高温度的流出物存在下，热解区中的碳质材料。 燃烧步骤可以另外以高火焰速度进行以产生具有升高的压力的流出物，并且碳质材料因此可另外在升高的压力下热解。
-
公开(公告)号：US4764270A
公开(公告)日：1988-08-16
申请号：US840858
申请日：1986-03-18
Applicant: C. Richard Hsieh , William I. Donaldson
Inventor： C. Richard Hsieh , William I. Donaldson
CPC classification number: C10G1/065
Abstract: An improved tar sands derived bitumen and coal liquification process is disclosed wherein substantial percentages of subdivided coal particles and tar sands derived bitumen liquids are mixed and then corefined with hydrogen under hydrocracking conditions, but in the absence of a separate catalyst, at a temperature range of 800.degree. to 900.degree. F. and a pressure of about 2400 psig. The resutling fluid after removal of residual solids is a suitable liquid feedstock for conventional refinery equipment to produce petroleum fractions useful as transportation and heating fuels. Preferably, a portion of the corefined bitumen-coal liquid product may be recycled for mixture with the bitumen liquid and coal. Raw or native tar sands may also be mixed with the liquid butumen and coal in the process.
Abstract translation: 公开了一种改进的焦油砂衍生的沥青和煤液化方法，其中衍生的沥青液体的重要百分比的细分煤颗粒和焦油砂混合，然后在加氢裂化条件下用氢气进行核化，但是在不存在单独的催化剂的情况下， 800°至900°F，压力约为2400psig。 去除残留固体后的废液是用于常规炼油设备生产用作运输和加热燃料的石油馏分的合适的液体原料。 优选地，一部分核心沥青煤液体产物可以再循环用于与沥青液体和煤混合。 在此过程中，原料或天然焦油砂也可与液体丁醇和煤混合。
-
公开(公告)号：US4708788A
公开(公告)日：1987-11-24
申请号：US631366
申请日：1984-07-16
Applicant: Jim Y. Low
Inventor： Jim Y. Low
Abstract: A liquefaction process for coal lignite or heavy oil is disclosed utilizing a hydrogen-donor solvent. The preferred hydrogen-donor solvent is recovered as a vapor from the liquefaction mixture. The preferred method for converting the vapor into active hydrogen-donor solvent form involves passage of the vapor over a catalyst bed positioned in the vapor space of the catalyst vessel. Novel apparatus for so positioning the catalyst bed is also disclosed.
Abstract translation: 公开了使用氢供体溶剂的煤褐煤或重油的液化方法。 优选的氢供体溶剂作为来自液化混合物的蒸气回收。 将蒸气转化成活性供氢溶剂形式的优选方法包括使蒸气通过位于催化剂容器的蒸气空间中的催化剂床上。 还公开了用于定位催化剂床的新型装置。
-
公开(公告)号：US4666589A
公开(公告)日：1987-05-19
申请号：US829904
申请日：1986-02-18
Applicant: Wolf-Dieter Klein , Alfons Feuchthofen , Claus Strecker , Ulrich Bonisch
Inventor： Wolf-Dieter Klein , Alfons Feuchthofen , Claus Strecker , Ulrich Bonisch
IPC: C10G1/06
CPC classification number: C10G1/065
Abstract: A method for pretreating a coal hydrogenation feedstock with preheated hydrogen containing a hydrogenation gas under high pressure and at elevated temperature, in a liquid phase slurry system, is disclosed. In this process a mixture of a slurry of finely ground coal and a slurry oil are fed to a preheater before being subjected to a hydrogenation and liquefaction reaction in a cascade of reactors at a pressure of from 100 to 40 bars and a temperature of 420.degree. to 490.degree. C. The reaction products are fed to a hot separator.In the process of the invention, prior to its preheating, a first partial stream of the hydrogenation gas, referred to as the slurry gas, is added to the mixture at process pressure. A second partial stream of the hydrogenation gas is heated by indirect heat exchange with a gaseous hot separator product in a gas heat exchanger. The mixture of slurry and slurry gas is preheated through indirect heat exchange in at least one heat exchanger downstream from the first gas heat exchanger, through which flows the hot separator head product after passing through the first heat exchanger. The heated second partial stream of hydrogenation gas is then added to the preheated mixture of slurry and slurry gas.This process provides improved heat transfer during the preheating of the coal-oil slurry and the mixture in a slurry with a hydrogenation gas.
Abstract translation: 公开了一种在液相浆料系统中，在高压和高温下预热含氢氢化气体的氢化原料的方法。 在该方法中，将精细研磨的煤和浆料油的浆料的混合物在100至40巴的压力和420℃的温度的级联反应器中进行氢化和液化反应之前进料到预热器中 至490℃。将反应产物进料至热分离器。 在本发明的方法中，在其预热之前，将氢化气体的第一部分流（称为浆料气体）在过程压力下加入混合物中。 通过在气体热交换器中与气态热分离器产物进行间接热交换来加热氢化气体的第二部分流。 浆料和浆料气体的混合物通过在第一气体热交换器下游的至少一个热交换器中的间接热交换进行预热，热分离器头产物在通过第一热交换器之后流过该热交换器。 然后将加热的第二部分氢化气体流加入到浆料和浆料气体的预热混合物中。 该过程在煤油浆料和混合物在加氢气体的浆料中预热期间提供了改进的热传递。
-
公开(公告)号：US4626342A
公开(公告)日：1986-12-02
申请号：US792393
申请日：1985-10-29
Applicant: Diwakar Garg , Swaminathan Sunder
Inventor： Diwakar Garg , Swaminathan Sunder
CPC classification number: C10G1/086
Abstract: An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids.
Abstract translation: 催化溶剂精制或在高温下在氢气压力下在溶剂中的非无烟煤的水解液的改进方法包括使用1,2-或1,4-醌与碱性化合物的混合物，其选自铵， 碱金属和碱土金属氧化物，弱酸的氢氧化物或盐。
-
-
-
-
-
-
-
-
-
Search Results
1142
records
(took 0.024 seconds)
