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公开(公告)号：US4230853A
公开(公告)日：1980-10-28
申请号：US80720
申请日：1979-10-01
申请人： Vittorio Messori , Renato Francese
发明人： Vittorio Messori , Renato Francese
IPC分类号： C07D251/28 , C07D251/44 , C07D251/50
CPC分类号： C07D251/44 , C07D251/28 , C07D251/50
摘要： In the commercial process for preparing chloro-bis(alkylamino)-s-triazines by step-wise replacement of two chlorine atoms of cyanuric chloride by means of alkylamino groups in which a molar excess of alkylamine is used in the second replacement step, the formation of tris(alkylamino)-s-triazines is suppressed by adding to the reaction mixture, after the second chlorine atom has been replaced with an alkylamino group, an oxidizing agent selected from the group consisting of hydrogen peroxide and alkali metal hypochlorites, persulphates and permanganates, in an amount of at least 1 equivalent for every mole of unreacted alkylamine present in the said reaction mixture.
摘要翻译： 在通过在第二替代步骤中通过使用摩尔过量的烷基胺的烷基氨基逐步置换氰尿酰氯的两个氯原子来制备氯 - 双（烷基氨基）-s-三嗪的商业方法中，形成 通过向反应混合物中加入三（烷基氨基）-s-三嗪的三烷基胺，在第二个氯原子被烷基氨基取代后，选自过氧化氢和碱金属次氯酸盐，过硫酸盐和高锰酸盐 ，对于存在于所述反应混合物中的每摩尔未反应的烷基胺，其量为至少1当量。
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公开(公告)号：US4224444A
公开(公告)日：1980-09-23
申请号：US80721
申请日：1979-10-01
申请人： Luciano Baldi , Vittorio Messori , Renato Francese
发明人： Luciano Baldi , Vittorio Messori , Renato Francese
IPC分类号： C07D251/44 , C07D251/50
CPC分类号： C07D251/50 , C07D251/44
摘要： Chloro-bis(alkylamino)-s-triazine is prepared by means of the step-wise replacement of two chlorine atoms of cyanuric chloride with alkylamino groups in an alkaline medium comprising water and a liquid organic compound which is a solvent for cyanuric chloride and forms a two-phase system with water, in which a molar excess of alkylamine is used in the second replacement step. Upon completion of the second replacement step the reaction mixture is freed from its aqueous phase and the residual suspension or solution of triazine in the organic compound is admixed with water added in a volumetric quantity of from 30 to 150% with respect to that of said aqueous phase.The chloro-bis(alkylamino)-s-triazine thus produced has high characteristics of handling and formulability.
摘要翻译： 通过在包含水的碱性介质和作为氰尿酰氯的溶剂的液体有机化合物中逐步取代氰尿酰氯与烷基氨基的两个氯原子来制备氯 - 双（烷基氨基）-s-三嗪 具有水的两相体系，其中在第二替代步骤中使用摩尔过量的烷基胺。 完成第二次置换步骤后，将反应混合物从其水相中除去，并将有机化合物中三嗪的剩余悬浮液或溶液与相对于所述水相的体积量为30至150％的水混合 相。 这样制备的氯 - 双（烷基氨基）-s-三嗪具有高的处理和配方特性。
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公开(公告)号：US4232153A
公开(公告)日：1980-11-04
申请号：US922698
申请日：1978-07-07
IPC分类号： C07D251/44 , C07D251/50
CPC分类号： C07D251/50 , C07D251/44
摘要： Chloro-bis(alkylamino)-s-triazines are prepared by step-wise replacement of two chlorine atoms of cyanuric chloride with alkylamino groups.Cyanuric chloride, an inorganic base and an alkylamine are continuously fed to a first tubular zone in stoichiometric proportions and reacted therein under turbulent conditions, at an elevated temperature not exceeding 90.degree. C., and for a short reaction time, and the reaction product is continuously fed to a second tubular reaction zone together with stoichiometric quantities of inorganic base and of a second alkylamine, and reacted therein with the latter at an elevated temperature not exceeding 100.degree. C., under turbulent conditions and for a short reaction time.
摘要翻译： 通过用烷基氨基逐步取代氰尿酰氯的两个氯原子来制备氯 - 双（烷基氨基）-s-三嗪。 将氰尿酰氯，无机碱和烷基胺以化学计量比连续进料到第一管状区域，并在湍流条件下在不超过90℃的高温下反应，反应时间短 与化学计量的无机碱和第二烷基胺一起连续进料到第二管状反应区，并在不超过100℃的升高温度下在湍流条件下反应并在短时间内与其反应。
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公开(公告)号：US4182874A
公开(公告)日：1980-01-08
申请号：US953320
申请日：1978-10-20
IPC分类号： C07D251/44 , C07D251/50
CPC分类号： C07D251/50 , C07D251/44
摘要： The commercial method of preparing chloro-bis(alkylamino)-s-triazine by step-wise replacement of two chlorine atoms of cyanuric chloride by means of alkylamino groups in an alkaline medium comprising water and a liquid organic compound is improved by adding to the reaction product, upon completion of the second replacement step, or during or after the distillation of the organic compound, at least 0.5% by weight with respect to the weight of the chloro-bis(alkylamino)-s-triazine, of minerals chosen from the groups of montmorillonite, paligorskite, vermiculite and chlorite and having a base-exchange capacity of at least 10 milli-equivalents for each 100 grams of said solid, thus deactivating the unreacted alkylamine and the tris(alkylamino)-s-triazines present in the reaction product.
摘要翻译： 通过在包含水和液体有机化合物的碱性介质中通过烷基氨基逐步置换氰尿酰氯的两个氯原子来制备氯 - 双（烷基氨基）-s-三嗪的商业方法通过向反应中加入 产物，在完成第二次置换步骤之后，或在蒸馏有机化合物之前或之后，相对于氯 - 双（烷基氨基） - 三嗪的重量，至少0.5重量％的矿物质选自 一组蒙脱石，paligorskite，蛭石和亚氯酸盐，并且对于每100克所述固体具有至少10毫当量的碱交换容量，从而使反应中存在的未反应的烷基胺和三（烷基氨基）-S-三嗪失活 产品。
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公开(公告)号：US4099006A
公开(公告)日：1978-07-04
申请号：US645137
申请日：1975-12-29
申请人： Luciano Baldi , Corrado Ferrari , Renato Francese
发明人： Luciano Baldi , Corrado Ferrari , Renato Francese
IPC分类号： C07D251/44 , C07D251/50
CPC分类号： C07D251/44 , C07D251/50
摘要： 2-CHLORO-S-TRIAZINE SUBSTITUTED IN AT LEAST ONE OF THE POSITIONS 4,6 OF THE TRIAZINE RING WITH AN AMINO GROUP IS OBTAINED BY FEEDING SEPARATELY AN AQUEOUS AMINE SOLUTION AND AN AQUEOUS NaOH solution into a water-organic liquid reaction medium containing cyanuric chloride, delivering to said medium per unit of time from 1.05 to 1.30 moles of amine for each mole of sodium hydroxide, feeding the amine solution until an amount of from 1 to 2 moles of amine per mole of cyanuric chloride is reached in the medium and the NaOH solution until an amount in moles equal to or slightly higher than the amount of amine moles fed in is reached in the medium. The temperature of the reaction medium is maintained at a value of from 5.degree.-15.degree. C to 60.degree.-70.degree. C during the feeding period.
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公开(公告)号：US4328369A
公开(公告)日：1982-05-04
申请号：US224998
申请日：1981-01-14
IPC分类号： C07C85/04
CPC分类号： C07C209/10
摘要： 2,6-dinitro-N-alkyl-anilines are prepared by continuously delivering a 2,6-dinitro-chlorobenzene, a dialkylamine, an inorganic base and water to a tubular reaction zone and operating in said reaction zone under turbulent conditions, at a temperature not exceeding 150.degree. C., for a short reaction time and with substantially complete conversion of the chlorobenzene.
摘要翻译： 通过将2,6-二硝基氯苯，二烷基胺，无机碱和水连续输送到管状反应区并在湍流条件下在所述反应区中操作来制备2,6-二硝基-N-烷基苯胺， 温度不超过150℃，反应时间短，氯苯基本上完全转化。
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公开(公告)号：US4182875A
公开(公告)日：1980-01-08
申请号：US953319
申请日：1978-10-20
申请人： Renato Francese , Roberto Esposito
发明人： Renato Francese , Roberto Esposito
IPC分类号： C07D251/44 , C07D251/50
CPC分类号： C07D251/44 , C07D251/50
摘要： In the commercial process for preparing chloro-bis(aklylamino)-s-triazines by step-wise replacement of two chlorine atoms of cyanuric chloride with alkylamino groups in which a molar excess of alkylamine is used in the second replacement step, the formation of tris-(alkylamino)-s-triazines is suppressed by submitting the reaction mixture, after the second replacement step is completed, to a pressure not exceeding 400 mm Hg, at a temperature not exceeding about 55.degree. C. and for a period not exceeding about 15 minutes, thereby removing the excess alkylamine from said reaction mixture by volatilization without substantially removing the other components of the reaction mixture.
摘要翻译： 在通过在第二次置换步骤中逐步取代氰尿酰氯的两个氯原子与其中使用摩尔过量的烷基胺的烷基氨基进行制备氯 - 双（甲基氨基）-s-三嗪的商业方法中，形成三 - （烷基氨基）-s-三嗪通过在第二次更换步骤完成后将反应混合物置于不超过400mm Hg的压力下，在不超过约55℃的温度下进行并且不超过约 15分钟，从而通过挥发而从基本上除去反应混合物的其它组分而从所述反应混合物中除去过量的烷基胺。
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公开(公告)号：US4275204A
公开(公告)日：1981-06-23
申请号：US73360
申请日：1979-09-07
IPC分类号： C07D251/50
CPC分类号： C07D251/50
摘要： Chloro-bis(alkylamino)-s-triazines are prepared by step-wise replacement of two chlorine atoms of cyanuric chloride by reaction with amines and alkali metal hydroxide in a medium comprising water and a liquid organic compound which is a solvent for cyanuric chloride and is substantially immiscible with water, the first step being carried out by contacting a first amine with a reaction medium containing the cyanuric chloride and the whole of the alkali metal hydroxide used for the step-wise replacement.
摘要翻译： 通过在包含水和作为氰尿酰氯的溶剂的液体有机化合物的介质中与胺和碱金属氢氧化物反应来逐步替代氰尿酰氯的两个氯原子来制备氯 - 双（烷基氨基）-s-三嗪， 与水基本上不混溶，第一步是通过使第一胺与含有氰尿酰氯的反应介质和用于逐步置换的全部碱金属氢氧化物接触来进行。
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