公开(公告)号：US4275204A

公开(公告)日：1981-06-23

申请号：US73360

申请日：1979-09-07

申请人： Vittorio Messori ,  Renato Francese ,  Roberto Esposito

发明人： Vittorio Messori ,  Renato Francese ,  Roberto Esposito

IPC分类号： C07D251/50

CPC分类号： C07D251/50

摘要： Chloro-bis(alkylamino)-s-triazines are prepared by step-wise replacement of two chlorine atoms of cyanuric chloride by reaction with amines and alkali metal hydroxide in a medium comprising water and a liquid organic compound which is a solvent for cyanuric chloride and is substantially immiscible with water, the first step being carried out by contacting a first amine with a reaction medium containing the cyanuric chloride and the whole of the alkali metal hydroxide used for the step-wise replacement.

摘要翻译： 通过在包含水和作为氰尿酰氯的溶剂的液体有机化合物的介质中与胺和碱金属氢氧化物反应来逐步替代氰尿酰氯的两个氯原子来制备氯 - 双（烷基氨基）-s-三嗪， 与水基本上不混溶，第一步是通过使第一胺与含有氰尿酰氯的反应介质和用于逐步置换的全部碱金属氢氧化物接触来进行。

公开(公告)号：US4182875A

公开(公告)日：1980-01-08

申请号：US953319

申请日：1978-10-20

申请人： Renato Francese ,  Roberto Esposito

发明人： Renato Francese ,  Roberto Esposito

IPC分类号： C07D251/44 ,  C07D251/50

CPC分类号： C07D251/44 ,  C07D251/50

摘要： In the commercial process for preparing chloro-bis(aklylamino)-s-triazines by step-wise replacement of two chlorine atoms of cyanuric chloride with alkylamino groups in which a molar excess of alkylamine is used in the second replacement step, the formation of tris-(alkylamino)-s-triazines is suppressed by submitting the reaction mixture, after the second replacement step is completed, to a pressure not exceeding 400 mm Hg, at a temperature not exceeding about 55.degree. C. and for a period not exceeding about 15 minutes, thereby removing the excess alkylamine from said reaction mixture by volatilization without substantially removing the other components of the reaction mixture.

摘要翻译： 在通过在第二次置换步骤中逐步取代氰尿酰氯的两个氯原子与其中使用摩尔过量的烷基胺的烷基氨基进行制备氯 - 双（甲基氨基）-s-三嗪的商业方法中，形成三 - （烷基氨基）-s-三嗪通过在第二次更换步骤完成后将反应混合物置于不超过400mm Hg的压力下，在不超过约55℃的温度下进行并且不超过约 15分钟，从而通过挥发而从基本上除去反应混合物的其它组分而从所述反应混合物中除去过量的烷基胺。