公开(公告)号：US6060617A

公开(公告)日：2000-05-09

申请号：US670348

申请日：1996-06-25

申请人： Randy W. Hall ,  Bobby J. McElroy ,  James A. Schwindeman ,  Conrad W. Kamienski ,  Terry L. Rathman ,  Robert C. Morrison

发明人： Randy W. Hall ,  Bobby J. McElroy ,  James A. Schwindeman ,  Conrad W. Kamienski ,  Terry L. Rathman ,  Robert C. Morrison

IPC分类号： C07C211/65 ,  C07F7/10

CPC分类号： C07F7/10 ,  C07C211/65

摘要： Organometallic amide compositions and processes for preparing the same, for example, by: reacting an alkali metal, alkali metal hydride, or alkali metal amide with a substituted amine in the absence of an electron carrier; reacting an alkali metal with a substituted amine in the presence of an electron carrier in a hydrocarbon solvent; distilling a composition which includes an alkali metal amide and a reduced electron carrier to recover the alkali metal amide; reacting an alkali metal with a substituted amine in the presence of an alkyl halide; and reacting a substituted amine capable of reacting with an alkali metal to form a hydrocarbon insoluble alkali metal amide with an alkali metal in the presence of a substituted amine capable of reacting with an alkali metal to form a hydrocarbon soluble alkali metal amide.

摘要翻译： 有机金属酰胺组合物及其制备方法，例如：在不存在电子载体的情况下使碱金属，碱金属氢化物或碱金属氨化物与取代的胺反应; 在电子载体存在下在烃溶剂中使碱金属与取代的胺反应; 蒸馏包含碱金属氨化物和还原电子载体以回收碱金属胺的组合物; 在烷基卤存在下使碱金属与取代的胺反应; 并使能够与碱金属反应的取代的胺与能够与碱金属反应形成烃溶性碱金属氨化物的取代胺存在下与碱金属形成不溶于烃的碱金属胺。