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1.发明授权Ruthenium-cobalt carbonyl catalysts for the dealkoxyhydroxymethylation of acetals to form glycol ethers 失效用于乙缩醛脱甲基羟甲基化形成二醇醚的钌 - 钴羰基催化剂
公开(公告)号：US4663489A
公开(公告)日：1987-05-05
申请号：US859514
申请日：1986-05-05
CPC分类号： B01J31/1608 , B01J31/20 , B01J31/2265 , C07C41/01 , C07C41/30 , C07C43/13 , B01J2231/34 , B01J2231/641 , B01J2531/0211 , B01J2531/821 , B01J2531/845
摘要： The cobalt carbonyl catalyst R.sup.5 CCo.sub.3 (CO).sub.9, desirably with Ru.sub.3 (CO).sub.12, wherein R.sup.5 is hydrogen; alkyl, preferably C.sub.1-5 lower alkyl; cycloalkyl or substituted cycloalkyl; cycloalkenyl, such as cyclohexenyl or cyclooctenyl; C.sub.1-12 alkoxy, such as methoxy or propoxy; aryl or alkyl-, cycloalkyl-, alkoxy-, halo-, or cyano-substituted aryl; cyano; or a silyl carbyne moiety of the formula R.sub.3.sup.6 Si, wherein R.sup.6 is alkyl or aryl, effectively catalyzes the dealkoxyhydroxymethylation of aldehyde acetals to form glycol monoethers. Methylal, for example, may be reacted with syngas; i.e., CO and H.sub.2, in the presence of this catalyst system to form the corresponding ethylene glycol monomethyl ether.The novel catalyst combination of R.sup.5 CCo.sub.3 (CO).sub.9 and Ru.sub.3 (CO).sub.12 is likewise claimed herein.
摘要翻译： 钴羰基催化剂R5CCo3（CO）9，理想地含有Ru 3（CO）12，其中R 5是氢; 烷基，优选C 1-5低级烷基; 环烷基或取代的环烷基; 环烯基，例如环己烯基或环辛烯基; C 1-12烷氧基，如甲氧基或丙氧基; 芳基或烷基 - ，环烷基 - ，烷氧基 - ，卤代或氰基取代的芳基; 氰基; 或式R36Si的甲硅烷基卡宾部分，其中R6是烷基或芳基，有效地催化醛缩醛的脱烷基羟甲基化以形成二醇单醚。 甲缩醛例如可以与合成气反应; 即CO和H 2，在该催化剂体系的存在下形成相应的乙二醇单甲醚。 本文还要求R5CCo3（CO）9和Ru3（CO）12）的新型催化剂组合。
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2.发明授权Ruthenium-cobalt carbonyl metal cluster catalysts for the dealkoxyhydroxymethylation of acetals to form glycol ethers 失效钌钴羰基金属簇催化剂，用于乙缩醛脱甲基羟甲基化形成二醇醚
公开(公告)号：US4618729A
公开(公告)日：1986-10-21
申请号：US782807
申请日：1985-10-02
CPC分类号： B01J31/20 , C07C41/01 , C07C41/30 , B01J2231/34 , B01J2231/641 , B01J2531/0211 , B01J2531/821 , B01J2531/845
摘要： The ruthenium-cobalt carbonyl metal cluster catalyst Co.sub.2 Ru(CO).sub.11 effectively catalyzes the dealkoxyhydroxymethylation of aldehyde acetals to form glycol monoethers. Methylal, for example, may be reacted with syngas, i.e., CO and H.sub.2, in the presence of this ruthenium-cobalt cluster catalyst to form the monomethyl ether of ethylene glycol.
摘要翻译： 钌钴羰基金属簇催化剂Co2Ru（CO）11有效地催化醛缩醛的脱烷基羟甲基化形成二醇单醚。 在这种钌 - 钴簇催化剂的存在下，例如甲缩醛可与合成气（即CO和H 2）反应，形成乙二醇的单甲基醚。
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3.发明授权Phosphonite-and phosphinite-promoted ruthenium - cobalt catalysts for the dealkoxyhydroxymethylation of acetals to form glycol ethers 失效亚磷酸盐和磷化物促进的钌 - 钴催化剂用于乙缩醛脱甲基羟甲基化以形成二醇醚
公开(公告)号：US4895818A
公开(公告)日：1990-01-23
申请号：US238435
申请日：1988-08-31
CPC分类号： C07C41/30 , B01J31/0261 , B01J31/0262 , B01J31/20 , B01J2231/34 , B01J2231/641 , B01J2531/0211 , B01J2531/821 , B01J2531/845
摘要： Ruthenium cobalt- or cobalt-containing catalysts which have been promoted with phosphonites or phosphinites effectively catalyze the dealkoxyhydroxymethylation of aldehyde acetals to form glycol monoethers. Methylal, for example, may be reacted with syngas, i.e., CO and H.sub.2, in the presence of these phosphonite- or phosphinite-promoted cobalt or ruthenium- cobalt catalysts to form the monomethyl ether of ethylene glycol. In a like manner acetaldehyde may be converted to the corresponding propylene glycol monoether. The process may advantageously be carried out with high yields and selectivities in the presence of a polar or non-polar organic solvent in combination with the catalyst system of this invention.The invention is also directed to the phosphonite- or phosphinite-promoted cobalt and ruthenium-cobalt catalyst systems per se.
摘要翻译： 已经用亚膦酸盐或次膦酸盐促进的含钌钴或钴的催化剂有效地催化醛缩醛的脱烷基羟甲基化以形成二醇单醚。 甲缩醛例如可以在合成气（即CO和H 2）的存在下，在这些亚膦酸盐或次膦酸盐促进的钴或钌 - 钴催化剂的存在下反应以形成乙二醇的单甲基醚。 以类似方式，乙醛可以转化成相应的丙二醇单醚。 在极性或非极性有机溶剂与本发明的催化剂体系的组合下，该方法可以有利地以高产率和选择性进行。 本发明还涉及亚膦酸盐或膦酸盐促进的钴和钌 - 钴催化剂体系本身。
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4.发明授权Phosphonite-and phosphonite-promoted ruthenium - cobalt catalysts for the dealkoxyhydroxymethylation of acetals to form glycol ethers 失效亚膦酸酯和亚膦酸盐促进的钌 - 钴催化剂用于缩醛的脱烷基羟甲基化形成二醇醚
公开(公告)号：US4895987A
公开(公告)日：1990-01-23
申请号：US871351
申请日：1986-06-06
CPC分类号： C07C41/30 , B01J31/0261 , B01J31/0262 , B01J31/20 , B01J2231/34 , B01J2231/641 , B01J2531/0211 , B01J2531/821 , B01J2531/845
摘要： Ruthenium-cobalt- or cobalt-containing catalysts which have been promoted with phosphonites or phosphinites effectively catalyze the dealkoxyhydroxymethylation of aldehyde acetals to form glycol monoethers. Methylal, for example, may be reacted with syngas, i.e., CO and H.sub.2, in the presence of these phosphonite- or phosphinite-promoted cobalt or ruthenium- cobalt catalysts to form the monomethyl ether of ethylene glycol. In a like manner acetaldehyde may be converted to the corresponding propylene glycol monoether. The process may advantageously be carried out with high yields and selectivities in the presence of a polar or non-polar organic solvent in combination with the catalyst system of this invention.The invention is also directed to the phosphonite- or phosphonite-promoted cobalt and ruthenium-cobalt catalyst system per se.
摘要翻译： 已经用亚膦酸盐或次膦酸盐促进的含钌钴或钴的催化剂有效地催化醛缩醛的脱烷基羟甲基化形成二醇单醚。 甲缩醛例如可以在合成气（即CO和H 2）的存在下，在这些亚膦酸盐或次膦酸盐促进的钴或钌 - 钴催化剂的存在下反应以形成乙二醇的单甲基醚。 以类似方式，乙醛可以转化成相应的丙二醇单醚。 在极性或非极性有机溶剂与本发明的催化剂体系的组合下，该方法可以有利地以高产率和选择性进行。 本发明还涉及亚膦酸盐或亚膦酸盐促进的钴和钌 - 钴催化剂体系本身。
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5.发明授权Phosphite-promoted ruthenium-cobalt catalysts for the dealkoxyhydroxymethylation of acetals to form glycol ethers 失效亚磷酸酯促进的钌 - 钴催化剂用于缩醛的脱烷基羟甲基化以形成二醇醚
公开(公告)号：US4692426A
公开(公告)日：1987-09-08
申请号：US901861
申请日：1986-08-29
CPC分类号： B01J31/0259 , B01J31/1608 , B01J31/185 , B01J31/20 , B01J31/2265 , C07C41/01 , C07C41/30 , C07C43/13 , B01J2231/34 , B01J2231/641 , B01J2531/0211 , B01J2531/821 , B01J2531/845
摘要： Ruthenium-cobalt carbonyl catalysts which have been promoted with an organophosphite effectively catalyze the dealkoxyhydroxymethylation of aldehyde acetals to form glycol monoethers. Methylal, for example, may be reacted with syngas, i.e., CO and H.sub.2, in the presence of this phosphite-promoted ruthenium carbonyl cobalt catalyst to form the monomethyl ether of ethylene glycol. In a like manner acetaldehyde may be converted to the corresponding propylene glycol monoether. The process may advantageously be carried out with high yields and selectivities in the presence of a polar or non-polar organic solvent in combination with the catalyst system of this invention.The invention is also directed to certain of the organophosphite-promoted cobalt and ruthenium-cobalt carbonyl catalyst systems per se.
摘要翻译： 已经用有机亚磷酸酯促进的钌 - 钴羰基催化剂有效地催化醛缩醛的脱烷基羟甲基化以形成二醇单醚。 在该亚磷酸盐促进的羰基钴钌催化剂的存在下，例如甲醛可以与合成气即CO和H 2反应，形成乙二醇的单甲基醚。 以类似方式，乙醛可以转化成相应的丙二醇单醚。 在极性或非极性有机溶剂与本发明的催化剂体系的组合下，该方法可以有利地以高产率和选择性进行。 本发明还涉及某些有机亚磷酸酯促进的钴和钌 - 钴羰基催化剂体系本身。
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6.发明授权Ruthenium-cobalt carbonyl catalysts for the dealkoxyhydroxymethylation of acetals to form glycol ethers 失效用于乙缩醛脱甲基羟甲基化形成二醇醚的钌 - 钴羰基催化剂
公开(公告)号：US4652542A
公开(公告)日：1987-03-24
申请号：US782805
申请日：1985-10-02
CPC分类号： B01J31/1608 , B01J31/20 , B01J31/2265 , C07C41/01 , C07C41/30 , C07C43/13 , B01J2231/34 , B01J2231/641 , B01J2531/0211 , B01J2531/821 , B01J2531/845
摘要： The cobalt carbonyl catalyst R.sup.5 CCo.sub.3 (CO).sub.9, desirably with Ru.sub.3 (CO).sub.12, wherein R.sup.5 is hydrogen; alkyl, preferably C.sub.1-5 lower alkyl; cycloalkyl or substituted cycloalkyl; cycloalkenyl, such as cyclohexenyl or cyclooctenyl; C.sub.1-12 alkoxy, such as methoxy or propoxy; aryl or alkyl-, cycloalkyl-, alkoxy-, halo-, or cyano-substituted aryl; cyano; or a silyl carbyne moiety of the formula R.sub.3.sup.6 Si, wherein R.sup.6 is alkyl or aryl, effectively catalyzes the dealkoxyhydroxymethylation of aldehyde acetals to form glycol monoethers. Methylal, for example, may be reacted with syngas; i.e., CO and H.sub.2, in the presence of this catalyst system to form the corresponding ethylene glycol monomethyl ether.
摘要翻译： 钴羰基催化剂R5CCo3（CO）9，理想地含有Ru 3（CO）12，其中R 5是氢; 烷基，优选C 1-5低级烷基; 环烷基或取代的环烷基; 环烯基，例如环己烯基或环辛烯基; C 1-12烷氧基，如甲氧基或丙氧基; 芳基或烷基 - ，环烷基 - ，烷氧基 - ，卤代或氰基取代的芳基; 氰基; 或式R36Si的甲硅烷基卡宾部分，其中R6是烷基或芳基，有效地催化醛缩醛的脱烷基羟甲基化以形成二醇单醚。 甲缩醛例如可以与合成气反应; 即CO和H 2，在该催化剂体系的存在下形成相应的乙二醇单甲醚。
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