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1.发明申请Processes for Epimerizing Cyclohexenyl Ketones with Subsequent Aldol Condensation to Produce Fragrance Compounds 有权用于使环己烯酮差向异构化的方法，随后的醛醇缩合产生香料化合物公开(公告)号：US20110152575A1
公开(公告)日：2011-06-23
申请号：US12641786
申请日：2009-12-18
申请人： Daniel Martin Bourgeois , Gregory Scot Miracle , Phillip John Porter , Eva Boros , Kenneth Richard Seddon , Harambage Quintus Nimal Gunaratne
发明人： Daniel Martin Bourgeois , Gregory Scot Miracle , Phillip John Porter , Eva Boros , Kenneth Richard Seddon , Harambage Quintus Nimal Gunaratne
IPC分类号： C07C45/67
CPC分类号： C07C45/69 , Y02P20/582 , C07C49/543
摘要： The present disclosure describes processes for the epimerization of a cyclohexene comprising the steps of providing to a reactor a first isomer of a 1-(2-alkyl-3-cyclohexen-1-yl)-alkanone compound according to Formula I wherein R1 ad R2 are each independently C1-C4 alkyl, and R3, R4, R5, R6, R7, and R8 are each independently selected from the group consisting of H and C1-C4 alkyl; and epimerizing the first isomer of the 1-(2-alkyl-3-cyclohexen-1-yl)-alkanone with a metal alkoxide base to form a second isomer of the 1-(2-alkyl-3-cyclohexen-1-yl)-alkanone.
摘要翻译： 本公开描述了环己烯差向异构化的方法，包括以下步骤：向反应器提供根据式I的1-（2-烷基-3-环己烯-1-基） - 烷酮化合物的第一异构体，其中R1至R2 各自独立地为C 1 -C 4烷基，R 3，R 4，R 5，R 6，R 7和R 8各自独立地选自H和C 1 -C 4烷基; 并用金属醇盐碱使1-（2-烷基-3-环己烯-1-基） - 烷酮的第一异构体差向异构化，以形成1-（2-烷基-3-环己烯-1-基 ） - 烷酮。
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公开(公告)号：US08067644B2
公开(公告)日：2011-11-29
申请号：US12641818
申请日：2009-12-18
申请人： Daniel Martin Bourgeois , Gregory Scot Miracle , Phillip John Porter , Eva Boros , Kenneth Richard Seddon , Harambage Quintus Nimal Gunaratne
发明人： Daniel Martin Bourgeois , Gregory Scot Miracle , Phillip John Porter , Eva Boros , Kenneth Richard Seddon , Harambage Quintus Nimal Gunaratne
CPC分类号： C07C403/16 , C07C45/69 , C07C2601/16 , C07C49/543
摘要： The present disclosure describes processes for producing cyclohexenes using Lewis acidic ionic liquids comprising the steps of providing to a reactor an α,β-unsaturated carbonyl dienophile, providing to the reactor a 1,3-diene, providing a Lewis acidic ionic liquid to the reactor; and reacting the α,β-unsaturated carbonyl dienophile with 1,3-diene to form a substituted cyclohexene product. The α,β-unsaturated carbonyl dienophile can be mesityl oxide, the 1,3-diene can be piperylene; and the Lewis acidic ionic liquid can be AlCl3:[C2mim]Cl; AlCl3:[C8mim]Cl; or mixtures thereof.
摘要翻译： 本公开描述了使用路易斯酸性离子液体生产环己烯的方法，包括以下步骤：向反应器提供α，β-不饱和羰基亲二烯体，向反应器提供1,3-二烯，向该反应器提供路易斯酸性离子液体 反应堆; 并使α和bgr-不饱和羰基亲二烯体与1,3-二烯反应形成取代的环己烯产物。 α，β-不饱和羰基亲电体可以是二甲苯，1,3-二烯可以是戊间二烯; 并且Lewis酸性离子液体可以是AlCl 3：[C2mim] Cl; AlCl 3：[C8mim] Cl; 或其混合物。
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3.发明授权Process for epimerising cyclohexenyl ketones and its application in Aldol condensation process 失效差向异构化环己烯酮的方法及其在醛醇缩合过程中的应用公开(公告)号：US07414158B2
公开(公告)日：2008-08-19
申请号：US11880509
申请日：2007-07-23
申请人： Yousef Georges Aouad , Daniel Martin Bourgeois , Gregory Scot Miracle , Jean Wevers , Harambage Quintas Nimal Gunaratne , Kenneth Richard Seddon , Eva Boros , Suhas Prabhaker Katdore , Tayeb Belhocine
发明人： Yousef Georges Aouad , Daniel Martin Bourgeois , Gregory Scot Miracle , Jean Wevers , Harambage Quintas Nimal Gunaratne , Kenneth Richard Seddon , Eva Boros , Suhas Prabhaker Katdore , Tayeb Belhocine
CPC分类号： C07C45/67 , C07C45/69 , C07C2601/18 , C07C49/543
摘要： Processes for producing intermediate materials used for perfumery, specifically, epimerized cyclohexenyl ketones, are disclosed. Processes for employing the epimerising reaction in an Aldol condensation reaction are also disclosed.
摘要翻译： 公开了用于制造用于香料的中间体材料，特别是差向异构环己烯酮的方法。 还公开了在醛缩醇缩合反应中使用差向异构化反应的方法。
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4.发明授权Conversion of sodium bromide to anhydrous hydrobromic acid and sodium bisulfate 失效将溴化钠转化成无水氢溴酸和硫酸氢钠公开(公告)号：US07045109B2
公开(公告)日：2006-05-16
申请号：US10993040
申请日：2004-11-19
IPC分类号： C01B7/09
摘要： Process for the conversion of sodium bromide to anhydrous hydrobromic acid and sodium bisulfate, said process with the following sequential steps: reaction of sodium bromide and sulfuric acid in a solution of water to produce hydrobromic acid and sodium bisulfate wherein the conversion of sodium bromide is greater than about 99%; adsorption of iron bromide onto a solid adsorbent; separation of hydrobromic acid and water from the sodium bisulfate; separation and drying of hydrobromic acid; and solidification of the sodium bisulfate into a flaked or granular form.
摘要翻译： 将溴化钠转化为无水氢溴酸和硫酸氢钠的方法，所述方法按以下顺序步骤：将溴化钠和硫酸在水溶液中反应生成氢溴酸和硫酸氢钠，其中溴化钠的转化率较大 比约99％; 将溴化铁吸附在固体吸附剂上; 从硫酸氢钠中分离氢溴酸和水; 氢溴酸的分离和干燥; 并将硫酸氢钠固化成片状或颗粒状。
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5.发明授权Conversion of sodium bromide to anhydrous hydrobromic acid and sodium bisulfate 失效将溴化钠转化成无水氢溴酸和硫酸氢钠公开(公告)号：US06811763B2
公开(公告)日：2004-11-02
申请号：US10265812
申请日：2002-10-07
IPC分类号： C01B709
摘要： Process for the conversion of sodium bromide to anhydrous hydrobromic acid and sodium bisulfate, said process with the following sequential steps: reaction of sodium bromide and sulfuric acid in a solution of water to produce hydrobromic acid and sodium bisulfate wherein the conversion rate is greater than about 95%; separation of hydrobromic acid and water from the sodium bisulfate; separation of hydrobromic acid from water; and drying of hydrobromic acid.
摘要翻译： 所述方法用以下顺序步骤将溴化钠转化成无水氢溴酸和硫酸氢钠的方法：将溴化钠和硫酸在水溶液中反应生成氢溴酸和硫酸氢钠，其中转化率大于约 95％; 从硫酸氢钠中分离氢溴酸和水; 氢溴酸与水分离; 并干燥氢溴酸。
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6.发明授权Processes for epimerizing cyclohexenyl ketones with subsequent aldol condensation to produce fragrance compounds 有权使环己烯基酮差向异构化的方法与随后的醛醇缩合产生香料化合物公开(公告)号：US08093432B2
公开(公告)日：2012-01-10
申请号：US12641786
申请日：2009-12-18
申请人： Daniel Martin Bourgeois , Gregory Scot Miracle , Phillip John Porter , Eva Boros , Kenneth Richard Seddon , Harambage Quintus Nimal Gunaratne
发明人： Daniel Martin Bourgeois , Gregory Scot Miracle , Phillip John Porter , Eva Boros , Kenneth Richard Seddon , Harambage Quintus Nimal Gunaratne
IPC分类号： C07C45/67
CPC分类号： C07C45/69 , Y02P20/582 , C07C49/543
摘要： The present disclosure describes processes for the epimerization of a cyclohexene comprising the steps of providing to a reactor a first isomer of a 1-(2-alkyl-3-cyclohexen-1-yl)-alkanone compound according to Formula I wherein R1 ad R2 are each independently C1-C4 alkyl, and R3, R4, R5, R6, R7, and R8 are each independently selected from the group consisting of H and C1-C4 alkyl; and epimerizing the first isomer of the 1-(2-alkyl-3-cyclohexen-1-yl)-alkanone with a metal alkoxide base to form a second isomer of the 1-(2-alkyl-3-cyclohexen-1-yl)-alkanone.
摘要翻译： 本公开描述了环己烯差向异构化的方法，包括以下步骤：向反应器提供根据式I的1-（2-烷基-3-环己烯-1-基） - 烷酮化合物的第一异构体，其中R1至R2 各自独立地为C 1 -C 4烷基，R 3，R 4，R 5，R 6，R 7和R 8各自独立地选自H和C 1 -C 4烷基; 并用金属醇盐碱使1-（2-烷基-3-环己烯-1-基） - 烷酮的第一异构体差向异构化，以形成1-（2-烷基-3-环己烯-1-基 ） - 烷酮。
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公开(公告)号：US20110152566A1
公开(公告)日：2011-06-23
申请号：US12641818
申请日：2009-12-18
申请人： Daniel Martin Bourgeois , Gregory Scot Miracle , Phillip John Porter , Eva Boros , Kenneth Richard Seddon , Harambage Quintus Nimal Gunaratne
发明人： Daniel Martin Bourgeois , Gregory Scot Miracle , Phillip John Porter , Eva Boros , Kenneth Richard Seddon , Harambage Quintus Nimal Gunaratne
CPC分类号： C07C403/16 , C07C45/69 , C07C2601/16 , C07C49/543
摘要： The present disclosure describes processes for producing cyclohexenes using Lewis acidic ionic liquids comprising the steps of providing to a reactor an α,β-unsaturated carbonyl dienophile, providing to the reactor a 1,3-diene, providing a Lewis acidic ionic liquid to the reactor; and reacting the α,β-unsaturated carbonyl dienophile with 1,3-diene to form a substituted cyclohexene product. The α,β-unsaturated carbonyl dienophile can be mesityl oxide, the 1,3-diene can be piperylene; and the Lewis acidic ionic liquid can be AlCl3:[C2mim]Cl; AlCl3:[C8mim]Cl; or mixtures thereof.
摘要翻译： 本公开描述了使用路易斯酸性离子液体生产环己烯的方法，包括以下步骤：向反应器提供α，β-不饱和羰基亲二烯体，向反应器提供1,3-二烯，向该反应器提供路易斯酸性离子液体 反应堆; 并使α，b' - 不饱和羰基亲二烯体与1,3-二烯反应，形成取代的环己烯产物。 α，β-不饱和羰基亲电体可以是二甲苯，1,3-二烯可以是戊间二烯; 并且Lewis酸性离子液体可以是AlCl 3：[C2mim] Cl; AlCl 3：[C8mim] Cl; 或其混合物。
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