公开(公告)号：US4980425A

公开(公告)日：1990-12-25

申请号：US372311

申请日：1989-06-28

申请人： Heinz Uhrig ,  Erich Ackermann ,  Alexander Sieber

发明人： Heinz Uhrig ,  Erich Ackermann ,  Alexander Sieber

IPC分类号： A01N25/30 ,  B01F17/34 ,  B01F17/42 ,  B01F17/52 ,  C08G8/04 ,  C08G8/28 ,  C08G8/36 ,  C08G65/28 ,  C09B67/46 ,  C11D1/74 ,  C11D7/50 ,  D06P1/60

CPC分类号： C08G8/36 ,  C08G8/28 ,  C09B67/0085 ,  Y10S516/02

摘要： The ever increasing demands on dispersants, emulsifiers and formulation aids, in particular in the preparation of azo dyes and pigments and in the preparation of dye and pigment dispersions, made it necessary to develop novel surface-active compounds.According to the invention, it has been possible by esterification of hydroxynaphthalenecarboxylic acids (on the carboxyl) with fatty alcohols or preferably with alkoxylates of fatty acids, resin acids or alkylphenols, condensation of the resulting esterification products with aldehydes to give novolak resins with subsequent alkoxylation and esterification of terminal OH groups with resin acids, fatty acids, aromatic carboxylic acids and hydroxycarboxylic acids with or without reaction with phthalic anhydride or maleic anhydride and sulfite to develop novel polyfunctional surfactant structures which are very highly suitable for a wide range of applications in dispersion and emulsification, in particular in the preparation and formulation of azo pigments.

摘要翻译： 对分散剂，乳化剂和配制助剂，特别是制备偶氮染料和颜料以及在制备染料和颜料分散体方面的日益增长的需求使得有必要开发新的表面活性化合物。 根据本发明，可以通过羟基萘羧酸（在羧基上）与脂肪醇或优选与脂肪酸，树脂酸或烷基酚的烷氧基化物酯化，得到的酯化产物与醛缩合，得到酚醛清漆树脂随后的烷氧基化 并且端基OH基团与树脂酸，脂肪酸，芳族羧酸和羟基羧酸酯化，与邻苯二甲酸酐或马来酸酐和亚硫酸酯反应或与其反应，开发新的多官能表面活性剂结构，其非常适用于分散体的广泛应用 和乳化，特别是在偶氮颜料的制备和配制中。

公开(公告)号：US5194665A

公开(公告)日：1993-03-16

申请号：US581515

申请日：1990-09-11

申请人： Heinz Uhrig ,  Erich Ackermann ,  Alexander Sieber

发明人： Heinz Uhrig ,  Erich Ackermann ,  Alexander Sieber

IPC分类号： C08G8/28 ,  C08G8/36 ,  C09B67/46

CPC分类号： C08G8/28 ,  C08G8/36 ,  C09B67/0085 ,  Y10S516/02

摘要： The ever increasing demands on dispersants, emulsifiers and formulation aids, in particular in the preparation of azo dyes and pigments and in the preparation of dye and pigment dispersions, made it necessary to develop novel surface-active compounds.According to the invention, it has been possible by esterification of hydroxynaphthalenecarboxylic acids (on the carboxyl) with fatty alcohols or preferably with alkoxylates of fatty acids, resin acids or alkylphenols, condensation of the resulting esterification products with aldehydes to give novolak resins with subsequent alkoxylation and esterification of terminal OH groups with resin acids, fatty acids, aromatic carboxylic acids and hydroxylcarboxylic acids with or without reaction with phthalic anhydride or maleic anhydride and sulfite to develop novel polyfunctional surfactant structures which are very highly suitable for a wide range of applications in dispersion and emulsification, in particular in the preparation and formulation of azo pigments.

摘要翻译： 对分散剂，乳化剂和配制助剂，特别是制备偶氮染料和颜料以及在制备染料和颜料分散体方面的日益增长的需求使得有必要开发新的表面活性化合物。 根据本发明，可以通过羟基萘羧酸（在羧基上）与脂肪醇或优选与脂肪酸，树脂酸或烷基酚的烷氧基化物酯化，得到的酯化产物与醛缩合，得到酚醛清漆树脂随后的烷氧基化 和端基OH基团与树脂酸，脂肪酸，芳族羧酸和羟基羧酸的酯化，与邻苯二甲酸酐或马来酸酐和亚硫酸盐反应或与其反应，开发新的多官能表面活性剂结构，其非常适用于分散体的广泛应用 和乳化，特别是在偶氮颜料的制备和配制中。

公开(公告)号：US5100989A

公开(公告)日：1992-03-31

申请号：US239509

申请日：1988-09-01

申请人： Heinz Uhrig ,  Erich Ackermann ,  Reinhold Deubel

发明人： Heinz Uhrig ,  Erich Ackermann ,  Reinhold Deubel

IPC分类号： A01N25/30 ,  B01F17/00 ,  B01F17/52 ,  C08G8/28 ,  C08G8/34 ,  C08G8/36 ,  C08G14/12 ,  C09B41/00 ,  D06P1/607

CPC分类号： A01N25/30 ,  B01F17/0028 ,  B01F17/0042 ,  B01F17/0057 ,  C08G14/12 ,  C08G8/28

摘要： The invention relates to surface-active compounds of the general formula (I) ##STR1## in which Ar is an aromatic system which is optionally substituted by C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -alkoxy, C.sub.2 -C.sub.5 -alkanoyl, C.sub.6 -C.sub.10 -aryl, (C.sub.6 -C.sub.10 -aryl)-C.sub.1 -C.sub.4 -alkyl, A has the formula --(X--O).sub.n --Y, wherein n denotes 1 to 50, X denotes ethylene or methylethylene and all or some of Y denote an acyl radical of a non-modified or modified natural resin acid and the other radicals Y denote radicals from the group comprising hydrogen, acyl radicals of saturated C.sub.1-24 -carboxylic acids, unsaturated C.sub.3-24 -carboxylic acids, C.sub.2-24 -hydroxy-fatty acids or C.sub.8-18 -alkyl-, -alkenyl- and -alkylidene-succinic acids, maleic acid, fumaric acid, sulfosuccinic acid, sulfuric acid, benzodicarboxylic acids and C.sub.1-16 -n-alkanedicarboxylic acids, W is a group --CHR-- or --CHR--N(R*)--T--N(R*)--CHR--, wherein R*is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -hydroxyalkyl, a radical A or --C.sub.2 -C.sub.4 -alkylene-O--A and R is H or C.sub.1-9 -alkyl, T is C.sub.2 -C.sub.12 -alkylene, which is optionally interrupted by --O-- or --NR'--, R' is H, C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -hydroxyalkyl, A or C.sub.2 -C.sub.4 -alkylene-O--A, W* is H or --CHR--N(R*)--T--N(R*)A and m is 1 to 16.The compounds are prepared on the basis of oxyalkylated novolaks of the formula (I) in which all the radicals Y denote hydrogen. The polyalkylene glycol chains are now terminally esterified or half-esterified in a one- or multi-stage reaction in accordance with the definition of A. The resulting surface-active products are suitable as emulsifiers and dispersing agents for the most diverse fields of applications.

摘要翻译： 本发明涉及通式（I）的表面活性化合物（Ⅰ），其中Ar是任选被C 1 -C 18烷基，C 1 -C 18烷氧基，C 2 -C 5 - 烷酰基 ，C 6 -C 10 - 芳基，（C 6 -C 10 - 芳基）-C 1 -C 4烷基，A具有式 - （XO）n Y，其中n表示1至50，X表示亚乙基或甲基亚乙基，并且全部或部分Y表示 未改性或改性的天然树脂酸的酰基，其它基团Y表示包括氢的基团，饱和C1-24羧酸的酰基，不饱和C3-24-羧酸，C2-24-羟基 - 脂肪酸或C 8-18烷基 - ， - 烯基 - 和 - 亚烷基 - 琥珀酸，马来酸，富马酸，磺基琥珀酸，硫酸，苯并二羧酸和C 1-16 - 正烷烃二羧酸，W是基团 - CHR-或-CHR-N（R *）-TN（R *）-CHR-，其中R *是氢，C1-C4-烷基，C2-C4-羟基烷基，基团A或-C2-C4-亚烷基 - OA和R是H或C1-9烷基，T是C2-C12-亚烷基，其是选择性的 被-O-或-NR'中断的，R'是H，C 1 -C 4烷基，C 2 -C 4羟基烷基，A或C 2 -C 4亚烷基-OA，W *是H或-CHR-N（R *） - TN（R *）A和m为1至16.该化合物基于其中所有基团Y表示氢的式（I）的烷氧基​​化线型酚醛清漆制备。 聚亚烷基二醇链现在根据A的定义在一步或多步反应中终止酯化或半酯化。得到的表面活性产物适合用作各种应用领域的乳化剂和分散剂。