公开(公告)号：US5969046A

公开(公告)日：1999-10-19

申请号：US683126

申请日：1991-04-09

申请人： F. J. Schindler ,  M. J. Hurwitz ,  M. H. Wolfersberger ,  R. L. Fulton, Jr. ,  W. E. Feely

发明人： F. J. Schindler ,  M. J. Hurwitz ,  M. H. Wolfersberger ,  R. L. Fulton, Jr. ,  W. E. Feely

IPC分类号： C08G63/91 ,  C08L33/14 ,  C08L63/00 ,  C08L67/02 ,  C08L67/06

CPC分类号： C08G63/918

摘要： A method for reacting a methylene-containing component such as an acrylic polymer prepared from acetoacetoxyalkyl (meth)acrylate and an alkene-containing component such as a polyfumarate, polymaleate, a polyester containing both fumarate and maleate groups or a polyacrylate comprises the reaction of a tertiary amine such as triethylene diamine and an epoxide such as a glycidyl-functional (meth)acrylic polymer in the presence of the methylene-containing component and alkene-containing component. The tertiary amine can be incorporated into the alkene-containing component such as the reaction of an unsaturated polyester with a compound having both tertiary amine and primary or secondary amine groups. The tertiary amine can be incorporated into the methylene-containing component such as an acrylic polymer derived from a tertiary amino-functional monmer and acetoacetoxyalkyl (meth)acrylate. The epoxide can be incorporated into the methylene-containing component such as an acrylic polymer obtained from glycidyl (meth)acrylate and acetoacetoxyalkyl (meth)acrylate. The epoxide can be incorporated into the alkene-containing component.

摘要翻译： 用于使含亚甲基的组分如（甲基）丙烯酸乙酰乙酰氧基烷基酯和含富烯酸的组分如聚富马酸盐，聚马来酸酯，含有富马酸盐和马来酸酯基团的聚酯或聚丙烯酸酯的烯烃组分制备的含亚甲基组分的方法包括： 叔胺如三亚乙基二胺和环氧化物如缩水甘油基官能的（甲基）丙烯酸聚合物，在含亚甲基的组分和含烯烃的组分的存在下。 可以将叔胺引入含烯烃的组分中，例如不饱和聚酯与具有叔胺和伯胺或仲胺基团的化合物的反应。 可以将叔胺引入到含亚甲基的组分中，例如衍生自叔氨基官能单体的丙烯酸聚合物和（甲基）丙烯酸乙酰乙酰氧基烷基酯。 可以将环氧化物加入到含亚甲基的组分中，例如由（甲基）丙烯酸缩水甘油酯和（甲基）丙烯酸乙酰乙酰氧基烷基酯获得的丙烯酸类聚合物。 环氧化物可以并入含烯烃的组分中。