Production of blue iron hexacyanoferrate-III pigments
    1.
    发明授权
    Production of blue iron hexacyanoferrate-III pigments 失效
    生产蓝铁六氰酸铁-III颜料

    公开(公告)号:US4466867A

    公开(公告)日:1984-08-21

    申请号:US467744

    申请日:1983-02-18

    IPC分类号: C09C1/26 C25B1/00

    CPC分类号: C25B1/00 C09C1/26 C01P2006/80

    摘要: Blue iron hexacyanoferrate-III pigments are produced by a process wherein complex iron-II hexacyanoferrate-II (Berlin white) is prepared by electrolysis of an aqueous catholyte solution containing (a) an iron-II salt, (b) an alkali metal salt, an ammonium salt or a mixture of these, and (c) hydrogen cyanide, in an electrolysis cell in which the anode chamber and cathode chamber are separated by an ion exchange membrane, using an electrically conductive aqueous liquid in the anode chamber, and the iron-II hexacyanoferrate-II obtained is then converted to the blue pigment.The process gives Berlin white, which is substantially free from salt, in high yield and high purity. Pollution caused by the process is very low, since only a small amount of salt is produced. Compared with the corresponding blue pigments produced by prior art processes, the pigments obtained give purer colorations with better gloss, and are of higher color strength.

    摘要翻译: 通过电解含有(a)铁-II盐,(b)碱金属盐的水性阴极电解液的方法制备复合铁 - 六氰基铁酸盐-II(柏林白)的方法制备蓝色六氰合铁酸盐III- 铵盐或它们的混合物,和(c)氰化氢在电解池中,其中阳极室和阴极室由离子交换膜分离,使用阳极室中的导电含水液体,铁 -II六氰基铁酸盐-II然后转化成蓝色颜料。 该方法给出柏林白色,其基本上不含盐,以高产率和高纯度。 该过程造成的污染非常低,因为只产生少量的盐。 与通过现有技术方法生产的相应的蓝色颜料相比,获得的颜料产生更好的着色,并具有较高的着色强度。

    Preparation of dyes which contain sulfonic acid groups and have a low
electrolyte content
    3.
    发明授权
    Preparation of dyes which contain sulfonic acid groups and have a low electrolyte content 失效
    制备含有磺酸基并具有低电解质含量的染料

    公开(公告)号:US4560745A

    公开(公告)日:1985-12-24

    申请号:US263007

    申请日:1981-05-12

    摘要: A process for the preparation of dyes which contain sulfonic acid groups and have a low electrolyte content, wherein an aqueous solution or suspension, which may or may not contain inorganic salts, of the dye containing sulfonic acid groups is(a) mixed with an amount, equivalent to the said dye, of a non-emulsifying, water-insoluble amine of a total of 12 to 40 carbon atoms, which forms, with the said dye, a salt which is sufficiently lipophilic for it to separate spontaneously from the aqueous phase,(b) the pH is brought to

    摘要翻译: 一种制备含有磺酸基并具有低电解质含量的染料的方法,其中含有磺酸基的染料可含有或不含有无机盐的水溶液或悬浮液为(a)与 相当于所述染料的总共12至40个碳原子的非乳化的水不溶性胺,其与所述染料形成足够亲油的盐,以使其与水相自发分离 ,(b)用酸将pH值调至<5,并将批料充分混合,(c)分离两个不同密度的相,(d)由染料的亲脂性铵盐组成的相 混合,用或不用水预先洗涤,制备其磺酸盐的水溶性碱,并且用水分离所得相,并将盐留在水溶液中或从中分离。

    Production of formaldehyde
    4.
    发明授权
    Production of formaldehyde 失效
    生产甲醛

    公开(公告)号:US3991118A

    公开(公告)日:1976-11-09

    申请号:US236210

    申请日:1972-03-20

    IPC分类号: C07C45/38 C07C45/16

    CPC分类号: C07C45/38

    摘要: Production of formaldehyde by oxidizing dehydrogenation of methanol in the presence of a silver catalyst and a tertiary or secondary amine. The formaldehyde which can be prepared by the invention is a disinfectant, tanning agent, reducing agent and valuable starting material for the production of synthetic resins, adhesives and plastics.

    摘要翻译: 在银催化剂和叔胺或仲胺的存在下,通过氧化甲醇脱氢制备甲醛。 本发明可制备的甲醛是生产合成树脂,粘合剂和塑料的消毒剂,鞣剂,还原剂和有价值的原料。