公开(公告)号：US4396786A

公开(公告)日：1983-08-02

申请号：US270814

申请日：1981-06-05

申请人： Geoffrey C. Bond ,  Alfred J. Bird

发明人： Geoffrey C. Bond ,  Alfred J. Bird

IPC分类号： C10G1/00 ,  C07C1/00

CPC分类号： C10G1/006 ,  Y10S208/951

摘要： A method for producing fuel oil from cellulosic materials (especially domestic or agricultural waste) in which the material is contacted with water and treated with a reducing gas (eg hydrogen or methane) and carbon monoxide in the presence of a platinum group metal (preferably ruthenium) or copper catalyst at 100.degree. to 950.degree. C. (preferably 100.degree. to 250.degree. C.) and at 10 to 680 (preferably 10 to 100) atmospheres. It is believed that the cellulose is hydrolyzed, then carbonylated to a keto acid which decarboxylates to produce a polymerizable acid and carbon dioxide. The aldehyde polymerizes and is hydrogenated to produce the fuel oil.

摘要翻译： 一种从纤维素材料（特别是家用或农业废物）生产燃料油的方法，其中材料与水接触并用还原气体（例如氢气或甲烷）和一氧化碳在铂族金属（优选钌）存在下进行处理 ）或铜催化剂在100至950℃（优选100至250℃）和10至680（优选10至100）的气氛下进行。 据信纤维素被水解，然后羰基化成脱羧酸的酮酸，产生可聚合的酸和二氧化碳。 醛聚合并被氢化以产生燃料油。