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    Radiation-curing printing inks with enhanced scratch resistance and lubricity
    1.
    发明授权
    Radiation-curing printing inks with enhanced scratch resistance and lubricity 失效
    具有增强的耐擦伤性和润滑性的辐射固化印刷油墨

    公开(公告)号：US5863966A

    公开(公告)日：1999-01-26

    申请号：US709175

    申请日：1996-09-06

    申请人： Thomas Ebbrecht ,  Georg Feldmann-Krane ,  Peter Lersch ,  Stefan Silber

    发明人： Thomas Ebbrecht ,  Georg Feldmann-Krane ,  Peter Lersch ,  Stefan Silber

    IPC分类号： C09D11/101 ,  C09D11/10

    CPC分类号： C09D11/101 ,  Y10S260/38

    摘要： Radiation-curing printing inks which comprise organopolysiloxanes of the general formula ##STR1## in which R.sup.1 =an alkyl radical having 1 to 8 carbon atoms,R.sup.2 =a group of the formula--CH.sub.2 --CH.sub.2 --C(O)O--R--(OC(O)--CH.dbd.CH.sub.2).sub.x-1and/or--CH.dbd.CH--C(O)O--R--(OC(O)--CH.dbd.CH.sub.2).sub.x-1in which x is an integer and is at least 2, and R is a hydrocarbon radical which optionally has alkoxy groups,R.sup.3 =R.sup.1 or R.sup.2,n=30 to 150,m=0 to 3, preferably 0,in quantities of from 0.01 to 3% by weight, based on the ink formulation.

    摘要翻译： 包含通式为“IMAGE”的有机聚硅氧烷的辐射固化印刷油墨，其中R 1 =具有1至8个碳原子的烷基，R 2 =式-CH 2 -CH 2 -C（O）OR-（OC（ O）-CH = CH 2）x-1和/或-CH = CH-C（O）OR-（OC（O）-CH = CH 2）x-1，其中x为整数且至少为2，R为 基于油墨配方，任选具有烷氧基的烃基R3 = R1或R2，n = 30至150，m = 0至3，优选0，其量为0.01至3重量％。

    Acrylate group-modified organosiloxanyl derivatives of alkanediol monovinyl ethers, process for their preparation, and their use as radiation-curable binders
    4.
    发明授权
    Acrylate group-modified organosiloxanyl derivatives of alkanediol monovinyl ethers, process for their preparation, and their use as radiation-curable binders 失效
    链烷二醇单乙烯基醚的丙烯酸酯基改性有机基硅氧烷衍生物，其制备方法及其作为可辐射固化粘合剂的用途

    公开(公告)号：US5977282A

    公开(公告)日：1999-11-02

    申请号：US982205

    申请日：1997-12-01

    申请人： Thomas Ebbrecht ,  Georg Feldmann-Krane ,  Stefan Silber ,  Stefan Stadtmuller

    发明人： Thomas Ebbrecht ,  Georg Feldmann-Krane ,  Stefan Silber ,  Stefan Stadtmuller

    IPC分类号： C08G77/38 ,  C09D183/07 ,  C08G77/12

    CPC分类号： C08G77/38

    摘要： Oraganopolysiloxanes of the general formula ##STR1## where R.sup.1 =identical or different aliphatic or aromatic hydrocarbon radicals,R.sup.2 =CH.sub.2 CH.sub.2 O(CR.sup.4 R.sup.5).sub.x OC(O)CR.sup.6 .dbd.CHR.sup.7, whereR.sup.4, R.sup.5, R.sup.6 and R.sup.7can be identical or different radicals and are each a H or alkyl radical, branched or unbranched, having up to a total of 6 C atoms and x has a value from 3 to 11, where --(CR.sup.4 R.sup.5)-- can also be a cyclic aliphatic or aromatic radical,R.sup.3 =R.sup.2 or R.sup.1,a=0 to 50 andb=0 to 500,but at least one radical R.sup.2 is attached terminally and/or laterally.

    摘要翻译： R 1 =相同或不同的脂族或芳族烃基，R2 = CH2CH2O（CR4R5）xOC（O）CR6 = CHR7，其中R4，R5，R6和R7可以是相同或不同的基团并且各自为H的通式的芳族聚多羟基硅氧烷 或烷基，支链或非支链，具有至多总共6个C原子，x具有3至11的值，其中 - （CR4R5） - 也可以是环状脂族或芳族基团，R3 = R2或R1，a = 0〜50，b = 0〜500，但至少有一个基团R2末端和/或侧向连接。

    Diaryliodonium salt catalysts made from iodotoluene and a method for preparing them
    5.
    发明授权
    Diaryliodonium salt catalysts made from iodotoluene and a method for preparing them 失效
    由碘甲苯制备的二芳基碘盐催化剂及其制备方法

    公开(公告)号：US06632960B2

    公开(公告)日：2003-10-14

    申请号：US10177549

    申请日：2002-06-21

    申请人： James V. Crivello ,  Georg Feldmann-Krane ,  Sascha Oestreich

    发明人： James V. Crivello ,  Georg Feldmann-Krane ,  Sascha Oestreich

    IPC分类号： C07C30900

    CPC分类号： C07C43/23 ,  C07F5/027 ,  C07F9/902

    摘要： Diaryliodonium salts are disclosed, as well as a method for preparing them, in which one of the aryl groups bonded to the positively-charged iodine ion contains a methyl substituent, and the other one contains a hydroxyl-substituted alkoxy group. The salts are synthesized from (o, m, or p)-iodotoluene, as opposed to iodobenzene, and therefore do not pose a carcinogenic risk. In addition, the present salts are unexpectedly more soluble in most organic solvents, as well as in nonpolar monomers, than the corresponding benzene catalysts. The salts are useful as cationic photoinitiators, cationic thermal initiators (often combined with a cocatalyst, e.g. copper), and as starting materials in the synthesis of urethane-containing iodonium salts.

    摘要翻译： 公开了二芳基碘鎓盐及其制备方法，其中与正电荷的碘离子键合的一个芳基含有甲基取代基，另一个含有羟基取代的烷氧基。 盐与（o，m或p） - 碘甲苯合成，而不是碘苯，因此不会造成致癌风险。 此外，与相应的苯催化剂相比，本发明的盐在大多数有机溶剂以及非极性单体中意外地更易溶。 这些盐可用作阳离子光引发剂，阳离子热引发剂（通常与助催化剂例如铜组合）和作为合成含氨基甲酸酯的碘鎓盐的起始原料。