Supported catalytic system for the production of ethylene propylene copolymers
    1.
    发明授权
    Supported catalytic system for the production of ethylene propylene copolymers 失效
    用于生产乙烯丙烯共聚物的负载催化体系

    公开(公告)号:US06403739B1

    公开(公告)日:2002-06-11

    申请号:US08557842

    申请日:1995-11-14

    IPC分类号: C08F468

    CPC分类号: C08F210/16 C08F4/68

    摘要: Catalytic component for the polymerization of ethylene with propylene prepared by: a) impregnation of an inert support with a solution of a compound of Vanadium having an oxidation state of between 3 and 5; b) subsequent treatment with a solution of a compound having general formula (I) RnAlXm wherein R is a C1-C20 alkyl radical, X is a halogen, n+m=3, and m is an integer between 0 and 2, the molar ratio between Aluminium in step (b) and Vanadium in step (a) being from 1/1 to 6/1.

    摘要翻译: 通过以下步骤制备乙烯聚合的催化组分:a)用氧化态为3至5的钒化合物的溶液浸渍惰性载体; b)随后用具有通式 (I)RnAlXm其中R是C1-C20烷基,X是卤素,n + m = 3,m是0和2之间的整数,步骤(b)中的铝与步骤(b)中的钒的摩尔比 a)从1/1到6/1。

    Catalyst for the preparation of elastomeric ethylene-propylene copolymers
    2.
    发明授权
    Catalyst for the preparation of elastomeric ethylene-propylene copolymers 失效
    用于制备弹性体乙烯 - 丙烯共聚物的催化剂

    公开(公告)号:US5578540A

    公开(公告)日:1996-11-26

    申请号:US595451

    申请日:1996-02-05

    CPC分类号: C08F210/16

    摘要: Solid component of a catalyst for the synthesis of elastomeric Ethylene-Propylene copolymers typically amorphous, basically consisting of a Titanium compound supported on a solid component mainly consisting of MgCl.sub.2, prepared by a process which comprises putting a solution (I), basically consisting of an organometallic compound of Aluminium diluted with aliphatic hydrocarbons, in contact with a solution (II) containingan anhydrous Magnesium halide in a composition of solvents selected from halohydrocarbons and aromatic hydrocarbons and relative mixtures, in the presence of an Aluminium trihalide;a tetravalent Titanium compound having general formula Ti(OR).sub.4-n X.sub.n.

    摘要翻译: 用于合成弹性体乙烯 - 丙烯共聚物的固体组分通常是无定形的,基本上由负载在主要由MgCl 2组成的固体组分上的钛化合物组成,该方法包括将基本上由 在三卤化铝的存在下,用选自卤代烃和芳族烃的溶剂组合物中含有无水卤化镁的溶液(II)和相对混合物与脂族烃稀释的铝的有机金属化合物接触; 具有通式Ti(OR)4-nXn的四价钛化合物。