公开(公告)号：US06346593B1

公开(公告)日：2002-02-12

申请号：US09458249

申请日：1999-12-09

申请人： Peter Hupfield ,  Grainne Moloney ,  Avril Surgenor ,  Richard Taylor

发明人： Peter Hupfield ,  Grainne Moloney ,  Avril Surgenor ,  Richard Taylor

IPC分类号： C08G7708

CPC分类号： C08G77/08 ,  C08G77/26

摘要： A polymerization process comprising mixing siloxane polymers with organosilicon compounds having at least one silicon-bonded group RN, which is a substituent comprising at least one amine group, and with a phosphazene base catalyst and allowing the siloxanes and organosilicon compounds to polymerize to form amino-functional polyorganosiloxane polymers is claimed. Preferably the phosphazene base is selected from the following formulae: ((R12N)3P═N—)x(R12N)3−xP═NR2; {((R12N)3P═N—)x(R12N)3−xP—N(H)R2}+{A−} {((R12N)3P═N—)y(R12N)4−yP}+{A}− or {(R12N)3P═N—(P(NR12)2═N)n—P+(NR12)3}{A−} in which R1 is hydrogen or an optionally substituted hydrocarbon group, or in which two R1 groups bonded to the same N atom may be linked to complete a heterocyclic ring, R2 is hydrogen or an optionally substituted hydrocarbon group, x is 1, 2 or 3; y is 1, 2, 3 or 4, n is an integer with a value of from 1 to 10 and A is an anion.

摘要翻译： 聚合方法包括将硅氧烷聚合物与具有至少一个含硅键合基团RN（其是包含至少一个胺基的取代基）和磷腈碱催化剂的有机硅化合物混合，并使硅氧烷和有机硅化合物聚合形成氨基 - 要求保护功能性聚有机硅氧烷聚合物。 优选地，磷腈碱选自下式：其中R 1是氢或任选取代的烃基，或者其中与相同N原子键合的两个R 1基团可以连接以形成杂环，R 2是氢或任选地 取代的烃基，x为1,2或3; y为1,2,3或4，n为1〜10的整数，A为阴离子。