公开(公告)号：US20090281349A1

公开(公告)日：2009-11-12

申请号：US12318551

申请日：2008-12-31

申请人： Sung-Yueh Shieh ,  Dein-Run Fung ,  Han-Ching Hsu ,  Yang-Tu Liu

发明人： Sung-Yueh Shieh ,  Dein-Run Fung ,  Han-Ching Hsu ,  Yang-Tu Liu

IPC分类号： C07C69/75

CPC分类号： C07C69/75 ,  C07C2601/14 ,  C08K5/12 ,  C08L27/06

摘要： A hexahydrophthalate based compound is adapted to use as a plasticizer that contains no phthalic acid and benzoic acid, possess physical properties superior to DEHA and DINA in transparency and adhesion and is friendly to organisms and the environment; and a process for producing the hexahydrophthalate based compound includes esterifying hexahydrophthalic anhydride, a diol, and a catalyst for decarboxylation to get hexahydrophthalic alcohol, and adding a monoacid into the hexahydrophthalic alcohol for further esterification, thereby obtaining the hexahydrophthalate based compound.

摘要翻译： 六氢邻苯二甲酸酯类化合物适用于不含邻苯二甲酸和苯甲酸的增塑剂，具有优于DEHA和DINA的物理性质，具有透明性和粘合性，对生物和环境友好; 制造六氢邻苯二甲酸酯类化合物的方法包括将六氢邻苯二甲酸酐，二醇和脱羧催化剂酯化得到六氢邻苯二甲醇，并将一元酸加入到六氢邻苯二甲醇中进一步酯化，由此得到六氢邻苯二甲酸酯类化合物。

公开(公告)号：US08017799B2

公开(公告)日：2011-09-13

申请号：US12318551

申请日：2008-12-31

申请人： Sung-Yueh Shieh ,  Dein-Run Fung ,  Han-Ching Hsu ,  Yang-Tu Liu

发明人： Sung-Yueh Shieh ,  Dein-Run Fung ,  Han-Ching Hsu ,  Yang-Tu Liu

IPC分类号： C07C69/74

CPC分类号： C07C69/75 ,  C07C2601/14 ,  C08K5/12 ,  C08L27/06

摘要： A hexahydrophthalate based compound is adapted to use as a plasticizer that contains no phthalic acid and benzoic acid, possess physical properties superior to DEHA and DINA in transparency and adhesion and is friendly to organisms and the environment; and a process for producing the hexahydrophthalate based compound includes esterifying hexahydrophthalic anhydride, a diol, and a catalyst for decarboxylation to get hexahydrophthalic alcohol, and adding a monoacid into the hexahydrophthalic alcohol for further esterification, thereby obtaining the hexahydrophthalate based compound.

摘要翻译： 六氢邻苯二甲酸酯类化合物适用于不含邻苯二甲酸和苯甲酸的增塑剂，具有优于DEHA和DINA的物理性质，具有透明性和粘合性，对生物和环境友好; 制造六氢邻苯二甲酸酯类化合物的方法包括将六氢邻苯二甲酸酐，二醇和脱羧催化剂酯化得到六氢邻苯二甲醇，并将一元酸加入到六氢邻苯二甲醇中进一步酯化，由此得到六氢邻苯二甲酸酯类化合物。

公开(公告)号：US20080183004A1

公开(公告)日：2008-07-31

申请号：US11699381

申请日：2007-01-30

申请人： Sung-Yueh Shieh ,  Dein-Run Fung ,  Han-Ching Hsu ,  Yang-Tu Liu ,  Hsun-Min Lin

发明人： Sung-Yueh Shieh ,  Dein-Run Fung ,  Han-Ching Hsu ,  Yang-Tu Liu ,  Hsun-Min Lin

IPC分类号： C07C67/08

CPC分类号： C08K5/12 ,  C07C67/08 ,  C07C2601/14 ,  C07C69/75

摘要： A method for preparing a kind of plasticizer containing cyclohexane poly carboxylic acid ester, particularly without phthalate, and with the advantage of effective shortening of reaction time, which method comprising having cyclohexane polycarboxylic acid or its derivatives, mono-alcohol and metal catalyst of tin and titanium or inorganic acid added together at the same time into a reactor to undergo a single stage of esterification at high temperature of 200˜250° C., and a reaction mixture of cyclohexane polycarboxylic acid ester was obtained by the process which is applicably used as a plasticizer without phthalate and no hazard to the living beings and environment.

摘要翻译： 一种制备一种含环己烷聚羧酸酯的增塑剂的方法，特别是没有邻苯二甲酸酯，并且具有有效缩短反应时间的优点，该方法包括使环己烷多元羧酸或其衍生物，锡的单醇和金属催化剂和 钛或无机酸同时加入到反应器中，在200〜250℃的高温下进行一步酯化，通过以下方法得到环己烷多元羧酸酯的反应混合物，该方法适用于 不含邻苯二甲酸酯的增塑剂，对生物和环境无害。