Process for skeletal isomerization of n-alkenes
    1.
    发明授权
    Process for skeletal isomerization of n-alkenes 失效
    正烯烃的骨架异构化方法

    公开(公告)号:US5396015A

    公开(公告)日:1995-03-07

    申请号:US983059

    申请日:1992-11-30

    IPC分类号: B01J29/85 C07C5/27

    摘要: Skeletal isomerization of n-alkenes into isoalkenes and enrichment of isoalkenes in alkene-containing hydrocarbon mixtures is effected in the presence of an isomerization catalyst containing a microporous silicon-containing alumophosphate.A goal of the method for skeletal isomerization is to provide a running time in one operating period of over 100 hours. This goal is achieved by using, as isomerization catalysts, microporous alumophosphates with a molecular sieve structure whose pore inlet openings have a diameter of 0.4 to 0.6 nm which are mixed with a binder and activated at temperatures of 623 to 873K.

    摘要翻译: 在含有微孔含硅的铝磷酸盐的异构化催化剂的存在下,将正烯烃的骨架异构化转化为异烯烃并富含含烯烃的烃混合物中的异烯烃。 骨骼异构化方法的目标是在一个运行时间内提供超过100小时的运行时间。 该目标通过使用具有分子筛结构的微孔铝磷酸盐作为异构化催化剂来实现,其孔的入口开口具有0.4至0.6nm的直径,其与粘合剂混合并在623至873K的温度下活化。