摘要:
Provided is an electrolyte containing tetrafluoroaluminate ions, which is advantageous in that the electrolyte can be prevented from leaking from both the cathode and the anode in an electrolytic capacitor.An electrolyte for electrolytic capacitor, which comprises: (A) a tetrafluoroaluminate ion, and (B) at least one compound selected from the group consisting of: (1) at least one compound selected from the group consisting of a phthalimide, a quinoline, a dioxime, a nitrophenol and an amino group-containing aromatic carboxylic acid; (2) at least one compound selected from the group consisting of an aluminum complex, a boric acid ester and a silicic acid ester; (3) at least one compound selected from the group consisting of a monocyclic quinone compound and a bicyclic quinone compound; (4) a tricyclic or higher polycyclic quinone compound; and (5) at least one compound selected from a heteropoly acid and a salt thereof, an electrolyte for electrolytic capacitor containing a tetrafluoroaluminate ion, which has a self-potential of −0.95 V or more with respect to aluminum in the electrolyte, relative to an I3−/I− reference electrode, and an electrolytic capacitor using the same.
摘要:
The present invention provides an electric double layer capacitor which has electrodes made of an alkali-activated carbon, prepared from a graphitic material, useful in manufacturing high-capacitance capacitors and which has an electrolytic solution containing chain carbonate and/or cyclic carbonate. Even if the electric double layer capacitor is used under high-temperature and high-voltage conditions, chain carbonate and/or cyclic carbonate is prevented from being degraded and the amount of generated gas is slight. The electric double layer capacitor has high initial performance and energy density and the performance of the electric double layer capacitor is maintained high. The electrolytic solution contains a quaternary ammonium salt except for a quaternary ammonium salt containing a carbon atom being bonded to the quaternary nitrogen atom and being bonded to other nitrogen atom than the quaternary nitrogen atom, chain carbonate and/or cyclic carbonate, and a solvent containing a carboxylic ester which contains five or more carbon atoms and which has two or more carboxylic ester bonds.
摘要:
There are provided an aluminum electrolytic capacitor comprising an anode, a cathode comprising aluminum and an electrolytic solution containing an onium salt of fluorine-containing anion, wherein the electrolytic solution has a water concentration of 1% by weight or less, or wherein the cathode has a peak top of Al2p spectrum of 74.0 to 75.8 eV as measured by a method in which the surface of the cathode in the aluminum electrolytic capacitor heated at 125° C. for 50 hours is analyzed by X-ray photoelectron spectroscopy (XPS); an electrolytic solution for electrolytic capacitor comprising a quaternary cyclic amidinium tetrafluoroaluminate and a solvent and containing specific impurity compounds in a total amount of 0.6% by weight or less, and an electrolytic capacitor using the electrolytic solution; and a method for preparing an organic onium tetrafluoroaluminate which is advantageously used in an aluminum electrolytic capacitor.
摘要:
There are provided an aluminum electrolytic capacitor comprising an anode, a cathode comprising aluminum and an electrolytic solution containing an onium salt of fluorine-containing anion, wherein the electrolytic solution has a water concentration of 1% by weight or less, or wherein the cathode has a peak top of Al2p spectrum of 74.0 to 75.8 eV as measured by a method in which the surface of the cathode in the aluminum electrolytic capacitor heated at 125° C. for 50 hours is analyzed by X-ray photoelectron spectroscopy (XPS); an electrolytic solution for electrolytic capacitor comprising a quaternary cyclic amidinium tetrafluoroaluminate and a solvent and containing specific impurity compounds in a total amount of 0.6% by weight or less, and an electrolytic capacitor using the electrolytic solution; and a method for preparing an organic onium tetrafluoroaluminate which is advantageously used in an aluminum electrolytic capacitor.
摘要:
Provided is an electrolyte containing tetrafluoroaluminate ions, which is advantageous in that the electrolyte can be prevented from leaking from both the cathode and the anode in an electrolytic capacitor.An electrolyte for electrolytic capacitor, which comprises: (A) a tetrafluoroaluminate ion, and (B) at least one compound selected from the group consisting of: (1) at least one compound selected from the group consisting of a phthalimide, a quinoline, a dioxime, a nitrophenol and an amino group-containing aromatic carboxylic acid; (2) at least one compound selected from the group consisting of an aluminum complex, a boric acid ester and a silicic acid ester; (3) at least one compound selected from the group consisting of a monocyclic quinone compound and a bicyclic quinone compound; (4) a tricyclic or higher polycyclic quinone compound; and (5) at least one compound selected from a heteropoly acid and a salt thereof, an electrolyte for electrolytic capacitor containing a tetrafluoroaluminate ion, which has a self-potential of −0.95 V or more with respect to aluminum in the electrolyte, relative to an I3−/I− reference electrode, and an electrolytic capacitor using the same.
摘要:
There are provided an aluminum electrolytic capacitor comprising an anode, a cathode comprising aluminum and an electrolytic solution containing an onium salt of fluorine-containing anion, wherein the electrolytic solution has a water concentration of 1% by weight or less, or wherein the cathode has a peak top of Al2p spectrum of 74.0 to 75.8 eV as measured by a method in which the surface of the cathode in the aluminum electrolytic capacitor heated at 125° C. for 50 hours is analyzed by X-ray photoelectron spectroscopy (XPS); an electrolytic solution for electrolytic capacitor comprising a quaternary cyclic amidinium tetrafluoroaluminate and a solvent and containing specific impurity compounds in a total amount of 0.6% by weight or less, and an electrolytic capacitor using the electrolytic solution; and a method for preparing an organic onium tetrafluoroaluminate which is advantageously used in an aluminum electrolytic capacitor.
摘要:
In an electric double layer capacitor and electrolytic solution, decomposition of at least one of an open-chain carbonate and a cyclic carbonate can be controlled under high temperature conditions, initial performance and maintained ratio of capacitance are superior, and energy density is high, when graphitized alkali-activated carbon is used as an electrode material and at least one of an open-chain carbonate and a cyclic carbonate is used in an organic electrolytic solution. The electric double layer capacitor includes electrodes containing alkali-activated carbon including graphitized carbon material, and an organic electrolytic solution in which a supporting salt is dissolved in solvent including aromatic carboxylate and at least one of an open-chain carbonate and a cyclic carbonate, in which the content of the aromatic carboxylate is not more than 50 weight % relative to the total weight of the solvent.
摘要:
There are provided an aluminum electrolytic capacitor comprising an anode, a cathode comprising aluminum and an electrolytic solution containing an onium salt of fluorine-containing anion, wherein the electrolytic solution has a water concentration of 1% by weight or less, or wherein the cathode has a peak top of Al2p spectrum of 74.0 to 75.8 eV as measured by a method in which the surface of the cathode in the aluminum electrolytic capacitor heated at 125° C. for 50 hours is analyzed by X-ray photoelectron spectroscopy (XPS); an electrolytic solution for electrolytic capacitor comprising a quaternary cyclic amidinium tetrafluoroaluminate and a solvent and containing specific impurity compounds in a total amount of 0.6% by weight or less, and an electrolytic capacitor using the electrolytic solution; and a method for preparing an organic onium tetrafluoroaluminate which is advantageously used in an aluminum electrolytic capacitor.
摘要:
There are provided an aluminum electrolytic capacitor comprising an anode, a cathode comprising aluminum and an electrolytic solution containing an onium salt of fluorine-containing anion, wherein the electrolytic solution has a water concentration of 1% by weight or less, or wherein the cathode has a peak top of Al2p spectrum of 74.0 to 75.8 eV as measured by a method in which the surface of the cathode in the aluminum electrolytic capacitor heated at 125° C. for 50 hours is analyzed by X-ray photoelectron spectroscopy (XPS); an electrolytic solution for electrolytic capacitor comprising a quaternary cyclic amidinium tetrafluoroaluminate and a solvent and containing specific impurity compounds in a total amount of 0.6% by weight or less, and an electrolytic capacitor using the electrolytic solution; and a method for preparing an organic onium tetrafluoroaluminate which is advantageously m used in an aluminum electrolytic capacitor.
摘要:
The present invention provides an electric double layer capacitor which has electrodes made of an alkali-activated carbon, prepared from a graphitic material, useful in manufacturing high-capacitance capacitors and which has an electrolytic solution containing chain carbonate and/or cyclic carbonate. Even if the electric double layer capacitor is used under high-temperature and high-voltage conditions, chain carbonate and/or cyclic carbonate is prevented from being degraded and the amount of generated gas is slight. The electric double layer capacitor has high initial performance and energy density and the performance of the electric double layer capacitor is maintained high. The electrolytic solution contains a quaternary ammonium salt except for a quaternary ammonium salt containing a carbon atom being bonded to the quaternary nitrogen atom and being bonded to other nitrogen atom than the quaternary nitrogen atom, chain carbonate and/or cyclic carbonate, and a solvent containing a carboxylic ester which contains five or more carbon atoms and which has two or more carboxylic ester bonds.