公开(公告)号：US4434031A

公开(公告)日：1984-02-28

申请号：US513820

申请日：1983-07-15

申请人： Hugh H. Horowitz ,  Harold S. Horowitz ,  John M. Longo

发明人： Hugh H. Horowitz ,  Harold S. Horowitz ,  John M. Longo

IPC分类号： C07C51/16 ,  C25B3/02 ,  C25B11/04

CPC分类号： C25B3/02 ,  C07C51/16 ,  C25B11/0447

摘要： A method for electrocatalytically reacting various oxidizable organic compounds by introducing current by means of an anode into an electrolyte of a cell containing the oxidizable organic compound. The anode comprises an electrocatalyst material which has at least one compound of the formula:A.sub.2 [B.sub.2-x B'.sub.x ]O.sub.7-ywherein A is selected from any of the pyrochlore structure metal cations in a group consisting of: Pb, Bi, and Tl, wherein B' is selected from any of the pyrochlore structure metal cations in a group consisting of Pb, Bi, Tl, and Sn; wherein B is a pyrochlore structure metal cation at least a major portion of which is selected from a group consisting of at least one of: Ru, Rh, Ir, and Os, wherein y is equal to or greater than zero and equal to or less than one; and wherein x is equal to or less than one and equal to or greater than zero.

摘要翻译： 一种通过将阳极引入电流到含有可氧化有机化合物的电池的电解液中来使各种可氧化有机化合物电催化反应的方法。 阳极包括具有至少一种下式的化合物的电催化剂材料：A2 [B2-xB'x] O7-y其中A选自任何烧绿石结构金属阳离子，由Pb，Bi和 T1，其中B'选自Pb，Bi，Tl和Sn组成的组中的任何烧绿石结构金属阳离子; 其中B是烧绿石结构金属阳离子，其至少主要部分选自由Ru，Rh，Ir和Os中的至少一种组成的组，其中y等于或大于0并且等于或小于 比一个 并且其中x等于或小于1并且等于或大于零。