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1.发明申请Dinuclear Indium Catalysts and Their Use for (Co)Polymerization of Cyclic Esters 有权双核铟催化剂及其用于环状酯的（Co）聚合公开(公告)号：US20150038651A1
公开(公告)日：2015-02-05
申请号：US14118433
申请日：2012-05-18
Applicant: Parisa Mehrkhodavandi , Insun Yu , J. Alberto Acosta-Ramirez
Inventor： Parisa Mehrkhodavandi , Insun Yu , J. Alberto Acosta-Ramirez
CPC classification number: C07F5/00 , B01J31/2243 , B01J2531/0216 , B01J2531/0238 , B01J2531/33 , C08G63/823 , C08G63/84
Abstract: Provided are novel dinuclear indium catalysts of formula (A) that are capable of living and immortal ring opening polymerization and copolymerization of cyclic ester monomers for the preparation of biodegradable polymers and copolymers, in particular polyesters. Also disclosed are polymerization methods and polymer products. These dinuclear indium catalysts allow less costly, highly reactive living polymerization of cyclic ester monomers with possible high turn over rates and/or substantial stereo chemical and microstructure control.
Abstract translation: 提供了式（A）的新颖的双核铟催化剂，其能够活化和不间断的开环聚合和环酯单体的共聚用于制备可生物降解的聚合物和共聚物，特别是聚酯。 还公开了聚合方法和聚合物产物。 这些双核铟催化剂允许具有可能的高翻转率和/或实质的立体化学和微结构控制的环酯单体的成本较低，高反应活性聚合。
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Patent Agency Ranking
公开(公告)号：US08298443B2
公开(公告)日：2012-10-30
申请号：US12161235
申请日：2007-01-19
Applicant: Michael S. Freund , Bhavana A. Deore , Insun Yu
Inventor： Michael S. Freund , Bhavana A. Deore , Insun Yu
CPC classification number: C08G73/0266
Abstract: A method for producing a polymer comprising reacting a fluoride and a monomer having a boronic acid moiety, or a salt thereof, in acidic aqueous solution and/or in an aliphatic alcohol. Polymerization occurs with the addition of an oxidizing agent. The method may further comprise the step of purification of the polymer by centrifugation with 0.5 M HCl and/or dispersion of the polymer in a solvent. The polymer has a morphology tunable by changing the solvent.
Abstract translation: 一种制备聚合物的方法，包括使氟化物和具有硼酸部分的单体或其盐在酸性水溶液和/或脂族醇中反应。 通过加入氧化剂进行聚合。 该方法还可以包括通过用0.5M HCl离心和/或在溶剂中分散聚合物来纯化聚合物的步骤。 通过改变溶剂，聚合物具有可调谐的形态。
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公开(公告)号：US20070093644A1
公开(公告)日：2007-04-26
申请号：US10581752
申请日：2004-12-06
Applicant: Bhavana Deore , Insun Yu , Michael Freund
Inventor： Bhavana Deore , Insun Yu , Michael Freund
IPC: C08G73/00
CPC classification number: C08G73/0266 , H01B1/128
Abstract: A substituted polyaniline whose self-doped state can be controlled via complexation between boronic acid groups along the backbone with D-fructose in the presence of fluoride is described. For the first time, this allows the formation of a water-soluble, self-doped conducting polymer under the polymerization conditions. In turn this facilitates the growth of polyaniline over a wider pH range
Abstract translation: 描述了一种取代的聚苯胺，其自掺杂态可以通过在氟化物存在下与D-果糖在骨架上的硼酸基团之间的络合来控制。 第一次，这允许在聚合条件下形成水溶性的自掺杂的导电聚合物。 反过来，这有助于聚苯胺在更宽的pH范围内的生长
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公开(公告)号：US09777023B2
公开(公告)日：2017-10-03
申请号：US14118433
申请日：2012-05-18
Applicant: Parisa Mehrkhodavandi , Insun Yu , J. Alberto Acosta-Ramirez
Inventor： Parisa Mehrkhodavandi , Insun Yu , J. Alberto Acosta-Ramirez
CPC classification number: C07F5/00 , B01J31/2243 , B01J2531/0216 , B01J2531/0238 , B01J2531/33 , C08G63/823 , C08G63/84
Abstract: Provided are novel dinuclear indium catalysts of formula (A) that are capable of living and immortal ring opening polymerization and copolymerization of cyclic ester monomers for the preparation of biodegradable polymers and copolymers, in particular polyesters. Also disclosed are polymerization methods and polymer products. These dinuclear indium catalysts allow less costly, highly reactive living polymerization of cyclic ester monomers with possible high turn over rates and/or substantial stereo-chemical and microstructure control.
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公开(公告)号：US08658759B2
公开(公告)日：2014-02-25
申请号：US10581752
申请日：2004-12-06
Applicant: Bhavana A. Deore , Insun Yu , Michael S. Freund
Inventor： Bhavana A. Deore , Insun Yu , Michael S. Freund
IPC: C08G73/00
CPC classification number: C08G73/0266 , H01B1/128
Abstract: A substituted polyaniline whose self-doped state can be controlled via complexation between boronic acid groups along the backbone with D-fructose in the presence of fluoride is described. For the first time, this allows the formation of a water-soluble, self-doped conducting polymer under the polymerization conditions. In turn this facilitates the growth of polyaniline over a wider pH range.
Abstract translation: 描述了一种取代的聚苯胺，其自掺杂态可以通过在氟化物存在下与D-果糖在骨架上的硼酸基团之间的络合来控制。 第一次，这允许在聚合条件下形成水溶性的自掺杂的导电聚合物。 反过来，这有助于聚苯胺在更宽的pH范围内的生长。
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公开(公告)号：US20100270507A1
公开(公告)日：2010-10-28
申请号：US12161235
申请日：2007-01-19
Applicant: Michael S. Freund , Bhavana A. Deore , Insun Yu
Inventor： Michael S. Freund , Bhavana A. Deore , Insun Yu
CPC classification number: C08G73/0266
Abstract: A method for producing a polymer comprising reacting a fluoride and a monomer having a boronic acid moiety, or a salt thereof, in acidic aqueous solution and/or in an aliphatic alcohol. Polymerization occurs with the addition of an oxidizing agent. The method may further comprise the step of purification of the polymer by centrifugation with 0.5 M HCl and/or dispersion of the polymer in a solvent. The polymer has a morphology tunable by changing the solvent.
Abstract translation: 一种制备聚合物的方法，包括使氟化物和具有硼酸部分的单体或其盐在酸性水溶液和/或脂族醇中反应。 通过加入氧化剂进行聚合。 该方法还可以包括通过用0.5M HCl离心和/或在溶剂中分散聚合物来纯化聚合物的步骤。 通过改变溶剂，聚合物具有可调谐的形态。
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