公开(公告)号：US06806238B1

公开(公告)日：2004-10-19

申请号：US10111002

申请日：2002-07-24

申请人： Gilles Lorentz ,  Jean-Marie Georgees

发明人： Gilles Lorentz ,  Jean-Marie Georgees

IPC分类号： C10M17302

CPC分类号： C10M173/02 ,  C10M171/06 ,  C10N2220/082 ,  C10N2230/06 ,  C10N2240/40

摘要： The invention concerns the use as extreme pressure additive in aqueous lubricants used for deforming or transforming metals, lamellar crystallites having a length (L) ranging between 0.1 and 100 &mgr;m, a width (I) ranging between 0.5 and 30 &mgr;m and a thickness (e) ranging between 5 and 200 nm, comprising a stack of organic phases (O) and of aqueous solutions (A) in the sequence O/[A/O]n, n being an integer different from 0 and such that the stack has a thickness between 5 and 200 nm, the organic phases comprising: i) at least an acid selected among: carboxylic acid, saturated or unsaturated, comprising at least 5 carbon atoms, acid phosphate esters of formula (RO)x—P(═O)(OH)x′ wherein R is a hydrocarbon radical, optionally polyalkoxylated, x and x′ being equal to 1 or 2, provided that the sum of x and x′ is equal to 3, said acid being optionally neutralized by an organic or mineral base; and at least a metal in the form of a multivalent ion; or (ii) at least a polyalkylene block polymer having a cloud point preferably ranging between 30 and 90° C. The invention also concerns said lamellar crystallites and a method for obtaining them.

摘要翻译： 本发明涉及用作用于使金属变形或转化的水性润滑剂中的极压添加剂，其长度（L）范围为0.1至100μm，宽度（I）范围在0.5至30μm之间的片层微晶和厚度（e ）范围在5至200nm之间，包含有序相（O）和水溶液（A）的叠层，其顺序为O / [A / O] n，n为不同于0的整数，并且使得所述叠层具有 有机相包含：i）至少一种酸选自：含有至少5个碳原子的饱和或不饱和羧酸，式（RO）xP（= O）（OH）的酸式磷酸酯 ）x'，其中R是烃基，任选地被聚烷氧基化，x和x'等于1或2，条件是x和x'之和等于3，所述酸任选地被有机或无机碱中和; 和至少一种多价离子形式的金属; 或（ii）至少具有浊点在30-90℃之间的聚点的聚亚烷基嵌段聚合物。本发明还涉及所述层状微晶及其获得方法。