Catalysts for Olefin Hydration and Method of Preparation
    2.
    发明申请
    Catalysts for Olefin Hydration and Method of Preparation 审中-公开
    烯烃水合催化剂及其制备方法

    公开(公告)号:US20110136926A1

    公开(公告)日:2011-06-09

    申请号:US12962798

    申请日:2010-12-08

    IPC分类号: B01J39/00

    CPC分类号: B01J31/10 B01J2231/645

    摘要: The present invention is directed to a polystyrene cation exchange resin catalyst for olefin hydration comprises: monomer units of (a) 7.5 to 11.5 wt % at least one polyvinylaromatic monomer and (b) 88.5 to 92.5 wt % at least one monovinylaromatic monomer; (c) 0.75 to 1.20 SO3H moiety on each aromatic ring of the polymer backbone; and (d) 0.70 to 1.20 halogen on each aromatic ring of the polymer backbone. The present invention also provides a method for preparing the catalyst including the steps of copolymerization, sulfonation, halogenation, and post treatment. Optimization of the copolymer crosslinking degree, sulfonation and halogenation extent enables the catalyst with a balance of catalysis activity and thermal stability.

    摘要翻译: 本发明涉及用于烯烃水合的聚苯乙烯阳离子交换树脂催化剂,其包含:(a)7.5至11.5wt%的至少一种聚乙烯基芳族单体和(b)88.5至92.5wt%的至少一种单乙烯基芳族单体的单体单元; (c)在聚合物主链的每个芳环上为0.75至1.20个SO 3 H部分; 和(d)聚合物主链的每个芳香环上的0.70至1.20个卤素。 本发明还提供了一种制备催化剂的方法,包括共聚,磺化,卤化和后处理的步骤。 共聚物交联度,磺化和卤化程度的优化使得催化剂具有催化活性和热稳定性的平衡。