公开(公告)号：US06168768A

公开(公告)日：2001-01-02

申请号：US09012537

申请日：1998-01-23

申请人： Dennis G. Alexion ,  Robert B. Fedich ,  John C. Wilbur ,  James H. Taylor, Jr. ,  James P. Glass, Jr. ,  Geoffrey R. Say ,  Richard P. O'Connor

发明人： Dennis G. Alexion ,  Robert B. Fedich ,  John C. Wilbur ,  James H. Taylor, Jr. ,  James P. Glass, Jr. ,  Geoffrey R. Say ,  Richard P. O'Connor

IPC分类号： B01D4700

CPC分类号： C10L3/10 ,  B01D53/04 ,  B01D53/48 ,  B01D53/52 ,  B01D2253/112 ,  B01D2256/16 ,  B01D2256/20 ,  B01D2256/24 ,  B01D2257/30 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2258/06 ,  B01D2259/402

摘要： Sour natural gas is processed to remove the sulfur compounds and recover C4+/C5+ hydrocarbons by scrubbing the gas with an amine solution to remove most of the sulfur, followed cooling the gas to remove C4+/C5+ hydrocarbons and more sulfur compounds as liquid condensate to produce a gas having less than 20 vppm of total sulfur. The condensate is sent to a fractionator to recover the C4+C5+ hydrocarbons. The sulfur and hydrocarbon reduced gas is contacted first with zinc oxide and then nickel, to produce a gas having less than 10 vppb of total sulfur which is passed into a synthesis gas generating unit to form a very low sulfur synthesis gas comprising a mixture of H2 and CO. This synthesis gas is useful for hydrocarbon synthesis with increased life of the hydrocarbon synthesis catalyst and greater hydrocarbon production from the hydrocarbon synthesis reactor. Contacting the synthesis gas with zinc oxide further reduces the sulfur content to below 3 vppb.

摘要翻译： 处理酸性天然气以除去硫化合物并通过用胺溶液洗涤气体以除去大部分硫来回收C4 + / C5 +烃，然后冷却气体以除去C4 + / C5 +烃和更多的硫化合物作为液体冷凝物产生 总硫含量低于20ppm的气体。 将冷凝物送至分馏器以回收C4 + C5 +烃。 硫和烃还原气体首先与氧化锌和镍接触，以产生小于10vppb的总硫的气体，其通入合成气生成单元中以形成非常低的硫合成气，其包含H 2 和CO。该合成气可用于烃合成，烃合成催化剂的寿命增加，并且来自烃合成反应器的更大的烃产量。 将合成气与氧化锌接触进一步将硫含量降低至低于3 vppb。

公开(公告)号：US06692711B1

公开(公告)日：2004-02-17

申请号：US09586089

申请日：2000-06-02

申请人： Dennis G. Alexion ,  Robert B. Fedich ,  John C. Wilbur ,  James H. Taylor, Jr. ,  James P. Glass, Jr. ,  Geoffrey R. Say ,  Richard P. O'Connor

发明人： Dennis G. Alexion ,  Robert B. Fedich ,  John C. Wilbur ,  James H. Taylor, Jr. ,  James P. Glass, Jr. ,  Geoffrey R. Say ,  Richard P. O'Connor

IPC分类号： B01D4700

CPC分类号： C10L3/10 ,  B01D53/04 ,  B01D53/48 ,  B01D53/52 ,  B01D2253/112 ,  B01D2256/16 ,  B01D2256/20 ,  B01D2256/24 ,  B01D2257/30 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2258/06 ,  B01D2259/402

摘要： Sour natural gas is processed to remove the sulfur compounds and recover C4+/C5+ hydrocarbons by scrubbing the gas with an amine solution to remove most of the sulfur, followed cooling the gas to remove C4+/C5+ hydrocarbons and more sulfur compounds as liquid condensate to produce a gas having less than 20 vppm of total sulfur. The condensate is sent to a fractionator to recover the C4+/C5+ hydrocarbons. The sulfur and hydrocarbon reduced gas is contacted first with zinc oxide and then nickel, to produce a gas having less than 10 vppb of total sulfur which is passed into a synthesis gas generating unit to form a very low sulfur synthesis gas comprising a mixture of H2 and CO. This synthesis gas is useful for hydrocarbon synthesis with increased life of the hydrocarbon synthesis catalyst and greater hydrocarbon production from the hydrocarbon synthesis reactor. Contacting the synthesis gas with zinc oxide further reduces the sulfur content to below 3 vppb.

摘要翻译： 处理酸性天然气以除去硫化合物并通过用胺溶液洗涤气体以除去大部分硫来回收C4 + / C5 +烃，然后冷却气体以除去C4 + / C5 +烃和更多的硫化合物作为液体冷凝物产生 总硫含量低于20ppm的气体。 将冷凝物送入分馏器以回收C4 + / C5 +烃。 硫和烃还原气体首先与氧化锌和镍接触，以产生小于10vppb的总硫的气体，其通入合成气生成单元中以形成非常低的硫合成气，其包含H 2 和CO。该合成气可用于烃合成，烃合成催化剂的寿命增加，并且来自烃合成反应器的更大的烃产量。 将合成气与氧化锌接触进一步将硫含量降低至低于3 vppb。