公开(公告)号：US20060141150A1

公开(公告)日：2006-06-29

申请号：US11023868

申请日：2004-12-27

Applicant: Lei Zheng ,  John Lean ,  Eric Castner ,  Thierry Florent Materne ,  Dane Parker ,  Frank Feher

Inventor： Lei Zheng ,  John Lean ,  Eric Castner ,  Thierry Florent Materne ,  Dane Parker ,  Frank Feher

IPC: B01J13/02

CPC classification number: C08F279/02 ,  C08F257/02 ,  C08F291/00 ,  C08F2/38

Abstract: The present invention discloses a process for producing a core-shell polymer that comprises: (1) preparing a monomer solution which is comprised of (a) at least one monomer, optional one crosslinking monomer (b) a conjugate acid of a surfactant with a pKa of less than 14, and (c) a controlled free radical polymerization agent; (2) preparing an aqueous medium which is comprised of (a) water, and (b) a conjugate base of a weak acid wherein the pKb of the base is less than 14; and (3) mixing the monomer solution with the aqueous medium under conditions that result in the in-situ formation of an emulsifier to produce a polymerization medium, and (4) initiating free radical polymerization within the polymerization medium to produce a core polymer, wherein the core contains a free radical control agents, (5) adding a second monomer to the polymerization medium containing the core polymer, and (6) allowing polymerization to proceed in the presence of the free radical control agent to produce the core-shell polymer.

Abstract translation: 本发明公开了一种制备核 - 壳聚合物的方法，其包括：（1）制备单体溶液，该单体溶液由（a）至少一种单体，任选的一种交联单体（b）表面活性剂的共轭酸与 pKa小于14，（c）受控自由基聚合剂; （2）制备由（a）水和（b）弱酸的共轭碱组成的水性介质，其中碱的pKb小于14; 和（3）在导致乳化剂原位形成以产生聚合介质的条件下将单体溶液与水性介质混合，和（4）在聚合介质内引发自由基聚合以制备芯聚合物，其中 核心包含自由基控制剂，（5）在含有核聚合物的聚合介质中加入第二单体，和（6）在自由基控制剂的存在下使聚合进行以制备核 - 壳聚合物。

公开(公告)号：US08435411B2

公开(公告)日：2013-05-07

申请号：US12959436

申请日：2010-12-03

Applicant: John Lean ,  Scott Griffin ,  Matthew Taylor

Inventor： John Lean ,  Scott Griffin ,  Matthew Taylor

IPC: C02F1/54

CPC classification number: B01D17/0208 ,  B01D17/047 ,  C22B3/0005 ,  C22B3/20 ,  Y02P10/234

Abstract: Methods of removing impurities from an impurity-loaded organic salt solution by intermixing the impurity-loaded organic salt solution with a stripping solution to form a biphasic mixture, wherein the intermixing effectively reduces the concentration of impurities in the impurity-loaded organic salt, thereby removing impurities from the organic salt and forming an impurity-reduced organic salt solution phase and a stripping solution phase are provided herein.

Abstract translation: 通过将杂质负载有机盐溶液与剥离溶液混合以形成双相混合物从杂质负载的有机盐溶液中除去杂质的方法，其中混合有效地降低杂质负载的有机盐中的杂质浓度，由此除去 本文提供了来自有机盐的杂质并形成杂质还原的有机盐溶液相和汽提溶液相。

公开(公告)号：US20110140037A1

公开(公告)日：2011-06-16

申请号：US12959436

申请日：2010-12-03

Applicant: John LEAN ,  Scott GRIFFIN ,  Matthew TAYLOR

Inventor： John LEAN ,  Scott GRIFFIN ,  Matthew TAYLOR

IPC: C09K3/00 ,  C07F9/54

CPC classification number: B01D17/0208 ,  B01D17/047 ,  C22B3/0005 ,  C22B3/20 ,  Y02P10/234

Abstract: Methods of removing impurities from an impurity-loaded organic salt solution by intermixing the impurity-loaded organic salt solution with a stripping solution to form a biphasic mixture, wherein the intermixing effectively reduces the concentration of impurities in the impurity-loaded organic salt, thereby removing impurities from the organic salt and forming an impurity-reduced organic salt solution phase and a stripping solution phase are provided herein.

Abstract translation: 通过将杂质负载有机盐溶液与剥离溶液混合以形成双相混合物从杂质负载的有机盐溶液中除去杂质的方法，其中混合有效地降低杂质负载的有机盐中的杂质浓度，由此除去 本文提供了来自有机盐的杂质并形成杂质还原的有机盐溶液相和汽提溶液相。

公开(公告)号：US20050288393A1

公开(公告)日：2005-12-29

申请号：US10875413

申请日：2004-06-24

Applicant: John Lean ,  Manoj Ajbani ,  Eric Castner ,  Lei Zheng ,  Christopher Kiehl

Inventor： John Lean ,  Manoj Ajbani ,  Eric Castner ,  Lei Zheng ,  Christopher Kiehl

IPC: C08L83/00

CPC classification number: C08L51/003 ,  C08F257/00 ,  C08L23/10 ,  C08L53/025 ,  C08L2205/03 ,  C08F236/04 ,  C08L2666/02

Abstract: A thermoplastic elastomer composition comprised of (a) a thermoplastic resin selected from the group consisting of polyphenylene ether, polypropylene, polyethylene, and polystyrene, (b) a block copolymer selected from the group consisting of styrene-ethylene butylene-styrene, styrene-ethylene propylene-styrene, hydrogenated polybutadiene, hydrogenated polyisoprene, hydrogenated styrene-isoprene random copolymer, styrene-ethylene propylene block copolymer, styrene-ethylene ethylene propylene-styrene and hydrogenated styrene-butadiene random copolymers, (c) a core-shell polymer comprised of a polymeric core and a polymeric shell with the proviso that the polymeric core and/or the polymeric shell may be crosslinked, and (d) an oil.

Abstract translation: 一种热塑性弹性体组合物，其包含（a）选自聚苯醚，聚丙烯，聚乙烯和聚苯乙烯的热塑性树脂，（b）嵌段共聚物，其选自苯乙烯 - 乙烯 - 丁烯 - 苯乙烯，苯乙烯 - 乙烯 丙烯 - 苯乙烯，氢化聚丁二烯，氢化聚异戊二烯，氢化苯乙烯 - 异戊二烯无规共聚物，苯乙烯 - 乙烯丙烯嵌段共聚物，苯乙烯 - 乙烯乙烯丙烯 - 苯乙烯和氢化苯乙烯 - 丁二烯无规共聚物，（c） 聚合物芯和聚合物壳，条件是聚合物芯和/或聚合物壳可以是交联的，和（d）油。