公开(公告)号：US08227083B2

公开(公告)日：2012-07-24

申请号：US12224812

申请日：2007-03-06

申请人： Kaoru Isobe ,  Katsuichi Chiba ,  Takanori Sakamoto

发明人： Kaoru Isobe ,  Katsuichi Chiba ,  Takanori Sakamoto

IPC分类号： B32B5/16 ,  B05D7/00 ,  C01G23/04 ,  H01B1/08 ,  H01B1/16

CPC分类号： C01G23/047 ,  C01G23/00 ,  C01G23/053 ,  C01G23/0536 ,  C01P2004/12 ,  C01P2004/30 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/40 ,  C04B35/62805 ,  C04B35/62886 ,  C04B2235/3232 ,  C04B2235/3886 ,  C04B2235/3895 ,  C04B2235/5296 ,  C04B2235/5409 ,  C04B2235/5436 ,  H01G9/2031 ,  Y02E10/542 ,  Y02P70/521 ,  Y10T428/2982 ,  Y10T428/2991

摘要： Titanium dioxide and an electro-conductive titanium oxide which each includes particles having a large major-axis length in a large proportion and comprises columnar particles having a satisfactory particle size distribution. A titanium compound, an alkali metal compound, and an oxyphosphorus compound are heated/fired in the presence of titanium dioxide nucleus crystals having an aspect ratio of 2 or higher to grow the titanium dioxide nucleus crystals. Subsequently, a titanium compound, an alkali metal compound, and an oxyphosphorus compound are further added and heated/fired in the presence of the grown titanium dioxide nucleus crystals. Thus, titanium dioxide is produced which comprises columnar particles having a weight-average major-axis length of 7.0-15.0 μm and in which particles having a major-axis length of 10 μm or longer account for 15 wt. % or more of all the particles. A solution of a tin compound and a solution of compounds of antimony, phosphorus, etc. are added to a suspension obtained by suspending the titanium dioxide. The particles are sedimented. Subsequently, the product obtained is heated/fired to produce an electro-conductive titanium oxide which comprises the titanium dioxide and an electro-conductive coating formed on the surface thereof.

摘要翻译： 二氧化钛和导电性氧化钛，其各自包括大比例的长轴长度大的颗粒，并且包括具有令人满意的粒度分布的柱状颗粒。 在长宽比为2以上的二氧化钛核晶体的存在下，对钛化合物，碱金属化合物和氧磷化合物进行加热烧成，生长二氧化钛核晶体。 随后，在生长的二氧化钛核晶体的存在下，进一步添加钛化合物，碱金属化合物和氧磷化合物并加热/烧制。 因此，制造二氧化钛，其包括重均长轴长度为7.0-15.0μm的柱状颗粒，其中长轴长度为10μm或更大的颗粒占15重量％。 所有颗粒的百分比或更多。 将锡化合物和锑，磷等化合物的溶液加入到通过悬浮二氧化钛获得的悬浮液中。 颗粒沉淀。 随后，将获得的产物加热/烧制以制备包含二氧化钛的导电氧化钛和在其表面上形成的导电涂层。

公开(公告)号：US07491349B2

公开(公告)日：2009-02-17

申请号：US11794269

申请日：2005-12-27

申请人： Hideo Takahashi ,  Kaoru Isobe ,  Katsuichi Chiba ,  Yuichi Yasuda

发明人： Hideo Takahashi ,  Kaoru Isobe ,  Katsuichi Chiba ,  Yuichi Yasuda

IPC分类号： H01B1/06

CPC分类号： C09C1/36 ,  B82Y30/00 ,  C01B21/0821 ,  C01G23/00 ,  C01P2002/60 ,  C01P2002/84 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/60 ,  C04B35/58014 ,  C04B35/62805 ,  C04B35/62807 ,  C04B35/62813 ,  C04B35/62821 ,  C04B35/62823 ,  C04B35/62886 ,  C04B35/62894 ,  C04B35/6325 ,  C04B2235/3232 ,  C04B2235/3418 ,  C04B2235/3886 ,  C04B2235/3895 ,  C04B2235/441 ,  C04B2235/449 ,  C04B2235/46 ,  C04B2235/465 ,  C04B2235/483 ,  C04B2235/5409 ,  C04B2235/5454 ,  C04B2235/549 ,  C04B2235/9661 ,  C09C1/3661

摘要： Disclosed is a titanium oxynitride with excellent hiding properties (light-blocking properties) which is also excellent in degree of blackness and oxidation stability. Specifically disclosed is a titanium oxynitride having a chemical composition expresses as TiNxOy.nSiO2 (wherein Ti represents titanium atoms; N represents nitrogen atoms; O represents oxygen atoms; Si represents silicon atoms; x represents the ratio of nitrogen atoms relative to titanium atoms, y represents the ratio of oxygen atoms relative to titanium atoms, and x and y are respectively a real number of more than 0 but less than 2; and n represents the molar ratio of SiO2 relative to TiNxOy which is a real number within a range of 0≦n≦0.05). This titanium oxynitride contains nitrogen atoms represented by N in an amount of not less than 17% by weight but less than 23% by weight, while having a specific surface area of 5-30 m2/g and a crystallite size determined by using an X-ray diffractometer of 17-25 nm.

摘要翻译： 公开了具有优异的黑色度和氧化稳定性优异的隐藏性（遮光性）的氮氧化钛。 具体公开了具有化学成分的钛氧氮化物表示为TiN x O y·nSiO 2（其中Ti表示钛原子; N表示氮原子; O表示氧原子; Si表示硅原子; x表示氮原子相对于钛原子的比例，y 表示氧原子相对于钛原子的比例，x和y分别是大于0但小于2的实数; n表示SiO 2相对于TiN x O y的摩尔比，实数为0的范围内的实数 <= n <= 0.05）。 该氮氧化钛含有氮含量不小于17重量％但小于23重量％的氮，而比表面积为5-30米2 /克，微晶尺寸通过使用X 17-25nm的射线衍射仪。

公开(公告)号：US08926713B2

公开(公告)日：2015-01-06

申请号：US13487370

申请日：2012-06-04

申请人： Kaoru Isobe ,  Katsuichi Chiba ,  Takanori Sakamoto

发明人： Kaoru Isobe ,  Katsuichi Chiba ,  Takanori Sakamoto

IPC分类号： C01G23/04 ,  C01G23/047 ,  C01G23/08 ,  C01G23/00 ,  C01G23/053 ,  H01G9/20 ,  C04B35/628 ,  B32B5/16

CPC分类号： C01G23/047 ,  C01G23/00 ,  C01G23/053 ,  C01G23/0536 ,  C01P2004/12 ,  C01P2004/30 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/40 ,  C04B35/62805 ,  C04B35/62886 ,  C04B2235/3232 ,  C04B2235/3886 ,  C04B2235/3895 ,  C04B2235/5296 ,  C04B2235/5409 ,  C04B2235/5436 ,  H01G9/2031 ,  Y02E10/542 ,  Y02P70/521 ,  Y10T428/2982 ,  Y10T428/2991

摘要： Titanium dioxide which includes particles having a large major-axis length in a large proportion and comprises columnar particles having a satisfactory particle size distribution. A titanium compound, an alkali metal compound, and an oxyphosphorus compound are heated/fired in the presence of titanium dioxide nucleus crystals having an aspect ratio of 2 or higher to grow the titanium dioxide nucleus crystals. Subsequently, a titanium compound, an alkali metal compound, and an oxyphosphorus compound are further added and heated/fired in the presence of the grown titanium dioxide nucleus crystals. Thus, titanium dioxide is produced which comprises columnar particles having a weight-average major-axis length of 7.0-15.0 μm and in which particles having a major-axis length of 10 μm or longer account for 15 wt. % or more of all the particles.

摘要翻译： 二氧化钛，其包括具有大比例的长轴长度的颗粒，并且包括具有令人满意的粒度分布的柱状颗粒。 在长宽比为2以上的二氧化钛核晶体的存在下，对钛化合物，碱金属化合物和氧磷化合物进行加热烧成，生长二氧化钛核晶体。 随后，在生长的二氧化钛核晶体的存在下，进一步添加钛化合物，碱金属化合物和氧磷化合物并加热/烧制。 因此，制造二氧化钛，其包括重均长轴长度为7.0-15.0μm的柱状颗粒，其中长轴长度为10μm或更大的颗粒占15重量％。 所有颗粒的百分比或更多。

公开(公告)号：US07785501B2

公开(公告)日：2010-08-31

申请号：US11722002

申请日：2005-12-27

申请人： Hiroaki Segawa ,  Kei Ikegami ,  Sachie Furukawa ,  Hideo Takahashi ,  Kaoru Isobe ,  Katsuichi Chiba ,  Yuichi Yasuda

发明人： Hiroaki Segawa ,  Kei Ikegami ,  Sachie Furukawa ,  Hideo Takahashi ,  Kaoru Isobe ,  Katsuichi Chiba ,  Yuichi Yasuda

IPC分类号： H01B1/06 ,  G02B5/20

CPC分类号： G02B5/205 ,  G02B5/003 ,  G02B5/201 ,  G02F1/133512

摘要： A black resin composition for a display device, which can achieve a high optical density even when its light-blocking agent content is relatively low and can achieve a high optical density even when it is formed into a thin film, and a member for display device which can reduce unevenness of display caused by a level difference in a pixel part resulting from the film thickness of the black resin composition. The black resin composition for a display device has a black titanium oxynitride represented by composition formula: TiNxOy-nSiO2 (wherein x and y each are a real number of larger than 0 but less than 2, and n is a real number within the range of 0 less than or equal to n less than or equal to 0.05), containing a nitrogen atom represented by N in an amount of 17 wt % or more but less than 23 wt %, and having a specific surface area of 5 to 30 m2/g and a crystalline size as measured with an X-ray diffractometer of 17 to 25 nm, and a curable binder system. Also, a member for display device having a light-blocking layer formed using the said black resin composition for display device.

摘要翻译： 一种用于显示装置的黑色树脂组合物，即使其遮光剂含量相对较低也能够获得高的光密度，并且即使形成为薄膜也可以实现高的光密度，以及显示装置的构件 这可以减少由黑色树脂组合物的膜厚度导致的像素部分的电平差引起的显示不均匀。 用于显示装置的黑色树脂组合物具有由组成式：TiN x O y-n SiO 2（其中x和y各自是大于0但小于2的实数）表示的黑色氮氧化钛，并且n是在 0以下，n小于或等于0.05），含有由17重量％以上且小于23重量％的N表示的氮原子，比表面积为5〜30m 2 / g和用17至25nm的X射线衍射仪测量的结晶尺寸和可固化粘合剂体系。 而且，具有使用该显示装置用黑色树脂组合物形成的遮光层的显示装置用部件。

公开(公告)号：US06833088B1

公开(公告)日：2004-12-21

申请号：US10069782

申请日：2002-02-28

申请人： Kaoru Isobe ,  Masanori Tomonari ,  Tsutomu Kikuchi

发明人： Kaoru Isobe ,  Masanori Tomonari ,  Tsutomu Kikuchi

IPC分类号： H01B120

CPC分类号： C09C1/0096 ,  C01P2002/50 ,  C01P2004/10 ,  C01P2004/20 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/84 ,  C01P2006/12 ,  C01P2006/22 ,  C01P2006/40 ,  C01P2006/60 ,  C01P2006/80 ,  C01P2006/90 ,  C09C3/08 ,  C09C3/12 ,  C09D5/24 ,  C09K3/16 ,  H01B1/20

摘要： The organic solvent-based dispersion of conductive powders of the present invention comprises an organic solvent-based medium as a dispersion medium, conductive tin oxide powders coated with an organic metal coupling agent at the surface of tin oxide particles and a dispersant, and shows excellent dispersibility and high transparency. Therefore, the dispersion is useful for antistatic purpose of transparent substrates including the display surface of display devices, their surface protecting materials, films, etc.

摘要翻译： 本发明的导电性粉末的有机溶剂系分散体包含作为分散介质的有机溶剂系介质，在氧化锡粒子表面涂布有机金属偶联剂的导电性氧化锡粉末和分散剂， 分散性和高透明度。 因此，该分散体对于包括显示装置的显示面，其表面保护材料，膜等的透明基板的抗静电性有用。

公开(公告)号：US20080318018A1

公开(公告)日：2008-12-25

申请号：US11722002

申请日：2005-12-27

申请人： Hiroaki Segawa ,  Kei Ikegami ,  Sachie Furukawa ,  Hideo Takahashi ,  Kaoru Isobe ,  Katsuichi Chiba ,  Yuichi Yasuda

发明人： Hiroaki Segawa ,  Kei Ikegami ,  Sachie Furukawa ,  Hideo Takahashi ,  Kaoru Isobe ,  Katsuichi Chiba ,  Yuichi Yasuda

IPC分类号： B32B27/00

CPC分类号： G02B5/205 ,  G02B5/003 ,  G02B5/201 ,  G02F1/133512

摘要： A black resin composition for a display device, which can achieve a high optical density even when its light-blocking agent content is relatively low and can achieve a high optical density even when it is formed into a thin film, and a member for display device which can reduce unevenness of display caused by a level difference in a pixel part resulting from the film thickness of the black resin composition. The black resin composition for a display device has a black titanium oxynitride represented by composition formula: TiNxOy-nSiO2 (wherein x and y each are a real number of larger than 0 but less than 2, and n is a real number within the range of 0≦n≦0.05), containing a nitrogen atom represented by N in an amount of 17 wt % or more but less than 23 wt %, and having a specific surface area of 5 to 30 m2/g and a crystalline size as measured with an X-ray diffractometer of 17 to 25 nm, and a curable binder system. Also, a member for display device having a light-blocking layer formed using the said black resin composition for display device.

摘要翻译： 一种用于显示装置的黑色树脂组合物，即使其遮光剂含量相对较低也能够获得高的光密度，并且即使形成为薄膜也可以实现高的光密度，以及显示装置的构件 这可以减少由黑色树脂组合物的膜厚度导致的像素部分的电平差引起的显示不均匀。 用于显示装置的黑色树脂组合物具有由组成式：TiN x O y-n SiO 2（其中x和y各自是大于0但小于2的实数）表示的黑色氮氧化钛，并且n是在 0≤n≤0.05），含有17重量％以上且小于23重量％的N表示的氮原子，比表面积为5〜30m 2 / g，结晶尺寸为 用17至25nm的X射线衍射仪测量，和可固化的粘合剂体系。 而且，具有使用该显示装置用黑色树脂组合物形成的遮光层的显示装置用部件。

公开(公告)号：US20080017835A1

公开(公告)日：2008-01-24

申请号：US11794269

申请日：2005-12-27

申请人： Hideo Takahashi ,  Kaoru Isobe ,  Katsuichi Chiba ,  Yuichi Yasuda

发明人： Hideo Takahashi ,  Kaoru Isobe ,  Katsuichi Chiba ,  Yuichi Yasuda

IPC分类号： H01B1/02

CPC分类号： C09C1/36 ,  B82Y30/00 ,  C01B21/0821 ,  C01G23/00 ,  C01P2002/60 ,  C01P2002/84 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/60 ,  C04B35/58014 ,  C04B35/62805 ,  C04B35/62807 ,  C04B35/62813 ,  C04B35/62821 ,  C04B35/62823 ,  C04B35/62886 ,  C04B35/62894 ,  C04B35/6325 ,  C04B2235/3232 ,  C04B2235/3418 ,  C04B2235/3886 ,  C04B2235/3895 ,  C04B2235/441 ,  C04B2235/449 ,  C04B2235/46 ,  C04B2235/465 ,  C04B2235/483 ,  C04B2235/5409 ,  C04B2235/5454 ,  C04B2235/549 ,  C04B2235/9661 ,  C09C1/3661

摘要： Disclosed is a titanium oxynitride with excellent hiding properties (light-blocking properties) which is also excellent in degree of blackness and oxidation stability. Specifically disclosed is a titanium oxynitride having a chemical composition expresses as TiNxOy.nSiO2 (wherein Ti represents titanium atoms; N represents nitrogen atoms; O represents oxygen atoms; Si represents silicon atoms; x represents the ratio of nitrogen atoms relative to titanium atoms, y represents the ratio of oxygen atoms relative to titanium atoms, and x and y are respectively a real number of more than 0 but less than 2; and n represents the molar ratio of SiO2 relative to TiNxOy which is a real number within a range of 0≦n≦0.05). This titanium oxynitride contains nitrogen atoms represented by N in an amount of not less than 17% by weight but less than 23% by weight, while having a specific surface area of 5-30 m2/g and a crystallite size determined by using an X-ray diffractometer of 17-25 nm.

摘要翻译： 公开了具有优异的黑色度和氧化稳定性优异的隐藏性（遮光性）的氮氧化钛。 具体公开了具有化学组成的钛氮氧化物，其表示为TiN x O y.n SiO 2（其中Ti表示钛原子; N表示氮原子; O表示氧原子; Si表示硅原子; x表示 氮原子相对于钛原子，y表示氧原子相对于钛原子的比例，x和y分别是大于0但小于2的实数; n表示SiO 2的摩尔比， / SUB>相对于TiNxOy，其为0≤n≤0.0的范围内的实数）。 这种氮氧化钛含有不少于17重量％但小于23重量％的N表示的氮原子，而比表面积为5-30微米2 /克， 通过使用17-25nm的X射线衍射仪测定的微晶尺寸。

公开(公告)号：US20120288711A1

公开(公告)日：2012-11-15

申请号：US13487370

申请日：2012-06-04

申请人： Kaoru ISOBE ,  Katsuichi Chiba ,  Takanori Sakamoto

发明人： Kaoru ISOBE ,  Katsuichi Chiba ,  Takanori Sakamoto

IPC分类号： C01G23/047 ,  C08K3/22

CPC分类号： C01G23/047 ,  C01G23/00 ,  C01G23/053 ,  C01G23/0536 ,  C01P2004/12 ,  C01P2004/30 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/40 ,  C04B35/62805 ,  C04B35/62886 ,  C04B2235/3232 ,  C04B2235/3886 ,  C04B2235/3895 ,  C04B2235/5296 ,  C04B2235/5409 ,  C04B2235/5436 ,  H01G9/2031 ,  Y02E10/542 ,  Y02P70/521 ,  Y10T428/2982 ,  Y10T428/2991

摘要： Titanium dioxide which includes particles having a large major-axis length in a large proportion and comprises columnar particles having a satisfactory particle size distribution. A titanium compound, an alkali metal compound, and an oxyphosphorus compound are heated/fired in the presence of titanium dioxide nucleus crystals having an aspect ratio of 2 or higher to grow the titanium dioxide nucleus crystals. Subsequently, a titanium compound, an alkali metal compound, and an oxyphosphorus compound are further added and heated/fired in the presence of the grown titanium dioxide nucleus crystals. Thus, titanium dioxide is produced which comprises columnar particles having a weight-average major-axis length of 7.0-15.0 μm and in which particles having a major-axis length of 10 μm or longer account for 15 wt. % or more of all the particles.

摘要翻译： 二氧化钛，其包括具有大比例的长轴长度的颗粒，并且包括具有令人满意的粒度分布的柱状颗粒。 在长宽比为2以上的二氧化钛核晶体的存在下，对钛化合物，碱金属化合物和氧磷化合物进行加热烧成，生长二氧化钛核晶体。 随后，在生长的二氧化钛核晶体的存在下，进一步添加钛化合物，碱金属化合物和氧磷化合物并加热/烧制。 因此，制造二氧化钛，其包括重均长轴长度为7.0-15.0μm的柱状颗粒，其中长轴长度为10μm或更大的颗粒占15重量％。 所有颗粒的百分比或更多。

公开(公告)号：US20090117383A1

公开(公告)日：2009-05-07

申请号：US12224812

申请日：2007-03-06

申请人： Kaoru Isobe ,  Katsuichi Chiba ,  Takanori Sakamoto

发明人： Kaoru Isobe ,  Katsuichi Chiba ,  Takanori Sakamoto

IPC分类号： B32B18/00 ,  B05D7/00 ,  C01G23/047 ,  H01B1/08

CPC分类号： C01G23/047 ,  C01G23/00 ,  C01G23/053 ,  C01G23/0536 ,  C01P2004/12 ,  C01P2004/30 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/40 ,  C04B35/62805 ,  C04B35/62886 ,  C04B2235/3232 ,  C04B2235/3886 ,  C04B2235/3895 ,  C04B2235/5296 ,  C04B2235/5409 ,  C04B2235/5436 ,  H01G9/2031 ,  Y02E10/542 ,  Y02P70/521 ,  Y10T428/2982 ,  Y10T428/2991

摘要： Titanium dioxide and an electro-conductive titanium oxide which each includes particles having a large major-axis length in a large proportion and comprises columnar particles having a satisfactory particle size distribution. A titanium compound, an alkali metal compound, and an oxyphosphorus compound are heated/fired in the presence of titanium dioxide nucleus crystals having an aspect ratio of 2 or higher to grow the titanium dioxide nucleus crystals. Subsequently, a titanium compound, an alkali metal compound, and an oxyphosphorus compound are further added and heated/fired in the presence of the grown titanium dioxide nucleus crystals. Thus, titanium dioxide is produced which comprises columnar particles having a weight-average major-axis length of 7.0-15.0 μm and in which particles having a major-axis length of 10 μm or longer account for 15 wt. % or more of all the particles. A solution of a tin compound and a solution of compounds of antimony, phosphorus, etc. are added to a suspension obtained by suspending the titanium dioxide. The particles are sedimented. Subsequently, the product obtained is heated/fired to produce an electro-conductive titanium oxide which comprises the titanium dioxide and an electro-conductive coating formed on the surface thereof.

摘要翻译： 二氧化钛和导电性氧化钛，其各自包括大比例的长轴长度大的颗粒，并且包括具有令人满意的粒度分布的柱状颗粒。 在长宽比为2以上的二氧化钛核晶体的存在下，对钛化合物，碱金属化合物和氧磷化合物进行加热烧成，生长二氧化钛核晶体。 随后，在生长的二氧化钛核晶体的存在下，进一步添加钛化合物，碱金属化合物和氧磷化合物并加热/烧制。 因此，生产二氧化钛，其包括重均长轴长度为7.0-15.0μm的柱状颗粒，其中长轴长度为10μm或更长的颗粒占15wt。 所有颗粒的百分比或更多。 将锡化合物和锑，磷等化合物的溶液加入到通过悬浮二氧化钛获得的悬浮液中。 颗粒沉淀。 随后，将获得的产物加热/烧制以制备包含二氧化钛的导电氧化钛和在其表面上形成的导电涂层。