公开(公告)号：US20100120984A1

公开(公告)日：2010-05-13

申请号：US12450778

申请日：2008-04-23

申请人： Masaaki Ozawa ,  Keisuke Odoi ,  Hironori Atarashi ,  Kei-ichi Akabori ,  Toshihiro Nagamura ,  Keiji Tanaka

发明人： Masaaki Ozawa ,  Keisuke Odoi ,  Hironori Atarashi ,  Kei-ichi Akabori ,  Toshihiro Nagamura ,  Keiji Tanaka

IPC分类号： C08L51/00 ,  C08L41/00

CPC分类号： C08J7/12 ,  C08L101/005

摘要： The present invention relates to a process for producing a polymer structure comprising: mixing and unifying a matrix polymer made of a linear polymer and a highly-branched polymer having hydrophilic functional groups at molecular ends and to form a structure containing the matrix polymer and the highly-branched polymer; and subjecting the obtained structure to either immersion in water and/or a hydrophilic solvent or exposure to an atmosphere of vapor of water and/or a hydrophilic solvent at a temperature ranging from a temperature lower than Tg of the matrix polymer by 30° C. to decomposition temperature of the matrix polymer; wherein the hydrophilic functional groups at the molecular ends of the highly-branched polymer are distributed in outermost surface of the polymer structure at an enhanced density. The present invention also relates to a process for producing a polymer structure in which vinyl polymer chains are grafted to at least a part of the hydrophilic functional groups.

摘要翻译： 本发明涉及一种聚合物结构体的制造方法，其特征在于，在分子末端将由线性聚合物构成的基质聚合物和具有亲水性官能团的高支化聚合物混合均匀并形成含有基体聚合物的结构， 支链聚合物 并将得到的结构物浸入水和/或亲水性溶剂中或在低于基体聚合物的Tg的温度范围内暴露于水和/或亲水性溶剂的气体的气氛中30℃。 到基体聚合物的分解温度; 其中高度支化聚合物的分子末端的亲水官能团以增强的密度分布在聚合物结构的最外表面。 本发明还涉及其中乙烯基聚合物链接枝至至少一部分亲水官能团的聚合物结构的方法。

公开(公告)号：US09029474B2

公开(公告)日：2015-05-12

申请号：US12450778

申请日：2008-04-23

申请人： Masaaki Ozawa ,  Keisuke Odoi ,  Hironori Atarashi ,  Kei-ichi Akabori ,  Toshihiko Nagamura ,  Keiji Tanaka

发明人： Masaaki Ozawa ,  Keisuke Odoi ,  Hironori Atarashi ,  Kei-ichi Akabori ,  Toshihiko Nagamura ,  Keiji Tanaka

IPC分类号： C08L51/00 ,  C08L41/00 ,  C08J7/12 ,  C08L101/00

CPC分类号： C08J7/12 ,  C08L101/005

摘要： The present invention relates to a process for producing a polymer structure comprising: mixing and unifying a matrix polymer made of a linear polymer and a highly-branched polymer having hydrophilic functional groups at molecular ends and to form a structure containing the matrix polymer and the highly-branched polymer; and subjecting the obtained structure to either immersion in water and/or a hydrophilic solvent or exposure to an atmosphere of vapor of water and/or a hydrophilic solvent at a temperature ranging from a temperature lower than Tg of the matrix polymer by 30° C. to decomposition temperature of the matrix polymer; wherein the hydrophilic functional groups at the molecular ends of the highly-branched polymer are distributed in outermost surface of the polymer structure at an enhanced density. The present invention also relates to a process for producing a polymer structure in which vinyl polymer chains are grafted to at least a part of the hydrophilic functional groups.

摘要翻译： 本发明涉及一种聚合物结构体的制造方法，其特征在于，在分子末端将由线性聚合物构成的基质聚合物和具有亲水性官能团的高支化聚合物混合均匀并形成含有基体聚合物的结构， 支链聚合物 并将得到的结构物浸入水和/或亲水性溶剂中或在低于基体聚合物的Tg的温度范围内暴露于水和/或亲水性溶剂的气体的气氛中30℃。 到基体聚合物的分解温度; 其中高度支化聚合物的分子末端的亲水官能团以增强的密度分布在聚合物结构的最外表面。 本发明还涉及其中乙烯基聚合物链接枝至至少一部分亲水官能团的聚合物结构的方法。