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公开(公告)号：US07786333B2
公开(公告)日：2010-08-31
申请号：US12389110
申请日：2009-02-19
申请人： Michael Van Der Puy , George R. Cook , Peter H. Sheidle , Kevin D. Uhrich , Haiyou Wang , Hsueh Sung Tung
发明人： Michael Van Der Puy , George R. Cook , Peter H. Sheidle , Kevin D. Uhrich , Haiyou Wang , Hsueh Sung Tung
CPC分类号： C07C17/25 , C07C17/354 , C07C17/38 , C07C19/14 , C07C19/08
摘要： A process for the production of fluorinated olefins, preferably fluorinated propenes, by contacting a feed stream containing a fluorinated olefin and hydrogen with a first amount of catalyst to produce the hydrofluorocarbon, wherein a first exit stream contains unreacted fluorinated olefin and hydrogen; contacting the first exit stream with a second amount of catalyst to produce a hydrofluorocarbon, wherein the second amount of catalyst is preferably greater than the first amount of catalyst; and contacting the hydrofluorocarbon with a catalyst for dehydrohalogenation to produce a product stream of fluorinated olefin.
摘要翻译： 通过使包含氟化烯烃和氢气的进料流与第一量催化剂接触以产生氢氟烃来生产氟化烯烃，优选氟化丙烯的方法，其中第一出口流含有未反应的氟化烯烃和氢; 使第一出口流与第二量的催化剂接触以产生氢氟烃，其中第二量的催化剂优选大于第一量的催化剂; 并将氢氟烃与用于脱卤化氢的催化剂接触以产生氟化烯烃的产物流。
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公开(公告)号：US08921623B2
公开(公告)日：2014-12-30
申请号：US13035239
申请日：2011-02-25
IPC分类号： C07C17/00 , C07C21/00 , C07C17/354
CPC分类号： C07C17/354 , C07C19/08 , C07C19/10
摘要： A process for the production of fluorinated alkanes by contacting a feed stream containing a fluorinated olefin and a reducing agent, preferably with a first amount of catalyst to produce a fluorinated alkane, at a first conversion level, wherein a first effluent stream contains unreacted fluorinated olefin and reducing agent; and contacting the first effluent stream under conditions effective to produce a higher level of conversion than said conversion level.
摘要翻译： 通过使包含氟化烯烃和还原剂的进料流，优选与第一量的催化剂接触以产生氟化烷烃，以第一转化水平接触生产氟化烷烃的方法，其中第一流出物流含有未反应的氟化烯烃 和还原剂; 以及在有效地产生比所述转化水平更高水平的转化率的条件下接触第一流出物流。
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公开(公告)号：US20110105807A1
公开(公告)日：2011-05-05
申请号：US12611288
申请日：2009-11-03
IPC分类号： C07C17/25
CPC分类号： C07C21/18 , C01B7/0718 , C01B7/0737 , C01B7/195 , C07C17/087 , C07C17/10 , C07C17/206 , C07C17/25 , Y02P20/125 , C07C19/10
摘要： Disclosed is a process for the manufacture of HFO-1234yf from TCP in three integrated steps that include hydrofluorination of TCP (tetrachloropropene) to HCFC-1233xf in the vapor phase followed by hydrofluorination of HCFC-1233xf to HCFC-244bb in the liquid phase which is then followed by dehydrochlorination in liquid or vapor phase to produce HFO-1234yf. The vapor phase hydrofluorination is carried out at a higher pressure than the liquid phase hydrofluorination, thereby eliminating the need for compression and/or intermediate recovery. Also, any HCl generated from this reaction is fed to the liquid phase hydrofluorination section to promote agitation and mixing. This results in a more economical process from an initial capital and operating cost versus conducting the 3-steps sequentially.
摘要翻译： 公开了一种从TCP制造HFO-1234yf的方法，其包括在气相中将TCP（四氯丙烯）氢氟化为HCFC-1233xf，然后在液相中HCFC-1233xf氢氟化为HCFC-244bb的三个整合步骤 然后在液相或汽相中进行脱氯化氢以产生HFO-1234yf。 气相氢氟化在比液相氢氟化更高的压力下进行，从而不需要压缩和/或中间回收。 此外，将由该反应生成的任何HCl进料至液相氢氟化部分以促进搅拌和混合。 这导致了从初始资本和运营成本的更经济的过程，而不是依次执行3个步骤。
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公开(公告)号：US07902410B2
公开(公告)日：2011-03-08
申请号：US11588671
申请日：2006-10-27
CPC分类号： C07C17/354 , C07C19/08 , C07C19/10
摘要： A process for the production of fluorinated alkanes by contacting a feed stream containing a fluorinated olefin and a reducing agent, preferably with a first amount of catalyst to produce a fluorinated alkane, at a first conversion level, wherein a first effluent stream contains unreacted fluorinated olefin and reducing agent; and contacting the first effluent stream under conditions effective to produce a higher level of conversion than said conversion level.
摘要翻译： 通过使包含氟化烯烃和还原剂的进料流，优选与第一量的催化剂接触以产生氟化烷烃，以第一转化水平接触生产氟化烷烃的方法，其中第一流出物流含有未反应的氟化烯烃 和还原剂; 以及在有效地产生比所述转化水平更高水平的转化率的条件下接触第一流出物流。
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公开(公告)号：US07560602B2
公开(公告)日：2009-07-14
申请号：US11588464
申请日：2006-10-27
申请人： Michael Van Der Puy , George R. Cook , Peter H. Scheidle , Kevin D. Uhrich , Haiyou Wang , Hsueh Sung Tung
发明人： Michael Van Der Puy , George R. Cook , Peter H. Scheidle , Kevin D. Uhrich , Haiyou Wang , Hsueh Sung Tung
CPC分类号： C07C17/25 , C07C17/354 , C07C17/38 , C07C19/14 , C07C19/08
摘要： A process for the production of fluorinated olefins, preferably fluorinated propenes, by contacting a feed stream containing a fluorinated olefin and hydrogen with a first amount of catalyst to produce the hydrofluorocarbon, wherein a first exit stream contains unreacted fluorinated olefin and hydrogen; contacting the first exit stream with a second amount of catalyst to produce a hydrofluorocarbon, wherein the second amount of catalyst is preferably greater than the first amount of catalyst; and contacting the hydrofluorocarbon with a catalyst for dehydrohalogenation to produce a product stream of fluorinated olefin.
摘要翻译： 通过使包含氟化烯烃和氢气的进料流与第一量催化剂接触以产生氢氟烃来生产氟化烯烃，优选氟化丙烯的方法，其中第一出口流含有未反应的氟化烯烃和氢; 使第一出口流与第二量的催化剂接触以产生氢氟烃，其中第二量的催化剂优选大于第一量的催化剂; 并将氢氟烃与用于脱卤化氢的催化剂接触以产生氟化烯烃的产物流。
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公开(公告)号：US09890096B2
公开(公告)日：2018-02-13
申请号：US13313649
申请日：2011-12-07
申请人： Stephen A. Cottrell , Yuon Chiu , Haluk Kopkalli , Hsueh Sung Tung , Kevin D. Uhrich , Peter Scheidle
发明人： Stephen A. Cottrell , Yuon Chiu , Haluk Kopkalli , Hsueh Sung Tung , Kevin D. Uhrich , Peter Scheidle
IPC分类号： C07C17/25 , C07C17/38 , C07C17/383 , C07C17/21 , C07C17/20 , C07C17/087
CPC分类号： C07C17/21 , C07C17/087 , C07C17/206 , C07C17/25 , C07C17/38 , C07C17/383 , C07C19/10 , C07C21/18
摘要： Disclosed is a process for the manufacture of 1234yf from 1,1,2,3-tetrachloropropene, abbreviated herein as “TCP,” in three integrated steps: (a) the R-1 hydrofluorination of TCP to form 1233xf in the vapor phase; (b) the R-2 hydrofluorination of 1233xf to form 244bb in either the liquid phase or in the liquid phase followed by the vapor phase; and (c) the R-3 dehydrochlorination of the 244bb in either the liquid or the vapor phase to produce 1234yf; wherein the vapor phase hydrofluorination of TCP in step (a) is carried out at a higher pressure than the liquid phase hydrofluorination of 1233xf; andwherein the HC1 generated during these steps is scrubbed with water to form an acid solution and the organic components are scrubbed with a caustic solution and then dried before further processing.
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公开(公告)号：US20120184785A1
公开(公告)日：2012-07-19
申请号：US13313649
申请日：2011-12-07
申请人： Stephen A. Cottrell , Yuon Chiu , Haluk Kopkalli , Hsueh Sung Tung , Kevin D. Uhrich , Peter Scheidle
发明人： Stephen A. Cottrell , Yuon Chiu , Haluk Kopkalli , Hsueh Sung Tung , Kevin D. Uhrich , Peter Scheidle
IPC分类号： C07C21/18
CPC分类号： C07C17/21 , C07C17/087 , C07C17/206 , C07C17/25 , C07C17/38 , C07C17/383 , C07C19/10 , C07C21/18
摘要： Disclosed is a process for the manufacture of 1234yf from 1,1,2,3-tetrachloropropene, abbreviated herein as “TCP,” in three integrated steps: (a) the R-1 hydrofluorination of TCP to form 1233xf in the vapor phase; (b) the R-2 hydrofluorination of 1233xf to form 244bb in either the liquid phase or in the liquid phase followed by the vapor phase; and (c) the R-3 dehydrochlorination of the 244bb in either the liquid or the vapor phase to produce 1234yf; wherein the vapor phase hydrofluorination of TCP in step (a) is carried out at a lower pressure than the liquid phase hydrofluorination of 123xf; and wherein the HCl generated during these steps is scrubbed with water to form an acid solution and the organic components are scrubbed with a caustic solution and then dried before further processing.
摘要翻译： 公开了一种在1,1,3,3-四氯丙烯中制备1234yf的方法，在本文中简称为“TCP”，在三个一体化步骤中：（a）TCP的R-1氢氟化在气相中形成1233xf; （b）1233xf的R-2氢氟化在液相或液相中形成244bb，随后是气相; 和（c）244bb在液相或气相中的R-3脱氯化氢以产生1234yf; 其中步骤（a）中TCP的气相氢氟化在比123xf的液相氢氟化更低的压力下进行; 并且其中在这些步骤期间产生的HCl用水洗涤以形成酸溶液，并且用苛性碱溶液洗涤有机组分，然后在进一步加工之前干燥。
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公开(公告)号：US20090209791A1
公开(公告)日：2009-08-20
申请号：US12389110
申请日：2009-02-19
申请人： Michael Van Der Puy , George R. Cook , Peter H. Sheidle , Kevin D. Uhrich , Haiyou Wang , Hsueh Sung Tung
发明人： Michael Van Der Puy , George R. Cook , Peter H. Sheidle , Kevin D. Uhrich , Haiyou Wang , Hsueh Sung Tung
CPC分类号： C07C17/25 , C07C17/354 , C07C17/38 , C07C19/14 , C07C19/08
摘要： A process for the production of fluorinated olefins, preferably fluorinated propenes, by contacting a feed stream containing a fluorinated olefin and hydrogen with a first amount of catalyst to produce the hydrofluorocarbon, wherein a first exit stream contains unreacted fluorinated olefin and hydrogen; contacting the first exit stream with a second amount of catalyst to produce a hydrofluorocarbon, wherein the second amount of catalyst is preferably greater than the first amount of catalyst; and contacting the hydrofluorocarbon with a catalyst for dehydrohalogenation to produce a product stream of fluorinated olefin.
摘要翻译： 通过使包含氟化烯烃和氢气的进料流与第一量催化剂接触以产生氢氟烃来生产氟化烯烃，优选氟化丙烯的方法，其中第一出口流含有未反应的氟化烯烃和氢; 使第一出口流与第二量的催化剂接触以产生氢氟烃，其中第二量的催化剂优选大于第一量的催化剂; 并将氢氟烃与用于脱卤化氢的催化剂接触以产生氟化烯烃的产物流。
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公开(公告)号：US4880510A
公开(公告)日：1989-11-14
申请号：US293594
申请日：1989-01-05
申请人： Kevin D. Uhrich
发明人： Kevin D. Uhrich
CPC分类号： C02F1/463 , C02F1/5236
摘要： A process for removing color impurities such as dye stuffs from wastewater solutions and simultaneously removing heavy metal contaminants is described. The process includes passing the wastewater solution through an electrolytic cell, having an anode of iron, an iron alloy, or an insoluble iron compound to generate ferrous iron at the anode which then reacts with hydroxide ion generated at the cathode causing a coprecipitation of the impurities with insoluble ferrous hydroxide.
摘要翻译： 描述了从废水溶液中除去诸如染料的颜色杂质并同时除去重金属污染物的方法。 该方法包括使废水溶液通过电解池，其具有铁阳极，铁合金或不溶性铁化合物，以在阳极产生亚铁，然后与在阴极处产生的氢氧根离子反应，使杂质共沉淀 用不溶性氢氧化亚铁。
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