公开(公告)号：US4479012A

公开(公告)日：1984-10-23

申请号：US363565

申请日：1982-03-30

申请人： Karl Fischer ,  Armin V. Grenacher ,  Manfred Herr ,  Max Strohmeyer

发明人： Karl Fischer ,  Armin V. Grenacher ,  Manfred Herr ,  Max Strohmeyer

IPC分类号： B01J23/00 ,  B01J23/46 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C45/81 ,  C07C45/82 ,  C07C47/02 ,  C07C67/00 ,  B01D3/14

CPC分类号： C07C45/81 ,  C07C45/50 ,  C07C45/82 ,  Y02P20/582 ,  Y10S203/06 ,  Y10S203/09

摘要： Aldehydes are obtained from the gaseous product of the hydroformylation of olefinically unsaturated compounds using a rhodium catalyst by a process (cf. FIG. 2) in which(a) this gaseous product is introduced, without being cooled or depressured, into a distillation column D,(b) the top fraction from this column is cooled in a condenser K so that the greater part of the aldehydes contained therein is condensed,(c) the condensate is separated, in a separator A, into a gas phase and a liquid phase,(d) the gas phase from A, after waste gas has been separated off, is again brought to the hydroformylation pressure by means of a compressor P, and is returned to the reactor as a recycle gas,(e) the liquid phase from A is returned to D, and(f) the aldehydes are taken off from column D as liquid bottom products and/or as a vaporous side stream.

摘要翻译： 醛通过使用铑催化剂的方法（参见图2）从烯属不饱和化合物的加氢甲酰化的气态产物获得，其中（a）将该气态产物不经冷却或减压引入蒸馏塔D ，（b）将该塔的顶部馏分在冷凝器K中冷却，使其中含有的大部分醛缩合，（c）冷凝物在分离器A中分离成气相和液相 ，（d）在废气分离后，来自A的气相再次通过压缩机P进入加氢甲酰化反应器，并作为循环气体返回到反应器，（e）液相从 A返回到D，和（f）醛作为液体底部产物和/或作为蒸气侧流从塔D中取出。

公开(公告)号：US4134915A

公开(公告)日：1979-01-16

申请号：US793788

申请日：1977-05-05

申请人： Heinz Hohenschutz ,  Max Strohmeyer ,  Manfred Herr ,  Hans Kiefer

发明人： Heinz Hohenschutz ,  Max Strohmeyer ,  Manfred Herr ,  Hans Kiefer

IPC分类号： C07C231/02 ,  C07C20060101 ,  C07C67/00 ,  C07C231/00 ,  C07C233/03 ,  C07C102/06

CPC分类号： C07C231/02

摘要： Formamide is manufactured continuously from methyl formate and gaseous ammonia. The reaction is carried out in a reactor at from 30 to 90.degree. C, from 5 to 20% by volume of the reactor output is drawn off continuously and fed to the formamide working-up stage, and the remainder of the reactor output is cooled, in an external circuit maintained by means of a pump, to from 25 to 60.degree. C and is mixed with the amount of fresh methyl formate required for steady-state operation, after which the appropriate amount of gaseous ammonia is introduced into the stream of liquid through a jet, by the sucking-jet principle, and the stream of liquid is recycled to the reactor.

摘要翻译： 由甲酸甲酯和气态氨连续制备甲酰胺。 该反应在30-90℃的反应器中进行，5至20体积％的反应器输出连续排出，并送入甲酰胺处理阶段，反应器输出的其余部分被冷却 在通过泵保持的外部电路中，温度为25至60℃，并与稳态操作所需的新鲜甲酸甲酯的量混合，之后将适量的气态氨引入到 液体通过喷射原理通过射流，并且液体流被再循环到反应器中。

公开(公告)号：US5401873A

公开(公告)日：1995-03-28

申请号：US208823

申请日：1994-03-11

申请人： Peter Zehner ,  Klaus Bittins ,  Wilhelm Haarde ,  Ulrich Eiden ,  Dietrich Wolff ,  Manfred Herr ,  Leopold Hupfer

发明人： Peter Zehner ,  Klaus Bittins ,  Wilhelm Haarde ,  Ulrich Eiden ,  Dietrich Wolff ,  Manfred Herr ,  Leopold Hupfer

IPC分类号： B01J31/02 ,  C07B61/00 ,  C07C67/36 ,  C07C69/06

CPC分类号： C07C67/36

摘要： Preparation of methyl formate by the reaction of carbon monoxide and methanol under conditions of elevated pressure and temperature in the presence of an alkali metal methylate, in whichA) the starting materials are mixed in a mixing zone, are allowed to react partially, and the reaction solution is saturated with CO andB) the reaction is allowed to reach completion in one or more secondary reaction zones without the addition of further starting materials.

摘要翻译： 在甲醇酸碱金属（其中A）原料在混合区中混合的条件下，通过一氧化碳和甲醇在升高的压力和温度条件下反应制备甲酸甲酯，使其部分反应， 反应溶液用CO饱和，B）使反应在一个或多个次级反应区中达到完成，而不添加进一步的起始原料。