公开(公告)号：US20130066036A1

公开(公告)日：2013-03-14

申请号：US13699085

申请日：2011-06-10

申请人： Masakatsu Asami ,  Takuya Tochimoto

发明人： Masakatsu Asami ,  Takuya Tochimoto

IPC分类号： C08G8/04

CPC分类号： C08G8/10

摘要： A method of manufacture of novolac-type phenol resin, wherein phenols and aldehydes are allowed to react with each other, a water-soluble organic phosphonic acid is used as a reaction catalyst, and a tertiary phosphine compound is used as a reaction promoter. It is preferable that the aforementioned organic phosphonic acid have the structure shown in the following general formula (1): R—PO(OH)2   (1) (R is a group which contains a carbon atom, and which contains —COON and/or —PO(OH)2).

摘要翻译： 使酚醛类和酚类相互反应的酚醛清漆型酚醛树脂的制造方法，使用水溶性有机膦酸作为反应催化剂，使用叔膦化合物作为反应促进剂。 上述有机膦酸优选具有以下通式（1）所示的结构：R-PO（OH）2（1）（R是含有碳原子的基团，并且含有-COON和/ 或-PO（OH）2）。

公开(公告)号：US06326453B2

公开(公告)日：2001-12-04

申请号：US09734734

申请日：2000-12-13

申请人： Masakatsu Asami ,  Yoshikazu Kobayashi

发明人： Masakatsu Asami ,  Yoshikazu Kobayashi

IPC分类号： C08G1402

CPC分类号： C08G8/20 ,  C08G8/00 ,  C08G8/04 ,  C08G8/08 ,  C08G8/10

摘要： A novolak-type phenol resin with less unreacted phenol and a narrow molecular weight distribution is produced in high yield by reaction of a phenol with an aldehyde using an organophosphonic acid as a catalyst, while keeping a water concentration of reaction system at not more than 30% by weight and a reaction temperature at 110° C.-200° C.

摘要翻译： 通过使用有机膦酸作为催化剂，通过苯酚与醛的反应，以保持反应体系的水浓度不超过30的方式，以高收率制备具有较少未反应苯酚和分子量分布较小的酚醛清漆型酚醛树脂 重量％，反应温度在110℃-200℃

公开(公告)号：US08822627B2

公开(公告)日：2014-09-02

申请号：US13699085

申请日：2011-06-10

申请人： Masakatsu Asami ,  Takuya Tochimoto

发明人： Masakatsu Asami ,  Takuya Tochimoto

IPC分类号： C08G14/02 ,  C08G8/10

CPC分类号： C08G8/10

摘要： A method of manufacture of novolac-type phenol resin, wherein phenols and aldehydes are allowed to react with each other, a water-soluble organic phosphonic acid is used as a reaction catalyst, and a tertiary phosphine compound is used as a reaction promoter. It is preferable that the aforementioned organic phosphonic acid have the structure shown in the following general formula (1): R—PO(OH)2  (1) (R is a group which contains a carbon atom, and which contains —COON and/or —PO(OH)2).

摘要翻译： 使酚醛类和酚类相互反应的酚醛清漆型酚醛树脂的制造方法，使用水溶性有机膦酸作为反应催化剂，使用叔膦化合物作为反应促进剂。 上述有机膦酸优选具有以下通式（1）所示的结构：R-PO（OH）2（1）（R是含有碳原子的基团，并且含有-COON和/ 或-PO（OH）2）。