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    ANODE FOR A HIGH-TEMPERATURE FUEL CELL AND PRODUCTION THEREOF
    2.
    发明申请
    ANODE FOR A HIGH-TEMPERATURE FUEL CELL AND PRODUCTION THEREOF 有权
    高温燃料电池阳极及其生产

    公开(公告)号：US20120244456A1

    公开(公告)日：2012-09-27

    申请号：US13510057

    申请日：2010-11-04

    申请人： Robert Muecke ,  Norbert H. Menzler ,  Hans Peter Buchkremer ,  Matthias Ruettinger ,  Marco Brandner ,  Thomas Franco ,  Andreas Venskutonis

    发明人： Robert Muecke ,  Norbert H. Menzler ,  Hans Peter Buchkremer ,  Matthias Ruettinger ,  Marco Brandner ,  Thomas Franco ,  Andreas Venskutonis

    IPC分类号： H01M4/86 ,  H01M4/88 ,  H01M8/12

    CPC分类号： H01M4/8636 ,  H01M4/8652 ,  H01M4/8825 ,  H01M4/8885 ,  H01M4/9016 ,  H01M2008/1293 ,  Y02E60/50 ,  Y02E60/525

    摘要： The substrate-supported anode for a high-temperature fuel cell comprises an at least three-layer anode laminate on a metallic substrate. Each of the layers of the anode laminate comprises yttria-stabilized zirconia and nickel, wherein the mean particle size of the nickel decreases from one layer to the next as the distance from the substrate increases. The last layer of the anode laminate, which is provided for contact with the electrolyte, has a root mean square roughness of less than 4 μm. The overall mean pore size of this layer is typically between 0.3 and 1.5 μm. Starting powders having a bimodal particle size distribution of yttria-stabilized zirconia and nickel-containing powder are used at least for the first and second layers of the anode laminate. The mean particle size of the nickel-containing powder is reduced from one layer to the next, whereby it is advantageously no more than 0.5 μm in the last layer of the anode laminate.

    摘要翻译： 用于高温燃料电池的衬底支撑的阳极包括在金属衬底上的至少三层阳极层叠体。 阳极层压板的每个层包括氧化钇稳定的氧化锆和镍，其中随着离开衬底的距离增加，镍的平均粒度从一层下降到下一层。 提供用于与电解质接触的阳极层压板的最后层具有小于4μm的均方根粗糙度。 该层的总平均孔径通常为0.3-1.5μm。 至少对阳极层叠体的第一层和第二层使用具有氧化钇稳定的氧化锆和含镍粉末的双峰粒度分布的起始粉末。 含镍粉末的平均粒径从一层减少到下一层，由此在阳极层压板的最后一层中有利地不超过0.5μm。

    Anode for a high-temperature fuel cell and production thereof
    3.
    发明授权
    Anode for a high-temperature fuel cell and production thereof 有权
    高温燃料电池用阳极及其制造方法

    公开(公告)号：US09048498B2

    公开(公告)日：2015-06-02

    申请号：US13510057

    申请日：2010-11-04

    申请人： Robert Muecke ,  Norbert H. Menzler ,  Hans Peter Buchkremer ,  Matthias Ruettinger ,  Marco Brandner ,  Thomas Franco ,  Andreas Venskutonis

    发明人： Robert Muecke ,  Norbert H. Menzler ,  Hans Peter Buchkremer ,  Matthias Ruettinger ,  Marco Brandner ,  Thomas Franco ,  Andreas Venskutonis

    IPC分类号： H01M4/90 ,  H01M4/04 ,  H01M4/86 ,  H01M4/88 ,  H01M8/12

    CPC分类号： H01M4/8636 ,  H01M4/8652 ,  H01M4/8825 ,  H01M4/8885 ,  H01M4/9016 ,  H01M2008/1293 ,  Y02E60/50 ,  Y02E60/525

    摘要： The substrate-supported anode for a high-temperature fuel cell comprises an at least three-layer anode laminate on a metallic substrate. Each of the layers of the anode laminate comprises yttria-stabilized zirconia and nickel, wherein the mean particle size of the nickel decreases from one layer to the next as the distance from the substrate increases. The last layer of the anode laminate, which is provided for contact with the electrolyte, has a root mean square roughness of less than 4 μm. The overall mean pore size of this layer is typically between 0.3 and 1.5 μm. Starting powders having a bimodal particle size distribution of yttria-stabilized zirconia and nickel-containing powder are used at least for the first and second layers of the anode laminate. The mean particle size of the nickel-containing powder is reduced from one layer to the next, whereby it is advantageously no more than 0.5 μm in the last layer of the anode laminate.

    摘要翻译： 用于高温燃料电池的衬底支撑的阳极包括在金属衬底上的至少三层阳极层叠体。 阳极层压板的每个层包括氧化钇稳定的氧化锆和镍，其中随着离开衬底的距离增加，镍的平均粒度从一层下降到下一层。 提供用于与电解质接触的阳极层压板的最后层具有小于4μm的均方根粗糙度。 该层的总平均孔径通常为0.3-1.5μm。 至少对阳极层叠体的第一层和第二层使用具有氧化钇稳定的氧化锆和含镍粉末的双峰粒度分布的起始粉末。 含镍粉末的平均粒径从一层减少到下一层，由此在阳极层压板的最后一层中有利地不超过0.5μm。