公开(公告)号：US09249259B2

公开(公告)日：2016-02-02

申请号：US14232015

申请日：2012-07-17

Applicant: Thomas Ernst Müller ,  Christoph Gürtler ,  Matthias Wohak ,  Jörg Hofmann ,  Muhammad Afzal Subhani ,  Maurice Cosemans ,  Walter Leitner

Inventor： Thomas Ernst Müller ,  Christoph Gürtler ,  Matthias Wohak ,  Jörg Hofmann ,  Muhammad Afzal Subhani ,  Maurice Cosemans ,  Walter Leitner

IPC: C08G64/32 ,  C08G64/34 ,  C08G65/26 ,  C08G64/00 ,  C07C68/04

CPC classification number: C08G64/323 ,  C08G64/34 ,  C08G65/2603 ,  C08G65/2663

Abstract: The present invention relates to a process for the activation of double metal cyanide (DMC) catalysts and to a process for the preparation of polyethercarbonate polyols from one or more H-functional starter compounds, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, characterized in that (α) (α1) the DMC catalyst and one or more H-functional starter compounds are placed in a reactor, (α2) an inert gas, an inert gas/carbon dioxide mixture or carbon dioxide is passed through the reactor at a temperature of 50 to 200° C. and at the same time a reduced pressure (absolute) of 10 mbar to 800 mbar is established in the reactor by removal of the inert gas or carbon dioxide, (β) under an atmosphere of inert gas/carbon dioxide mixture or under a pure carbon dioxide atmosphere, alkylene oxide is added to the mixture from step (α) at temperatures of 50 to 200° C., and (γ) one or more alkylene oxides and carbon dioxide are metered into the mixture resulting from step (β).

Abstract translation: 本发明涉及一种活化双金属氰化物（DMC）催化剂的方法，以及一种由一种或多种H官能起始化合物，一种或多种环氧烷和二氧化碳在存在下制备聚醚碳酸酯多元醇的方法 一种双金属氰化物催化剂，其特征在于将（α）（α1）DMC催化剂和一种或多种H官能起始化合物置于反应器中，（α2）惰性气体，惰性气体/二氧化碳混合物或二氧化碳 在50至200℃的温度下通过反应器，同时通过除去惰性气体或二氧化碳，在反应器中建立10毫巴至800毫巴的减压（绝对）（绝对）。 ）在惰性气体/二氧化碳混合物的气氛下或在纯二氧化碳气氛下，在步骤（α）的混合物中，在50〜200℃的温度下加入环氧烷，（γ）一种或多种环氧烷烃 并将二氧化碳计量加入 由（步骤（bgr））产生的混合物。

公开(公告)号：US20140155559A1

公开(公告)日：2014-06-05

申请号：US14131977

申请日：2012-07-17

Applicant: Thomas Ernst Müller ,  Christoph Gürtler ,  Matthias Wohak ,  Jörg Hofmann ,  Muhammad Afzal Subhani ,  Maurice Cosemans ,  Walter Leitner

Inventor： Thomas Ernst Müller ,  Christoph Gürtler ,  Matthias Wohak ,  Jörg Hofmann ,  Muhammad Afzal Subhani ,  Maurice Cosemans ,  Walter Leitner

IPC: C08G65/26

CPC classification number: C08G65/2663 ,  C08G64/34 ,  C08G65/2603

Abstract: The present invention relates to a process for the preparation of polyether carbonate polyols from one or more H-functional starter compounds, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, wherein (α) the H-functional starter substance or a mixture of at least two H-functional starter substances is initially introduced into the reaction vessel, (β) for the activation, a part amount (based on the total amount of the amount of alkylene oxides employed in steps (β) and (γ)) of one or more alkylene oxides is added to the mixture resulting from step (α), it also being possible for step (β) to be carried out several times for the activation, (γ) one or more alkylene oxides and carbon dioxide are metered continuously into the mixture resulting from step (β) (“copolymerization”), the alkylene oxides employed for the copolymerization being identical to or different from the alkylene oxides employed in step (β), characterized in that in step (γ) the carbon dioxide is passed into the mixture by (i) gassing the reaction mixture in the reactor from the bottom, (ii) using a hollow shaft stirrer, (iii) a combination of the metering operations according to (i) and (ii), and/or (iv) gassing over the surface of the liquid by using stirrer units configured in several stages.

Abstract translation: 本发明涉及在双金属氰化物催化剂存在下由一种或多种H官能起始化合物，一种或多种环氧烷和二氧化碳制备聚醚碳酸酯多元醇的方法，其中（α）H官能团 起始物质或至少两种H功能性起始物质的混合物最初被引入反应容器（（bgr））中用于活化，部分量（基于步骤（bgr）中使用的环氧烷烃的总量 （γ））和（γ））加入到由步骤（α）得到的混合物中，对于活化，（γ）一个或多个步骤（＆bgr）可以进行几次， 更多的环氧烷和二氧化碳被连续地计量到由步骤（（bgr））（“共聚”）得到的混合物中，用于共聚的烯化氧与步骤（bgr）中使用的环氧烷烃相同或不同， 其特征在于在步骤（γ）中，二氧化碳通过以下步骤进入混合物：（i）从底部将反应混合物放入反应器中，（ii）使用中空轴搅拌器，（iii）根据 至（i）和（ii），和/或（iv）通过使用在几个阶段中配置的搅拌器单元在液体的表面上放气。

公开(公告)号：US09120894B2

公开(公告)日：2015-09-01

申请号：US14131977

申请日：2012-07-17

Applicant: Thomas Ernst Müller ,  Christoph Gürtler ,  Matthias Wohak ,  Jörg Hofmann ,  Muhammad Afzal Subhani ,  Maurice Cosemans ,  Walter Leitner

Inventor： Thomas Ernst Müller ,  Christoph Gürtler ,  Matthias Wohak ,  Jörg Hofmann ,  Muhammad Afzal Subhani ,  Maurice Cosemans ,  Walter Leitner

IPC: C08G85/00 ,  C08G65/00 ,  C08G65/26 ,  C08G64/34

CPC classification number: C08G65/2663 ,  C08G64/34 ,  C08G65/2603

Abstract: The present invention relates to a process for the preparation of polyether carbonate polyols from one or more H-functional starter compounds, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, wherein (α) the H-functional starter substance or a mixture of at least two H-functional starter substances is initially introduced into the reaction vessel, (β) for the activation, a part amount (based on the total amount of the amount of alkylene oxides employed in steps (β) and (γ)) of one or more alkylene oxides is added to the mixture resulting from step (α), it also being possible for step (β) to be carried out several times for the activation, (γ) one or more alkylene oxides and carbon dioxide are metered continuously into the mixture resulting from step (β) (“copolymerization”), the alkylene oxides employed for the copolymerization being identical to or different from the alkylene oxides employed in step (β), characterized in that in step (γ) the carbon dioxide is passed into the mixture by (i) gassing the reaction mixture in the reactor from the bottom, (ii) using a hollow shaft stirrer, (iii) a combination of the metering operations according to (i) and (ii), and/or (iv) gassing over the surface of the liquid by using stirrer units configured in several stages.

Abstract translation: 本发明涉及在双金属氰化物催化剂存在下由一种或多种H官能起始化合物，一种或多种环氧烷和二氧化碳制备聚醚碳酸酯多元醇的方法，其中（α）H官能团 起始物质或至少两种H功能性起始物质的混合物最初被引入反应容器（（bgr））中用于活化，部分量（基于步骤（bgr）中使用的环氧烷烃的总量 （γ））和（γ））加入到由步骤（α）得到的混合物中，对于活化，（γ）一个或多个步骤（＆bgr）可以进行几次， 更多的环氧烷和二氧化碳被连续地计量到由步骤（（bgr））（“共聚”）得到的混合物中，用于共聚的烯化氧与步骤（bgr）中使用的环氧烷烃相同或不同， 其特征在于在步骤（γ）中，二氧化碳通过以下步骤进入混合物：（i）从底部将反应混合物放入反应器中，（ii）使用中空轴搅拌器，（iii）根据 至（i）和（ii），和/或（iv）通过使用在几个阶段中配置的搅拌器单元在液体的表面上放气。

公开(公告)号：US20140228537A1

公开(公告)日：2014-08-14

申请号：US14232015

申请日：2012-07-17

Applicant: Thomas Ernst Müller ,  Christoph Gürtler ,  Matthias Wohak ,  Jörg Hofmann ,  Muhammad Afzal Subhani ,  Maurice Cosemans ,  Walter Leitner

Inventor： Thomas Ernst Müller ,  Christoph Gürtler ,  Matthias Wohak ,  Jörg Hofmann ,  Muhammad Afzal Subhani ,  Maurice Cosemans ,  Walter Leitner

IPC: C08G64/32

CPC classification number: C08G64/323 ,  C08G64/34 ,  C08G65/2603 ,  C08G65/2663

Abstract: The present invention relates to a process for the activation of double metal cyanide (DMC) catalysts and to a process for the preparation of polyethercarbonate polyols from one or more H-functional starter compounds, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, characterized in that (α) (α1) the DMC catalyst and one or more H-functional starter compounds are placed in a reactor, (α2) an inert gas, an inert gas/carbon dioxide mixture or carbon dioxide is passed through the reactor at a temperature of 50 to 200° C. and at the same time a reduced pressure (absolute) of 10 mbar to 800 mbar is established in the reactor by removal of the inert gas or carbon dioxide, (β) under an atmosphere of inert gas/carbon dioxide mixture or under a pure carbon dioxide atmosphere, alkylene oxide is added to the mixture from step (α) at temperatures of 50 to 200° C., and (γ) one or more alkylene oxides and carbon dioxide are metered into the mixture resulting from step (β).

Abstract translation: 本发明涉及一种活化双金属氰化物（DMC）催化剂的方法，以及一种由一种或多种H官能起始化合物，一种或多种环氧烷和二氧化碳在存在下制备聚醚碳酸酯多元醇的方法 一种双金属氰化物催化剂，其特征在于将（α）（α1）DMC催化剂和一种或多种H官能起始化合物置于反应器中，（α2）惰性气体，惰性气体/二氧化碳混合物或二氧化碳 在50至200℃的温度下通过反应器，同时通过除去惰性气体或二氧化碳，在反应器中建立10毫巴至800毫巴的减压（绝对）（绝对）。 ）在惰性气体/二氧化碳混合物的气氛下或在纯二氧化碳气氛下，在步骤（α）的混合物中，在50〜200℃的温度下加入环氧烷，（γ）一种或多种环氧烷烃 并将二氧化碳计量加入 由（步骤（bgr））产生的混合物。