公开(公告)号：US07132383B2

公开(公告)日：2006-11-07

申请号：US10363648

申请日：2001-09-10

申请人： Takahiro Nakajima ,  Kenichi Tsukamoto ,  Shoichi Gyobu ,  Fumikazu Yoshida ,  Maki Sato ,  Naoki Watanabe ,  Katsuhiko Kageyama ,  Mitsuyoshi Kuwata ,  Nobuo Moriyama ,  Haruo Matsumoto ,  Yoshitomo Ikehata ,  Yoshinao Matsui ,  Masaou Matsuda ,  Munekazu Okuhara ,  Hiroki Fukuda

发明人： Takahiro Nakajima ,  Kenichi Tsukamoto ,  Shoichi Gyobu ,  Fumikazu Yoshida ,  Maki Sato ,  Naoki Watanabe ,  Katsuhiko Kageyama ,  Mitsuyoshi Kuwata ,  Nobuo Moriyama ,  Haruo Matsumoto ,  Yoshitomo Ikehata ,  Yoshinao Matsui ,  Masaou Matsuda ,  Munekazu Okuhara ,  Hiroki Fukuda

IPC分类号： B01J31/00

CPC分类号： D01F6/62 ,  C08G63/82 ,  C08G63/83 ,  C08G63/84 ,  C08G63/87

摘要： A polymerization catalyst for polyester production which contains neither a germanium compound nor an antimony compound as a major component. It contains aluminum as the main metallic ingredient, has excellent catalytic activity, and gives a polyester which is effectively inhibited from suffering thermal degradation, during melt molding, without deactivating or removing the catalyst, and is excellent in thermal stability, stability to thermal oxidation, and hydrolytic resistance. The polymerization catalyst contains as a first metallic ingredient at least one member selected among aluminum and compounds thereof and further contains a phosphorus compound represented by a specific chemical formula. The polyester produced with this catalyst is usable as fibers, films, sheets, various moldings including hollow moldings, etc.

摘要翻译： 用于聚酯生产的聚合催化剂，既不含锗化合物也不含锑化合物作为主要成分。 它含有铝作为主要的金属成分，具有优异的催化活性，并且在熔融成型期间得到有效抑制热降解的聚酯，而不会使催化剂失活或除去，并且热稳定性，热氧化稳定性优异， 和耐水解性。 聚合催化剂含有选自铝及其化合物中的至少一种元素作为第一金属成分，并且还含有由特定化学式表示的磷化合物。 使用该催化剂制造的聚酯可用作纤维，薄膜，片材，各种模制品，包括中空模制品等。