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公开(公告)号:US6127306A
公开(公告)日:2000-10-03
申请号:US43054
申请日:1998-07-06
申请人: Nicola Husing , Ulrich Schubert
发明人: Nicola Husing , Ulrich Schubert
IPC分类号: B01J21/08 , B01J31/02 , B01J31/16 , B01J31/20 , B01J31/24 , B01J37/03 , C01B33/158 , C09K5/06 , B01J31/00 , C01B33/12
CPC分类号: C09K5/063 , B01J21/08 , B01J31/1633 , B01J31/20 , B01J31/2404 , B01J37/033 , C01B33/1585 , B01J2531/822
摘要: The invention relates to aerogels containing functional residues of the formula (I)--Y--Z, wherein Y is a straight-chained or branched alkylene group with 1 to 22 carbon atoms; Z is halogen, pseudohalogen, SR.sup.1, PR.sup.2 R.sup.3, colorant residue or metal complex residue; R.sup.1 is H, a straight-chained or branched alkyl group with 1 to 22 carbon atoms or an aryl group with 4 to 10 carbon atoms; and R.sup.2 and R.sup.3 are identical or different, a straight-chained or branched alkyl group with 1 to 22 carbon atoms, or an aryl group with 4 to 10 carbon atoms. The aerogels are suitable, for example, as catalyst stayes and/or sensors. They can be obtained by metal alcoholates and metal alcoholates in which at least one alcoholate residue is replaced by the --Y--Z group being converted into a lyogel by hydrolysis and condensation, and subsequently being dried.
摘要翻译: PCT No.PCT / EP96 / 03999 Sec。 371日期:1998年7月6日 102(e)1998年7月6日PCT PCT 1996年9月12日PCT公布。 公开号WO97 / 10178 日期:1997年3月20日本发明涉及含有式(I)-Y-Z的功能性残基的气凝胶,其中Y是具有1至22个碳原子的直链或支链亚烷基; Z是卤素,假卤素,SR1,PR2R3,着色剂残基或金属络合物残基; R1是H,具有1至22个碳原子的直链或支链烷基或具有4至10个碳原子的芳基; R2和R3相同或不同,具有1至22个碳原子的直链或支链烷基或具有4至10个碳原子的芳基。 气凝胶例如作为催化剂残留物和/或传感器是合适的。 它们可以通过金属醇化物和金属醇化物获得,其中至少一个醇化物残基被-Y-Z基团替代,通过水解和缩合转化成lyogel,随后被干燥。