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1.发明授权Catalytic systems made of a complex of rare earths for stereospecific polymerisation of conjugated dienes 有权由稀土复合物制成的催化体系用于共轭二烯的立体有择聚合公开(公告)号：US08946368B2
公开(公告)日：2015-02-03
申请号：US13318022
申请日：2010-04-27
摘要： The present invention relates to a multi-component catalytic system that can be used for the cis-1,4 stereospecific polymerization of conjugated dienes. The system is based on: (i) a rare-earth complex of Formula (II) Ln(A)3(B)n, Ln being a rare-earth metal, A a ligand, B a Lewis base or a solvent molecule and n a number from 0 to 3; (ii) an alkylating agent; (iii) a compound based on an aromatic ring and having at least two heteroatoms chosen from the elements O, N, S, P, and corresponding to the Formula (III): in which the R groups each denote hydrogen, an alkyl radical optionally comprising one or more heteroatoms (N, O, P, S, Si) or one or more halogen atoms, a halogen atom, a group based on one or more heteroatoms (N, O, P, S, Si); x and y are integers from 0 to 6; D is a group having a chemical function, one of the atoms of which has a non-bonding pair; L being an atom from column 1 of the Periodic Table.
摘要翻译： 本发明涉及可用于共轭二烯的顺式-1,4-立体有择聚合的多组分催化体系。 该系统基于：（i）式（II）Ln（A）3（B）n的稀土络合物，Ln是稀土金属，A a配体，B路易斯碱或溶剂分子，以及 na数从0到3; （ii）烷基化剂; （iii）基于芳环并且具有至少两个选自元素O，N，S，P的杂原子并且对应于式（III）的化合物：其中R基团各自表示氢，任选的烷基 包括一个或多个杂原子（N，O，P，S，Si）或一个或多个卤素原子，卤素原子，基于一个或多个杂原子（N，O，P，S，Si）的基团。 x和y是0〜6的整数; D是具有化学功能的基团，其原子之一具有非键合对; L是周期表第1列的原子。
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2.发明申请Catalytic Systems Made of a Complex of Rare Earths For Stereospecific Polymerisation Of Conjugated Dienes 有权由稀土复合物制成的催化体系用于共轭二烯的立体特异性聚合公开(公告)号：US20120123070A1
公开(公告)日：2012-05-17
申请号：US13318022
申请日：2010-04-27
IPC分类号： C08F4/00 , C08F136/06 , C08F136/08 , C08F4/52
摘要： La present invention relates to a multi-component catalytic system that can be used for the cis-1,4 stereospecific polymerization of conjugated dienes. The system is based on:(i) a rare-earth complex of Formula (II) Ln(A)3(B)n, Ln being a rare-earth metal, A a ligand, B a Lewis base or a solvent molecule and n a number from 0 to 3;(ii) an alkylating agent;(iii) a compound based on an aromatic ring and having at least two heteroatoms chosen from the elements O, N, S, P, and corresponding to the Formula (III): in which the R groups each denote hydrogen, an alkyl radical optionally comprising one or more heteroatoms (N, O, P, S, Si) or one or more halogen atoms, a halogen atom, a group based on one or more heteroatoms (N, O, P, S, Si); x and y are integers from 0 to 6; D is a group having a chemical function, one of the atoms of which has a non-bonding pair; L being an atom from column 1 of the Periodic Table.
摘要翻译： 本发明涉及可用于共轭二烯的顺式-1,4-立体有择聚合的多组分催化体系。 该系统基于：（i）式（II）Ln（A）3（B）n的稀土络合物，Ln是稀土金属，A a配体，B路易斯碱或溶剂分子，以及 na数从0到3; （ii）烷基化剂; （iii）基于芳环并且具有至少两个选自元素O，N，S，P的杂原子并且对应于式（III）的化合物：其中R基团各自表示氢，任选的烷基 包括一个或多个杂原子（N，O，P，S，Si）或一个或多个卤素原子，卤素原子，基于一个或多个杂原子（N，O，P，S，Si）的基团。 x和y是0〜6的整数; D是具有化学功能的基团，其原子之一具有非键合对; L是周期表第1列的原子。
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