公开(公告)号：US4158003A

公开(公告)日：1979-06-12

申请号：US741017

申请日：1976-11-11

申请人： Otto Bitterlin ,  Paul Dussy

发明人： Otto Bitterlin ,  Paul Dussy

IPC分类号： C09B50/06 ,  C09B45/48

CPC分类号： C09B50/06

摘要： Heavy-metal-containing bisformazan dyestuffs of the formula ##STR1## WHEREIN A.sub.1, A.sub.2, B.sub.1 and B.sub.2 are the same or different and each represents an unsubstituted or substituted o-phenylene radical or an o-naphthylene radical,R.sub.1 and R.sub.2 are the same or different and each represent a monovalent organic radical,Me.sub.1 and Me.sub.2 each represent nickel or copper,X.sub.1 and X.sub.2 are the same or different and each represents a metal-binding substituent connected to A.sub.1, B.sub.1, A.sub.2 or B.sub.2 in a position ortho to that to which the nitrogen is linked,Y represents the radical of a dibasic carboxylic acid or a radical which is derived from an, at least, bifunctional heterocyclic compound,Z represents a salt-forming water-solubilizing group, dissociating acid in water, selected from --SO.sub.3.sup..crclbar. M.sym. and --COO.sup..crclbar. M.sup..sym.wherein M.sup..sym. represents a cation,N represents a number from 2 to 6, andWherein aromatic radicals present may contain further substituents known per se for use in azo dyestuffs, and wherein the grouping --NH--Y--HN-- is bound directly or via a bridging member to a ring carbon atom of A.sub.1, A.sub.2, B.sub.1, B.sub.2, R.sub.1 or R.sub.2 ,which bis-formazans are substantive dyestuffs suitable for the dyeing or printing of textile material made from natural or regenerated cellulose. The aforesaid bis-formazan dyestuffs are distinguished by high coloring strength and substantivity to cellulose textile material. The dyeings obtained therewith are of a pure shade of color and have good fastness properties, especially to light and wet.

摘要翻译： 具有下式的重金属的双甲缩醛染料，其中A1，A2，B1和B2相同或不同，并且各自表示未取代或取代的邻亚苯基或邻亚萘基， R1和R2相同或不同，各自表示一价有机基团，Me1和Me2各自表示镍或铜，X1和X2相同或不同，表示与A1，B1，A2或B2连接的金属结合取代基 在与氮连接的位置的邻位，Y表示二元羧酸或至少由双官能的杂环化合物衍生的基团的基团，Z表示形成盐的水溶性基团，离解的 其中M（+）表示阳离子，N代表从2到6的数目，以及存在于本文中的AROMATIC RADICALS可能含有的 在AZO DYESTUFFS和本集团所使用的更多替代品 ING -NH-Y-HN-直接键合或通过桥连构件结合到A1，A2，B1，B2，R1或R2的环碳原子上，双甲烷是适合纺织材料的染色或印花的实质性染料 由天然或再生纤维素制成。 上述双甲an染料的特征在于高着色强度和对纤维素纺织材料的亲和性。 由此获得的染色具有纯色的色泽，并且具有良好的牢度性能，特别是对于光和湿。

公开(公告)号：US4116624A

公开(公告)日：1978-09-26

申请号：US737932

申请日：1976-11-01

申请人： Otto Bitterlin ,  Fabio Beffa

发明人： Otto Bitterlin ,  Fabio Beffa

IPC分类号： C09B45/24 ,  C09B45/00 ,  D06P1/10

CPC分类号： C09B45/24

摘要： The present invention provides heavy metal complexes of azo dyes of the formula ##STR1## wherein each of A and A' represents a coupling component of the phenylenediamine, naphthol, naphthylamine, pyrazolone, aminopyrazole, acylacetamide, pyridone, 2,4,6-triaminopyridine or barbituric acid series, which is bound in ortho-position to a hydroxy, amino or enolisable keto group to the azo group, while A and A' carry at least one sulpho group and contain no other ionogenic substituents.

摘要翻译： 本发明提供式（I）的偶氮染料的重金属络合物，其中A和A'各自表示苯二胺，萘酚，萘胺，吡唑啉酮，氨基吡唑，酰基乙酰胺，吡啶酮，2,4 ，6-三氨基吡啶或巴比妥酸系列，其与邻位羟基，氨基或可烯化的酮基键合至偶氮基，而A和A'携带至少一个磺基并且不含其它离子型取代基。