摘要:
Provided is a process for making 2-chloro-1,1,1,2-tetrafluoropropane. The process has the step of hydrofluorinating 2-chloro-3,3,3-trifluoropropene in the presence of a catalyst selected from the group consisting of SbCl3, SbCl5, SbF5, TiCl4, SnCl4, Cr2O3, and fluorinated Cr2O3.
摘要翻译:提供了制备2-氯-1,1,1,2-四氟丙烷的方法。 该方法具有在选自SbCl 3,SbCl 5,SbF 5,TiCl 4,SnCl 4,Cr 2 O 3和氟化Cr 2 O 3的催化剂存在下氢化2-氯-3,3,3-三氟丙烯的步骤。
摘要:
A process for making 2-chloro-1,1,1,2-tetrafluoropropane. The process has the step of contacting 2-chloro-3,3,3-trifluoropropene with hydrogen fluoride in the presence of a catalyst having about 25 to about 99.9 mole percent antimony pentachloride and about 0.1 to about 75 mole percent of a metal of a Lewis acid under conditions sufficient to form the 2-chloro-1,1,1,2-tetrafluoropropane. There is a second process for making 2-chloro-1,1,1,2-tetrafluoropropane. The process has the step of hydrofluorinating about 75 to about 99.9 mole percent 2-chloro-3,3,3-trifluoropropene and about 0.1 to about 25 mole percent of one or more other hydrocarbons having at least one chlorine atom in the presence of a catalyst of fluorinated antimony pentachloride under conditions sufficient to form the 2-chloro-1,1,1,2-tetrafluoropropane. There is yet another process for hydrofluorinating 2-chloro-3,3,3-trifluoropropene to 2-chloro-1,1,1,2-tetrafluoropropane. The process has the step of contacting the 2-chloro-3,3,3-trifluoropropene with hydrogen fluoride in the presence of a vapor phase catalyst under conditions sufficient to form the 2-chloro-1,1,1,2-tetrafluoropropane.
摘要:
Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF═CH2 (1234yf). In certain preferred embodiments the processes comprise first exposing a compound of Formula (IA) C(X)2═CClC(X)3 (IA) where each X is independently F, Cl or H, preferably CCl2═CClCH2Cl, to one or more sets of reaction conditions, but preferably a substantially single set of reaction conditions, effective to produce at least one chlorofluoropropane, preferably in accordance with Formula (IB): CF3CClX′C(X′)3 Formula (IB) where each X′ is independently F, Cl or H, and then exposing the compound of Formula (IB) to one or more sets of reaction conditions, but preferably a substantially single set of reaction conditions, effective to produce a compound of Formula (II) CF3CF═CHZ (II) where Z is H, F, Cl, I or Br.
摘要:
A click pen applicator device that provides predetermined dosing of the formulation for precise application, and rapidly primes the formulation using the dosing click mechanism to prepare the applicator for use.
摘要:
A data object management scheme for storing a large plurality of small data objects (e.g., image files) in small number of large object stack file for storage in secondary storage (e.g., hard disks). By storing many individual data objects in a single object stack file, the number of files stored in the secondary storage is reduced by several orders of magnitude, from the billions or millions to the hundreds or so. Index data for each object stack file is generated and stored in primary storage to allow efficient and prompt access to the data objects. Requests to store or retrieve the data objects are made using HTTP messages including file identifiers that identify the files storing the data objects and keys identifying the data objects. A file server stores or retrieves the data object from secondary storage of a file server without converting the requests to NSF or POSIX commands.
摘要:
A cryosurgery device includes an aerosol container holding a liquid refrigerant and having a valve and a stem extending out therefrom; an actuator seated on the stem and including an outlet tube for receiving released refrigerant from the container; a hub mounted on the container and including slots therein; and a base having a central opening for receiving the hub, the base including aligning projections that enter the slots in the hub to engage and apply pressure to the actuator to cause the actuator to depress the stem and release refrigerant into the base. The container may further contain an applicator tube mounted to the hub in fluid communication with the outlet tube with a porous tip mounted to a distal end of the applicator tube for receiving the refrigerant and, being chilled thereby, applied to a skin lesion to be treated.
摘要:
A transducer assembly (100) for connecting a transducer (102) to a device, the transducer assembly comprising: a transducer mount (110) adapted to receive the transducer; and a clamp (120) comprising first and second jaws (122, 124), the first and second jaws being adapted to selectively clamp to a flange portion (106) of the device. The transducer mount (110) may comprise a housing (112), a resilient member (114) and first and second end walls (115, 116). The first end wall may be operatively connected to the device. The transducer (102) may be held within the housing and adjacent to the first end wall. The resilient member being disposed between the transducer and the second end wall.
摘要:
Disclosed is a method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa-m (I) to at least one compound of formula (II) CF3CZCHZ (II). where each X is independently Cl, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, m is 1 or 2; a is 2 or 3, and a-m≧0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a C1 addition agent under conditions effective to produce a compound of formula (I).
摘要翻译:公开了一种制备氟化有机化合物的方法,包括氢氟丙烯,其优选包括将至少一种式(I)化合物:CF 3 CF n CH m X a-m(I)转化为至少一种式(II)CF 3 CZCHZ(II)化合物。 其中每个X独立地为Cl,I或Br; 每个Z独立地为H或F; n为1或2; m为1,2或3,条件是当n为1时,m为1或2; a为2或3,a-m≥0。 某些实施方案包括在有效产生式(I)化合物的条件下使氟化C 2烯烃如四氟乙烯与C1加成剂反应的步骤。