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1.发明申请公开(公告)号：US20100270207A1
公开(公告)日：2010-10-28
申请号：US12768327
申请日：2010-04-27
申请人： Jefferson Roberto Gomes , José Luiz Zotin , Marcelo Edral Pacheco , Raissa Maria Cotta Ferreira Da Silva
发明人： Jefferson Roberto Gomes , José Luiz Zotin , Marcelo Edral Pacheco , Raissa Maria Cotta Ferreira Da Silva
IPC分类号： C10G65/02
CPC分类号： C10G3/44 , B01J23/28 , B01J23/883 , B01J35/0006 , C10G3/46 , C10G3/50 , C10G3/54 , C10G45/04 , C10G45/08 , C10G65/04 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/4006 , C10G2300/4012 , Y02P30/20
摘要： A co-processing combining a first selective catalytic bed consisting of only one metal element selected from group VIB metals and of at least one conventional hydrotreating bimetallic catalytic bed. The co-processing provides control of the hydroconversion reactions of the triglycerides and/or fatty acids of biomass oil diluted in a refinery stream of petroleum hydrocarbons and minimizes the generation of gaseous products that are undesirable to the process, while maintaining the levels of unsaturated hydrocarbons hydrogenation and of heteroatomic contaminants removal from the refinery stream of petroleum hydrocarbons. The co-processing selectively providing n-paraffins of even number of carbon atoms, generated from the biomass oil, which are incorporated in a hydrotreated liquid product in petroleum refining HDT units.
摘要翻译： 组合由仅由选自VIB族金属和至少一种常规加氢精制双金属催化床的一种金属元素组成的第一选择性催化床的共加工。 协同处理可以控制稀释在石油烃精炼物流中的生物质油的甘油三酸酯和/或脂肪酸的加氢转化反应，并最大限度地减少不利于该方法产生的气态产物，同时保持不饱和烃的含量 氢化和从炼油厂石油烃中除去的杂原子污染物。 共处理选择性地提供由生物质油产生的偶数个碳原子的正链烷烃，其被并入石油精炼HDT单元中的加氢处理液体产物中。
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2.发明授权Process for hydrotreating biomass oil diluted in a refinery stream of petroleum hydrocarbons 有权在石油烃炼油厂稀释的生物质油加氢处理方法公开(公告)号：US08507738B2
公开(公告)日：2013-08-13
申请号：US12768327
申请日：2010-04-27
申请人： Jefferson Roberto Gomes , José Luiz Zotin , Marcelo Edral Pacheco , Raissa Maria Cotta Ferreira Da Silva
发明人： Jefferson Roberto Gomes , José Luiz Zotin , Marcelo Edral Pacheco , Raissa Maria Cotta Ferreira Da Silva
CPC分类号： C10G3/44 , B01J23/28 , B01J23/883 , B01J35/0006 , C10G3/46 , C10G3/50 , C10G3/54 , C10G45/04 , C10G45/08 , C10G65/04 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/4006 , C10G2300/4012 , Y02P30/20
摘要： A co-processing combining a first selective catalytic bed consisting of only one metal element selected from group VIB metals and of at least one conventional hydrotreating bimetallic catalytic bed. The co-processing provides control of the hydroconversion reactions of the triglycerides and/or fatty acids of biomass oil diluted in a refinery stream of petroleum hydrocarbons and minimizes the generation of gaseous products that are undesirable to the process, while maintaining the levels of unsaturated hydrocarbons hydrogenation and of heteroatomic contaminants removal from the refinery stream of petroleum hydrocarbons. The co-processing selectively providing n-paraffins of even number of carbon atoms, generated from the biomass oil, which are incorporated in a hydrotreated liquid product in petroleum refining HDT units.
摘要翻译： 组合由仅由选自VIB族金属和至少一种常规加氢精制双金属催化床的一种金属元素组成的第一选择性催化床的共加工。 协同处理可以控制稀释在石油烃精炼物流中的生物质油的甘油三酸酯和/或脂肪酸的加氢转化反应，并最大限度地减少不利于该方法产生的气态产物，同时保持不饱和烃的含量 氢化和从炼油厂石油烃中除去的杂原子污染物。 共处理选择性地提供由生物质油产生的偶数个碳原子的正链烷烃，其被并入石油精炼HDT单元中的加氢处理液体产物中。
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3.发明申请公开(公告)号：US20090301932A1
公开(公告)日：2009-12-10
申请号：US12298071
申请日：2007-04-26
申请人： Jefferson Roberto Gomes , Raissa Maria Cotta Ferreira da Silva , Rogerio Oddone , Adriana De Souza Ferreira , Nelmo Furtado Fernandes
发明人： Jefferson Roberto Gomes , Raissa Maria Cotta Ferreira da Silva , Rogerio Oddone , Adriana De Souza Ferreira , Nelmo Furtado Fernandes
IPC分类号： C10G69/02
CPC分类号： C10G3/46 , C10G3/50 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/307 , C10G2300/308 , C10G2300/4018 , C10G2400/04 , Y02P30/20
摘要： A process is described for hydroconversion of a mixture of organic oils of different origins in a conventional hydrotreatment unit, constituted by at least two catalyst beds, under moderately severe process conditions to obtain diesel fuel oil. The process includes injection of a stream of oil of animal or plant origin, with independently adjusted flow rates, from the second catalyst bed of the hydrotreatment unit onwards, in accordance with the variations in temperature observed in each of the catalyst beds after the first bed. The process is applicable to conventional hydrotreatment units, and makes it possible to overcome the effects of the highly exothermic nature of hydroconversion reactions in oils of animal and/or plant origin in hydrotreatment process for obtaining specified diesel fuel oil.
摘要翻译： 描述了用于在中等严苛工艺条件下由至少两个催化剂床构成的常规加氢处理单元中将不同来源的有机油混合物加氢转化以获得柴油燃料油的方法。 该方法包括根据在第一床之后的每个催化剂床中观察到的温度变化向前注入来自加氢处理单元的第二催化剂床的具有独立调节的流速的动物或植物来源的油流 。 该方法适用于常规加氢处理装置，并且可以克服在加氢处理过程中用于获得特定柴油的动物和/或植物来源的加氢转化反应的高度放热性质的影响。
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4.发明授权公开(公告)号：US08366910B2
公开(公告)日：2013-02-05
申请号：US12298071
申请日：2007-04-26
申请人： Jefferson Roberto Gomes , Raissa Maria Cotta Ferreira da Silva , Rogerio Oddone , Adriana de Souza Ferreira , Nelmo Furtado Fernandes
发明人： Jefferson Roberto Gomes , Raissa Maria Cotta Ferreira da Silva , Rogerio Oddone , Adriana de Souza Ferreira , Nelmo Furtado Fernandes
CPC分类号： C10G3/46 , C10G3/50 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/307 , C10G2300/308 , C10G2300/4018 , C10G2400/04 , Y02P30/20
摘要： A process is described for hydroconversion of a mixture of organic oils of different origins in a conventional hydrotreatment unit, constituted by at least two catalyst beds, under moderately severe process conditions to obtain diesel fuel oil. The process includes injection of a stream of oil of animal or plant origin, with independently adjusted flow rates, from the second catalyst bed of the hydrotreatment unit onwards, in accordance with the variations in temperature observed in each of the catalyst beds after the first bed. The process is applicable to conventional hydrotreatment units, and makes it possible to overcome the effects of the highly exothermic nature of hydroconversion reactions in oils of animal and/or plant origin in hydrotreatment process for obtaining specified diesel fuel oil.
摘要翻译： 描述了用于在中等严苛工艺条件下由至少两个催化剂床构成的常规加氢处理单元中将不同来源的有机油混合物加氢转化以获得柴油燃料油的方法。 该方法包括根据在第一床之后的每个催化剂床中观察到的温度变化向前注入来自加氢处理单元的第二催化剂床的具有独立调节的流速的动物或植物来源的油流 。 该方法适用于常规加氢处理装置，并且可以克服在加氢处理过程中用于获得特定柴油的动物和/或植物来源的加氢转化反应的高度放热性质的影响。
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