公开(公告)号：US06379879B2

公开(公告)日：2002-04-30

申请号：US09793045

申请日：2001-02-26

申请人： Jörg Hagemann ,  Günter Helling ,  Heinz Wiesen ,  Ralf Wirowski ,  Ralf Büscher

发明人： Jörg Hagemann ,  Günter Helling ,  Heinz Wiesen ,  Ralf Wirowski ,  Ralf Büscher

IPC分类号： G63C108

CPC分类号： G03C7/3005 ,  G03C7/30517 ,  G03C7/3225 ,  G03C7/344 ,  G03C7/346 ,  G03C7/36 ,  G03C7/384 ,  G03C7/3885 ,  Y10S430/156 ,  Y10S430/158

摘要： A color photographic recording material having at least one spectrally sensitized silver halide emulsion layer, characterized in that said silver halide emulsion layer contains an oil former having a pKa value of less than 18 and a DIR coupler and the material contains at least one color coupler, wherein the color coupler and/or the DIR coupler have specific structures, is distinguished by an increased interimage effect in comparison with the prior art without sensitivity being reduced.

摘要翻译： 具有至少一种光谱增感卤化银乳剂层的彩色照相记录材料，其特征在于，所述卤化银乳剂层含有pKa值小于18的成油剂和DIR成色剂，并且该材料含有至少一种颜色成色剂， 其中彩色耦合器和/或DIR耦合器具有特定结构，其特征在于与现有技术相比增加的图像效果，而不会降低灵敏度。

公开(公告)号：US06531269B2

公开(公告)日：2003-03-11

申请号：US09804564

申请日：2001-03-12

申请人： Ralf Wirowski ,  Jan Haller ,  Stefan Herrmann ,  Jürgen Jung

发明人： Ralf Wirowski ,  Jan Haller ,  Stefan Herrmann ,  Jürgen Jung

IPC分类号： G03C7333

CPC分类号： G03C7/333 ,  G03C7/3029 ,  G03C7/30547

摘要： A color photographic silver halide material, which has a support which comprises at least one blue-sensitive, yellow-coupling silver halide emulsion layer nearest the light source and at least one green-sensitive, magenta-coupling silver halide emulsion layer and at least one red-sensitive, cyan-coupling silver halide emulsion layer which are further from the light source than is the at least one blue-sensitive layer, and which contains at least one cyan masking coupler which has its maximum absorption above 650 mn, the red-sensitive layers have their maximum sensitivity at 620±20 nm and the absorption of the masking coupler at the maximum sensitivity of the red-sensitive layers is at most 70% of its absorption at 690 mn, is distinguished by improved color reproduction and color saturation in the magenta layer without loss of sensitivity.

摘要翻译： 一种彩色照相卤化银材料，其具有包含至少一个最接近光源的蓝色敏感的黄色耦合的卤化银乳剂层和至少一种感绿的品红色偶合的卤化银乳剂层和至少一种 红色敏感的青色耦合的卤化银乳剂层，其比来自光源的至少一个蓝色感光层更远，并且其包含至少一个其最大吸收高于650nm的青色掩蔽耦合器， 敏感层在620±20nm处具有最大灵敏度，并且在感光层的最大灵敏度处的掩蔽成色剂的吸收在其690nm处的吸收的至多70％，其特征在于改进的色彩再现和色彩饱和度 品红色层不失灵敏度。

公开(公告)号：US06218097B1

公开(公告)日：2001-04-17

申请号：US09385734

申请日：1999-08-30

申请人： Peter Bell ,  Ralf Büscher ,  Lothar Rosenhahn ,  Heinz Wiesen ,  Ralf Wirowski

发明人： Peter Bell ,  Ralf Büscher ,  Lothar Rosenhahn ,  Heinz Wiesen ,  Ralf Wirowski

IPC分类号： G03C108

CPC分类号： G03C7/3225 ,  G03C7/3029 ,  G03C7/305 ,  G03C7/384 ,  G03C2007/3034 ,  Y10S430/158

摘要： A colour photographic silver halide material having a support and at least one photosensitive silver halide emulsion layer which contains a magenta coupler of the formula (I) in which R1 to R3, a, b, c and X have the meaning stated in the description, which material contains a DIR coupler of the formula (II) in which R6 to R11 have the meaning stated in the description, is distinguished by improved processing stability.

摘要翻译： 具有支持体的彩色照相卤化银材料和含有式（I）的品红色偶联剂的至少一种感光卤化银乳剂层，其中R1至R3，a，b，c和X具有说明书中所述的含义， 哪个材料含有式（II）的DIR成色剂，其中R6至R11具有说明书中所述的含义，其特征在于改进的加工稳定性。

公开(公告)号：US06569611B2

公开(公告)日：2003-05-27

申请号：US10043760

申请日：2002-01-10

申请人： Jan Haller ,  Ralf Wirowski

发明人： Jan Haller ,  Ralf Wirowski

IPC分类号： G03C146

CPC分类号： G03C7/333 ,  G03C7/30547 ,  G03C7/3335

摘要： A color photographic silver halide material having a support, which material comprises at last one blue-sensitive, yellow-coupling silver halide emulsion layer and at least one green-sensitive, magenta-coupling silver halide emulsion layer and at least one red-sensitive, cyan-coupling silver halide emulsion layer, and which contains at least one masking coupler which has two chromophores which absorb in the wavelength range from 420 to 750 nm and are eliminable or decolorizable by coupling with the developer oxidation product, is distinguished by improved sensitivity associated with undiminished color purity.

摘要翻译： 一种具有支持体的彩色照相卤化银材料，该材料包括最后一个蓝色敏感的黄色耦合的卤化银乳剂层和至少一种感绿的品红色偶联卤化银乳剂层和至少一种红色敏感的， 青色偶联卤化银乳剂层，并且其包含至少一种掩蔽成色剂，其具有通过与显影剂氧化产物偶联可消除或脱色的具有420nm至750nm波长范围内吸收的两个发色团，其特征在于具有相关联的改善的敏感性 颜色纯度不变。

公开(公告)号：US06261758B1

公开(公告)日：2001-07-17

申请号：US09616445

申请日：2000-07-14

申请人： Ralf Wirowski ,  Hans-Ulrich Borst ,  Detlev Kapitza ,  Jörg Siegel ,  Peter Bergthaller ,  Heinrich Odenwälder

发明人： Ralf Wirowski ,  Hans-Ulrich Borst ,  Detlev Kapitza ,  Jörg Siegel ,  Peter Bergthaller ,  Heinrich Odenwälder

IPC分类号： G03C1035

CPC分类号： G03C1/07 ,  G03C1/0051 ,  G03C2001/0055 ,  G03C2001/0153 ,  G03C2200/33

摘要： The production of tabular silver bromide-iodide emulsions and silver bromide-chloride-iodide emulsions with an aspect ratio 32, an iodide content from 1 to 40 mol % and a chloride content from 0 to 20 mol %, by the process steps of (a) silver halide nucleus precipitation, and (b) at least one further precipitation of silver halide, wherein rein at least one aromatic five- or six-membered, heterocyclic compound, which is free from—SH—,—SSO2H— and—SSO2R groups, is added in an amount from 10−9 to 10−4 mol/mol silver during nucleus precipitation or during the precipitation of an inner zone of the silver halide grain which is different from the nucleus precipitate, results in an improved speed/grain size ratio and in an increased stability of a photographic material which contains an emulsion produced in this manner.

摘要翻译： 通过（a）的方法步骤制备长宽比为32，碘化物含量为1至40摩尔％，氯化物含量为0至20摩尔％的片状溴化银碘化物乳液和溴化银 - 碘化碘化银乳剂 ）卤化银核沉淀，和（b）卤化银的至少一种进一步沉淀，其中保留至少一种不含-SH - ， - SSO2H和 - SSO2R基团的芳族五元或六元杂环化合物 ，在沉淀过程中或在不同于核沉淀物的卤化银颗粒的内部区域的析出过程中，其添加量为10-9至10-4mol / mol银，导致速度/晶粒尺寸的改善 比例和增加的含有以这种方式生产的乳液的照相材料的稳定性。